Interaction of RuIII(EDTA) with cellular thiols and O2: biological implications thereof

Reaction of [Ru^III(EDTA)(CyS)]^2? (edta^4? = ethylenediaminetetraacetate; CySH = cysteine) with molecular oxygen (O₂) has been studied as a function of pH (4.0–8.0) and cysteine concentration (0.2–2.0 mM) at room temperature (25 °C). Biological activities of the [Ru(EDTA)]/CySH/O₂ system pertaining to cleavage of supercoiled plasmid DNA to its nicked open circular form has been explored in this work. Results are discussed in regard to the reaction of the ruthenium(III)-complex with molecular oxygen) and a working mechanism is proposed for the biological activities of the ruthenium(III)-complex in the presence of O₂.     

Real‐time electro‐diffusion method to discriminate carbon nanomaterials

We report both the experimental and theoretical insights of differential electro‐diffusion behavior of carbon nanomaterials (e.g. single wall, multiwall carbon nanotubes, and graphene). We thus discriminate one from the other in a soft gel system. The differential mobility of such material depends on their intrinsic properties, both extend and rate of migration bearing the discriminatory signature. The mobility analysis is made by a real time monitoring of the respective bands.     

Kinetic market models with single commodity having price fluctuations

We study here numerically the behavior of an ideal gas like model of markets having only one non-consumable commodity. We investigate the behavior of the steady-state distributions of money, commodity and total wealth, as the dynamics of trading or exchange of money and commodity proceeds, with local (in time) fluctuations in the price of the commodity. These distributions are studied in markets with agents having uniform and random saving factors. The self-organizing features in money distribution are similar to the cases without any commodity (or with consumable commodities), while the commodity distribution shows an exponential decay. The wealth distribution shows interesting behavior: gamma like distribution for uniform saving propensity and has the same power-law tail, as that of the money distribution, for a market with agents having random saving propensity.     

On use of ghost-less beam splitter in reversal shear interferometer for measurement of spatial coherence of large cross-section laser beam

A configuration of reversal shear interferometer suitable for measurement of spatial coherence of high average power, large cross-section laser beam has been discussed. Ghost-less beam splitters in which unwanted multiple reflections from the surfaces have been suppressed by total internal reflection are used for beam splitting and re-combination. Advantages and drawbacks of this configuration have been discussed.     

Effects of screening on quark-antiquark cross sections in quark-gluon plasma

Lowest-order cross sections for qq? production and annihilation can be approximately corrected for higher-order QCD effects by using a corrective K-factor. For energies where quark masses cannot be ignored, the K-factor is dominated by the wave function distortion arising from the initialor final-state interaction between the quark and the antiquark. We evaluate this K-factor for qq? production and annihilation in a quark-gluon plasma by taking into account the effects of Debye screening through a color-Yukawa potential. We present the corrective K-factor as a function of dimensionless parameters which may find applications in other systems involving attractive or repulsive Yukawa interactions. Prominent peaks of the K-factor occur for an attractive q-q? color-Yukawa interaction with Debye screening lengths of 0.835 and 3.23 times the Bohr radius, corresponding to two lowest s-wave qq? bound states moving into the continuum to become qq? resonances as the Debye screening length decreases. These resonances, especially the cc? and the bb? resonances, may be utilized to study the quark-gluon plasma by examining the systematics of the temperature dependence of heavy-quark pair production just above the threshold.     

Proton NMR in CeNiInH0.53 down to liquid helium temperature

The NMR probe and the matching network has been designed for the¹H NMR study in CeNiInH_0.53 down to liquid helium temperature using Bruker MSL 100 spectrometer. NMR line-shape measurement shows the absence of any signature of proton pairing in CeNiInH_0.53 down to 3.86 K, as it was observed for high hydrogen concentration. The measurement of the spin-lattice relaxation time in the temperature range 300–20K reveals that the relaxation rate is mainly governed by the Korringa-type relaxation mechanism.     

Study of copolymer–copolymer interactions and formation of intermacromolecular complexes

Interpolymer complex formation has been studied between methacrylic acid-methacrylamide copolymer and acrylic acid–acrylamide copolymer. The respective co-monomer units of the two copolymers enter into complex formation through H-bonding and ion dipole interactions. The unreacted units in the copolymer complex also interact with homopolymers such as PEO and PVP to form ternary complex. Formation of complexes and replacement reactions could be shown through several experimental techniques, e.g., viscometry, conductometry, and potentiometry.     

Effect of radiation on the Peierls transition

The effect of radiation on the Peierls transition in a one-dimensional metal is investigated. It is pointed out that an external radiation field satisfying appropriate frequency conditions reduces the width of the Peierls gap.