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11.
In order to develop mixed protonic and electronic conductors, we proposed a novel concept for material design that enables to control partial conductivities by fabricating solid solutions of protonic and electronic conductors. In this work, Sr-doped LaBO3 and Sr-doped CeBO3 were chosen as model compounds conducting protons and electron holes, respectively. Solid solutions of the above borates, Sr-doped La1 − xCexBO3, were prepared, and their electrical conductivities were investigated in 8.5 × 102-4.2 × 103 Pa of p(H2O) and 1.0 × 10-1.0 × 105 Pa of p(H2) at 1073 K. From the experimental results of the gas partial pressure dependences of the conductivities, major charge carrier species were identified as a function of x. It was found that proton was the major charge carrier when x < 0.2 while the contribution of the electron hole conduction became remarkable as x increased above 0.2. The contribution of the electron hole conduction can be interpreted by the percolation model. 相似文献
12.
Tadakatsu Mandai Masashi Yamaguchi Yuka Nakayama Junzo Otera Mikio Kawada 《Tetrahedron letters》1985,26(22):2675-2676
Development of a new synthetic method for α-ketosilanes can be achieved by a sequence of alkylation of methoxy(phenylthio)trialkylsilylmethane and oxidation with NaIO4. 相似文献
13.
K Okamoto M Matsumoto M Watanabe M Kawada T Imamoto I Imada 《Chemical & pharmaceutical bulletin》1985,33(9):3745-3755
14.
Raman scattering of FexV3-xS4 with 0?x?2 has been studied. The observed spectra of V3S4, one of the end members of this solid solution, have been assigned to the Raman active lattice modes based on the C2h3 space group symmetry. On the basis of the results obtained for V3S4, the nature of the metal-metal interactions and the site distributions of Fe atoms in (Fe, V)3S4 have been discussed. 相似文献
15.
Various types of α-cyanoallylic acetates were undergone the palladium-catalyzed rearrangement to give the γ-acetoxy-α,β-unsaturated nitriles in high yields. These rearranged acetates were conveniently transformed into the furan derivatives often encountered in natural products by the reduction using diisobutylaluminum hydride. 相似文献
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Abstract Thermoluminescence (TL) and ESR phenomena induced by X-ray irradiation of the mixed samples of K2SO4 and alkaline earth metal sulfate (MgSO4 or BaSO4) were investigated in terms of the reactivities and the crystallogrpahic properties. A high intensive TL resulted from the diffusion of a small amount of Mg2+ into K2SO4 crystals. The amount formed of K2Mg2(SO4)3, langbeinite, compound had a maximum at the stoichiometric composition. From the ESR measurements, SO? 3 radicals were found to be easily formed in the langebeinite by excitation. Both the TL and the ESR phenomena were hardly observed in the K2SO4–BaSO4 system due to little diffusion of Ba2+ with much larger radius than Mg2+. The results were mainly discussed on the basis of the radii of the component cations in these systems. In addition, the fundamental data as to the application to the ESR dosimetry were obtained. 相似文献
19.
K. Tshoo Y. Satou H. Bhang S. Choi T. Nakamura S. Deguchi Y. Kawada Y. Kondo N. Kobayashi Y. Nakayama K. N. Tanaka N. Tanaka N. Aoi M. Ishihara T. Motobayashi H. Otsu H. Sakurai S. Takeuchi Y. Togano K. Yoneda Z. H. Li F. Delaunay J. Gibelin F. M. Marques N. A. Orr T. Honda M. Matsushita T. Kobayashi Y. Miyashita T. Sumikama K. Yoshinaga S. Shimoura D. Sohler T. Zheng Z.X. Cao 《Few-Body Systems》2013,54(1-4):459-463
The unbound excited states of the most neutron-rich dripline oxygen isotope, 24O, have been investigated by using the 24O(p,p′)24O* reaction at the beam energy of 62 MeV/nucleon in inverse kinematics. The first and second unbound excited states of 24O have been observed at ${E_{\rm x}= 4.63_{-0.14}^{+0.30}}$ MeV and ${E_{\rm x}= 5.13_{-0.24}^{+0.19}}$ MeV (preliminary) along with the evidence for another higher lying state at around 7.3 MeV. The quadrupole deformation parameter ${\beta_{2^+}}$ was deduced to be ${0.15_{-0.03}^{+0.08}}$ (preliminary) for the first time. The systematics of the ${\beta_{2^+}}$ and the ${E_{\rm x}(2_1^+)}$ in the Z = 8 isotopes shows the N = 16 spherical shell closure in 24O. 相似文献
20.
Izumi Sakamoto Kazuya Iwaoka Yuta Kawada Takanori Naito Kazuyoshi Makida Yuki Takeuchi Takeshi Nishii Mitsuyo Horikawa Hiroto Kaku Tetsuto Tsunoda 《Tetrahedron》2018,74(24):3052-3060
3,3-Dimethoxypropylsulfonyl (Dimps) chloride was prepared and used as a new versatile sulfonating agent for ammonia, primary and secondary amines to afford corresponding Dimps-amides in excellent yields. The resulting N-nonsubstituted and N-monosubstituted Dimps-amides, activated amines, were alkylated satisfactorily under new Mitsunobu conditions. The Dimps group was removed by treatment in aqueous solution under acidic followed by basic conditions. Furthermore, epilachnene, the defensive droplets from the Mexican bean beetle, Epilachna varivestis, was synthesized utilizing this Dimps methodology in short steps. 相似文献