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191.
Wojciech Bocian Jarosław Jaźwínski Lech Stefaniak Graham A. Webb 《Chemistry of Heterocyclic Compounds》1995,31(9):1103-1107
1H,13C,14N and15N NMR measurements are reported for four mesoionic 1-oxa-2, 3, 4-triazoles containing exocyclic nitrogenous groups. The NMR signal assignments are discussed and compared with those previously published for some corresponding oxatriazoles. The results obtained support the proposed cyclic mesoionic structures for the compounds studied. The questions of possible charge delocalization and valence tautomerism are addressed. Compound with N– H as a exocyclic group (Fig. 1) is found to be relatively unstable, this is attributed to proton migration in the corresponding non-cyclic form of this molecule.Published in Khimiya Geterotsikiicheskikh Soedinenii, No. 9, pp. 1260–1263, September, 1995. 相似文献
192.
F. Máca 《Czechoslovak Journal of Physics》1993,43(9-10):941-945
We present the calculations of electronic structure and photoemission spectra for a lattice-matched Ag-Au(111) superlattice. The selfconsistent band structure exhibits a superlattice gap at about 1 eV below the Fermi level. A surface state is found in this gap and its dispersion properties are investigated. Its energy location is varied with location of surface terminating plane within the superlattice period. The calculated normal photoemission spectra explain well available experimental data. 相似文献
193.
José Natário 《General Relativity and Gravitation》2006,38(3):475-484
We find a class of warp drive spacetimes possessing Newtonian limits, which we then determine. The same method is used to
compute Newtonian limits of the Schwarzschild solution and spatially flat Friedmann-Robertson-Walker cosmological models.
This work was partially supported by FCT/POCTI/FEDER. 相似文献
194.
A new and rather trivial model is suggested with mechanism that implies simultaneous violation of the zeroth and the second
laws of thermodynamics. Mathematically rigorous quantum theory reduces to a trivial application of the Golden rule formula.
It yields exciton on-energy-shell diffusion caused by bath-nonassisted excitation hopping between tails of different exciton
site levels ε1 < ε2 broadened by bath-assisted finite life-time effects. The elastic character of the hopping implies 1 ↔ 2-symmetric transfer
rate W. Thus the net diffusion exciton flow W(P
1 - P
2) and also, as argued, the net energy flow are possible due to different near-to-equilibrium exciton populations P
1 > P
2. As the sites are provided with two different baths, the population imbalance and the flows survive even for slightly different
local bath temperatures T
1 < T
2 < T
1ε2/ε1. Thus spontaneous exciton and also energy flows against temperature step become possible, in contradiction with the Clausius
form of the second law. Violations of both the laws disappear in the high-temperature, i.e. classical limit
Received 16 May 2001 and Received in final form 20 September 2001 相似文献
195.
196.
Jan Andres Karel Pastor Pavla Šnyrychová 《Journal of Fixed Point Theory and Applications》2007,2(1):153-170
A multivalued version of Sharkovskiĭ’s theorem is formulated for M-maps on linear continua and, more generally, for triangular M-maps on a Cartesian product of linear continua. This improves the main result of [AP1] in the sense that our multivalued
analogue holds with at most two exceptions. A further specification requires some additional restrictions. For instance, 3-
orbits of m-maps imply the existence of k-orbits for all
k ? \mathbbNk \in {\mathbb{N}}
, except possibly for
k ?k \in
{4, 6}. It is also shown that, on every connected linearly ordered topological space, an M-map with orbits of all periods can always be constructed. This demonstrates that Baldwin’s classification of linear continua
in terms of admissible periods [Ba] is useless for multivalued maps. 相似文献
197.
Lubomír Kubáček 《Mathematica Slovaca》2007,57(1):59-82
In some situations estimates of unknown parameters must be corrected by additional measurements. It is in principle no problem
to calculate the corrected estimates, however, it is of more interest to find formulae for correction itself. The formulae
enable us to design an additional experiment and to judge its usefulness.
The aim of the paper is to find such formulae for several situations.
Supported by the grant of the Council of Czech Government MSM 6 198 959 214. 相似文献
198.
We investigate traces of functions, belonging to a class of functions with dominating mixed smoothness in ℝ3, with respect to planes in oblique position. In comparison with the classical theory for isotropic spaces a few new phenomenona
occur. We shall present two different approaches. One is based on the use of the Fourier transform and restricted to p = 2. The other one is applicable in the general case of Besov-Lizorkin-Triebel spaces and based on atomic decompositions. 相似文献
199.
Influence of boric acid on the electrochemical deposition of Ni 总被引:1,自引:0,他引:1
M. Šupicová R. Rozik L. Trnková R. Oriňáková M. Gálová 《Journal of Solid State Electrochemistry》2006,10(2):61-68
The electrolytic deposition of Ni onto a paraffin-impregnated graphite electrode from supporting chloride electrolyte (0.5 mol dm−3 NaCl) adjusted to the required pH using dilute HCl is investigated. The effect of electrolyte composition on the Ni electrodeposition
is studied using linear sweep voltammetry in the cathodic region. An elimination voltammetry procedure was applied to evaluate
the polarization curves. The aim of this work was to deduce the mechanism of Ni reduction in the chloride bath as well as
the influence of boric acid on this. Positively-charged NiCl+ ions were found to be the electroactive particles in the Ni reduction mechanism. The strong competition between the NiCl+, Cl− and H+ ions for active sites at the electrode is discussed. Kinetically-controlled adsorption/desorption processes of various species
were also confirmed using elimination voltammetry with a linear scan. The evolution of gaseous hydrogen, catalyzed by the
freshly-deposited Ni, accompanies the electrodeposition process. The presence of boric acid at a sufficiently high concentration
inhibits the deposition of Ni and, at the same time, improves the morphology and brightness, as well as the adhesion of the
deposited Ni.
Elimination voltammetry with a linear scan is an efficient way to evaluate current–potential curves that reflect the electrodeposition
of one-component Ni coatings. By eliminating selected currents, additional interesting and useful information can be obtained
from voltammetric data. 相似文献
200.