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41.
Masataka Sugimoto Takumi Koizumi Takashi Taniguchi Kiyohito Koyama Katsuhiro Saito Daigo Nonokawa Tsuyoshi Morita 《Journal of Polymer Science.Polymer Physics》2009,47(22):2226-2237
Melt rheological behaviors of hyperbranched‐polystyrene (PS) copolymerized by dendric macromonomer technique are presented. The time–temperature superposition principle was applicable to the hyperbranched‐PS. The branched‐PS showed slightly lower zero‐shear viscosity in comparison with linear PS regardless of a presence of a number of branches expected from the dendric macromonomer technique. Although the influence of use of multimethacryloyl macromonomer in the polymerization process was marginal for linear viscoelastic regime, nonlinear shear and uniaxial elongational flows showed distinct differences between linear and branched‐PS. The strain dependence of the damping function became weak as increase of macromonomer content. The branched‐PS exhibited the growing elongational viscosity function comparing with linear PS. This prominent effect on the elongational flow behavior can be explained by the molecular architecture of the branched‐PS. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 2226–2237, 2009 相似文献
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Dr. Shintaro Ishida Dr. Takashi Abe Dr. Fumiya Hirakawa Tomoyuki Kosai Katsuhiro Sato Prof. Dr. Mitsuo Kira Prof. Dr. Takeaki Iwamoto 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(43):15100-15103
A persistent dialkylsilanone was synthesized by the dehydrobromination of a dialkylbromosilanol with tris(trimethylsilyl)silyl potassium in solution at ?80 °C: It was characterized by NMR and IR spectroscopy, and was tested in several reactions. In 29Si NMR spectrum in [D8]toluene, the signal due to the unsaturated silicon nuclei was observed at 128.7 ppm. Reactions of the dialkylsilanone with water and mesitonitrile oxide gave a silanediol and a [2+3] cycloadduct, respectively. The silanone remains intact in [D8]toluene below ?80 °C for at least two days, while it undergoes unprecedented isomerization to give a siloxysilene by means of 1,3‐silyl migration at higher temperatures. 相似文献
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Frontispiece: Entropy‐Driven 1,2‐Type Friedel–Crafts Reaction of Phenols with N‐tert‐Butoxycarbonyl Aldimines 下载免费PDF全文
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It is well‐known that every planar graph has a vertex of degree at most five. Kotzig proved that every 3‐connected planar graph has an edge xy such that deg(x) + deg (y) ≤ 13. In this article, considering a similar problem for the case of three or more vertices that induce a connected subgraph, we show that, for a given positive integer t, every 3‐connected planar graph G with |V(G)| ≥ t has a connected subgraph H of order t such that Σx∈V(H) degG(x) ≤ 8t − 1. As a tool for proving this result, we consider decompositions of 3‐connected planar graphs into connected subgraphs of order at least t and at most 2t − 1. © 1999 John Wiley & Sons, Inc. J Graph Theory 30: 191–203, 1999 相似文献
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Toshio Matsushita Ken Hirotsu Taiichi Higuchi Kichisuke Nishimoto Masaaki Yoshifuji Katsuhiro Shibayama Naoki Inamoto 《Tetrahedron letters》1984,25(31):3321-3324
Ab initio Calculations of the isomerization reaction of diphosphene 1-sulfide (2′) to thiadiphosphirane (3′) suggest that the energy barrier of the reaction in the ground state is 25 kcal/mol and that 2′ lies 21 kcal/mol above 3′, while the calculations show that there exists one local minimum on the lowest triplet energy surface. 相似文献
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A graph G of order at least 2n+2 is said to be n‐extendable if G has a perfect matching and every set of n independent edges extends to a perfect matching in G. We prove that every pair of nonadjacent vertices x and y in a connected n‐extendable graph of order p satisfy degG x+degG y ≥ p ? n ? 1, then either G is hamiltonian or G is isomorphic to one of two exceptional graphs. © 2002 Wiley Periodicals, Inc. J Graph Theory 40: 75–82, 2002 相似文献
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