Upconversion Based Tunable White-Light Generation in Ln:Y<Subscript>2</Subscript>O<Subscript>3</Subscript> Nanocrystalline Phosphor (Ln = Tm/Er/Yb)

We report the generation of efficient white light based on upconversion (UC) in Tm³⁺/Er³⁺/Yb³⁺:Y₂O₃ nanocrystalline phosphor synthesized by simple and cost effective solution combustion technique on 976 nm laser excitation. The calculated color coordinates (using 1931 CIE standard) for samples annealed at different temperatures vary from (0.16, 0.30) to (0.32, 0.33) with dopant concentration, annealing temperature and the pump power; thus providing a wide color tunability including the white one. White emission is observed even at a very low laser power (60 mW). The maximum upconversion efficiency obtained for white emission is 2.79% with the color coordinates (0.30, 0.32) at laser power of 420 mW which is quite close to the standard white color coordinates.     

Tunable,dual-wavelength interferometrically coupled continuous-wave parametric source

Generation of dual-wavelength continuous-wave (cw) radiation with independent and arbitrarily tuning, and indefinitely close spacing, using two cw optical parametric oscillators (OPOs) coupled with an anti-resonant ring interferometer is reported. The singly resonant OPOs, based on identical 30-mm-long MgO:sPPLT crystals, are pumped by a single cw laser at 532 nm. Two pairs of signal and idler wavelengths can be independently and arbitrarily tuned, with each signal (idler) pair tuned through degeneracy and beyond. Frequency separation between two distinct resonant signal waves from 7 down to 0.8 THz is demonstrated, and their overlap at 951 nm providing a frequency difference as small as ~220 MHz is shown. The OPOs independently provide a signal (idler) wavelength coverage across 870–1,000 nm (1,040–1,370 nm) and simultaneously generate idler powers of >1 W.     

Exact Solutions for the Flow of Fractional Maxwell Fluid in Pipe-Like Domains

This paper presents an analysis of unsteady flow of incompressible fractional Maxwell fluid filled in the annular region between two infinite coaxial circular cylinders. The fluid motion is created by the inner cylinder that applies a longitudinal time-dependent shear stress and the outer cylinder that is moving at a constant velocity. The velocity field and shear stress are determined using the Laplace and finite Hankel transforms. Obtained solutions are presented in terms of the generalized G and R functions. We also obtain the solutions for ordinary Maxwell fluid and Newtonian fluid as special cases of generalized solutions. The influence of different parameters on the velocity field and shear stress is also presented using graphical illustration. Finally, a comparison is drawn between motions of fractional Maxwell fluid, ordinary Maxwell fluid and Newtonian fluid.     

Effect of Zn and Mg doping on structural,dielectric and magnetic properties of tetragonal CuFe2O4

The Cu_1?xA_xFe₂O₄ (A = Zn, Mg; x = 0.0, 0.5) ferrites were successfully synthesized by chemical co-precipitation method. X-ray diffraction and Raman spectroscopy reveals that all the ferrite samples are in single-phase with tetragonal structure for CFO and cubic spinel structure for CZFO and CMFO samples. SEM micrograph shows the variation of grain size with Zn and Mg doping in parent CFO sample. Frequency dependent dielectric response confirms the dielectric polarization and electrical conduction mechanism in the present series with a maximum value of dielectric constant and loss tangent for CZFO sample. The anomaly ～493 K in temperature dependent dielectric constant and dielectric loss is assigned to tetragonal to cubic phase transition in CFO sample. The magnetic measurement explored that the saturation value (M_s) is maximum for CZFO as compared to CFO and CMFO ferrites samples.     

List star chromatic index of sparse graphs

A star edge-coloring of a graph $G$ is a proper edge coloring such that every 2-colored connected subgraph of $G$ is a path of length at most 3. For a graph $G$, let the list star chromatic index of $G$, $c{h}_s^{\prime }\left(G\right)$, be the minimum $k$ such that for any $k$-uniform list assignment $L$ for the set of edges, $G$ has a star edge-coloring from $L$. Dvo?ák et al. (2013) asked whether the list star chromatic index of every subcubic graph is at most 7. In Kerdjoudj et al. (2017) we proved that it is at most 8. In this paper we consider graphs with any maximum degree, we proved that if the maximum average degree of a graph $G$ is less than $\frac{14}{5}$ (resp. 3), then $c{h}_s^{\prime }\left(G\right)\le 2\Delta \left(G\right)+2$ (resp. $c{h}_s^{\prime }\left(G\right)\le 2\Delta \left(G\right)+3$).     

Electrochemical and spectral characterization of blue copper protein models

Blue copper proteins play a central role in various enzymatic anabolic/catabolic pathways in living cells by virtue of the integrated metal ions. These ions may exist in variable oxidation states, with suitable reduction potentials and fast electron-transfer rates which in turn is a manifestation of their unusual geometry and co-ordination. We report the electrochemical and spectral characterization of three novel complexes of copper (II) with N₂S type tridentate chelating agent 2,2′-dithiodianiline (dta), having structural similarities to the active site of Type I copper proteins. High positive redox potentials in the range of 0.5–0.6 V vs Ag/AgCl electrode of the complexes and the absorption maxima at ～550 nm, with high extinction coefficients, correspond well with typical blue copper proteins. The IR and EPR studies support the assigned pseudo tetrahedral structures to the complexes. The diffusion coefficient and rate constant for heterogeneous charge transfer for Cu²⁺/Cu⁺ coordinated in a potentially bio-mimetic Type I site is reported.     

Nanocompatible chemistry toward fabrication of target-specific gold nanoparticles

Nanocompatible chemistry which utilizes a novel nontoxic phosphino amino acid as a reducing agent has resulted in the development of therapeutically useful gold nanoparticles under biologically benign media. Stabilization of gold nanoparticles by the edible gum arabic matrix has provided an effective pathway toward in vivo stable target-specific gold nanoparticles.     

Multicrystal, continuous-wave, single-pass second-harmonic generation with 56% efficiency

We report a simple and compact implementation for single-pass second-harmonic-generation (SP-SHG) of cw laser radiation, based on a cascaded multicrystal (MC) scheme, that can provide the highest conversion efficiency at any given fundamental power. By deploying a suitable number of identical 30-mm-long MgO:sPPLT crystals in a cascade and a 30W cw Yb-fiber laser at 1064nm as the fundamental source, we demonstrate SP-SHG into the green with a conversion efficiency as high as 56% in the low-power as well as the high-power regime, providing 5.6W of green output for 10W and 13W of green output for 25.1W of input pump power. The MC scheme permits substantial increase in cw SP-SHG efficiency compared to the conventional single-crystal scheme without compromising performance with regard to power stability and beam quality.     

Physics with the new WASA-at-COSY facility

The Wide Angle Shower Apparatus (WASA), previously operated at Uppsala, Sweden, is now installed at the COSY accelerator at Jülich Forschungszentrum, Germany. The main goal of the WASA-at-COSY collaboration is to study symmetry violations in hadronic reactions focusing on η and η′ decays. The Nuclear Physics Institute at Jülich Forschungszentrum and Department of Physics at IIT Bombay are collaborating to understand QCD at intermediate distance scales using the proton beam from the COSY accelerator with proton and deuteron targets. In this paper, we present the preliminary analysis on three different channels being investigated jointly by the two groups.     

beta-acylvinyl anion and dianion equivalents: lithiation of 1-[(2EZ)-3-chloroprop-2-enyl]-1H-1,2,3-benzotriazole: preparation and elaboration of 1-(2-oxiranylvinyl)-1H-benzotriazoles

The allyllithium generated from 1-[(2EZ)-3-chloroprop-2-enyl]-1H-1,2,3-benzotriazole (5) and LDA, in the presence of HMPA, reacts with enolizable and nonenolizable carbonyls solely at the CCl terminus to give 1-(2-oxiranylvinyl)benzotriazoles 6a-g in 61-82% yields. Allyllithiums generated from 6a,c reacted exclusively at the CBt terminus to give 10a-d in 68-88% yields. Acidic hydrolysis of (oxiranylvinyl)benzotriazoles 6a-g and 10a-d provided 4-hydroxyalk-2-en-1-one derivatives 12a,b,c,e,g, 13a-d, and furan 14 in 54-86% yields.