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71.
N. Azcan M. Kara D. T. Asilbekova T. Ozek K. H. C. Baser 《Chemistry of Natural Compounds》2000,36(2):132-136
Neutral lipids, glycolipids, phospholipids, pigments, and essential oil of the above-ground part ofOriganum onites L. (Lamiaceae) are isolated and characterized for the first time. The fatty-acid composition of the lipids and the components of the hydrocarbons, sterols, and essential oil are determined by GC/MS. Linolenic and palmitic acids dominate in the acids of the lipids. The main components of the hydrocarbons are nonacosane; of the sterols, \-sitosterol; of the pigments, chlorophylls a and b. A total of 54 components are identified in the essential oil.Presented at the IIIrd International Symposium on the Chemistry of Natural Compounds, Bukhara, Uzbekistan, 19–22 December, 1998.Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 106–109, March–April, 2000. 相似文献
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We study the hub covering problem which, so far, has remained one of the unstudied hub location problems in the literature. We give a combinatorial and a new integer programming formulation of the hub covering problem that is different from earlier integer programming formulations. Both new and old formulations are nonlinear binary integer programs. We give three linearizations for the old model and one linearization for the new one and test their computational performances based on 80 instances of the CAB data set. Computational results indicate that the linear version of the new model performs significantly better than the most successful linearization of the old model both in terms of average and maximum CPU times as well as in core storage requirements. 相似文献
75.
Elif Gungor Mustafa Burak Coban Hulya Kara Yasemin Acar 《Journal of Cluster Science》2018,29(3):533-540
A new open-cubane MnIII, [{(H2O)MnIIIL}{MnIIIL}]2·2(CH3OH).2(CH3CH2OH)·2Cl, 1 where H 2 L=[N-(2-hydroxyethyl)-3-methoxysalicylaldimine] has been synthesized and characterized by element analysis, FT-IR, solid UV–Vis spectroscopy and single crystal X-ray diffraction. The crystal structure determination shows an open-cubane tetranuclear complex. The Mn1 (Mn1i) ions is hexacoordinate by NO5 donor sets while the Mn2 (Mn2i) is pentacoordinate by NO4 donor sets. The solid state photoluminescence properties of complex 1 and its ligand H 2 L have been investigated under UV light at 349 nm in the visible region. H 2 L exhibits blue emission while complex 1 shows orange-red emission at room temperature. Variable-temperature magnetic susceptibility measurements on the complex 1 in the range 2–300 K indicate an antiferromagnetic interaction. 相似文献
76.
A. Sibari Z. Kerrami A. Kara M. Hamedoun A. Benyoussef O. Mounkachi M. Benaissa 《Journal of Solid State Electrochemistry》2018,22(1):11-16
A computational study of the adsorption and diffusion behavior of alkali and alkaline earth metal atoms on a phosphorene monolayer is reported. Our calculations were performed within the framework of density functional theory using the Perdew–Burke–Ernzerhof functional and projector augmented wave potentials, as derived from the generalized gradient approximation. Our binding energy calculations for various potential adsorption sites showed that the site located above the center of a triangle formed by three surface phosphorus atoms is the most attractive to all adatoms. In addition, simulation of the diffusion of adatoms across the surface of the phosphorene monolayer showed that the diffusion is anisotropic, with K having the lowest diffusion barrier (0.02 eV along the zigzag pathway). To the best of our knowledge, this is the lowest diffusion barrier of any metal adatom on a single layer of phosphorene. While phosphorene exhibited significantly better adatom adsorption and diffusion than graphene, it also showed a reduced storage capacity compared to graphene, most probably due to the structural distortion induced by the oversaturated phosphorene surface. This finding strongly suggests that a phosphorene–graphene hybrid system could be employed as a promising high-capacity ion anode. 相似文献
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Karlo Jurica Vesna Benković Sunčana Sikirić Irena Brčić Karačonji Nevenka Kopjar 《Natural product research》2020,34(16):2354-2357
Abstract Although strawberry tree (Arbutus unedo L.) leaves have long been used as a herbal remedy, insufficient information is available on their nephrotoxicity. We assessed the safety of strawberry tree water leaf extract and its key component arbutin, administered per os to Lewis rats of both genders at 200?mg/kg b.w./day for 14 and 28 days. The effects of the tested compounds on DNA integrity in renal cells was evaluated using alkaline comet assay, while kidney function was studied using serum creatinine and urea levels. Strawberry tree water leaf extract showed high biocompatibility with kidney tissue. It did not impair DNA integrity of renal cells and kidney function, either in male or female rats. However, exposure to single arbutin affected the levels of primary DNA damage in renal cells which could be related to metabolic conversion of arbutin into hydroquinone, whose nephrotoxicity has previously been proven. 相似文献
79.
Matthew R. Dintzner Kara M. Morse Kristen M. McClelland Deborah M. Coligado 《Tetrahedron letters》2004,45(1):79-81
The [1,3] shift reaction of 3-methyl-2-butenyl phenyl ether was catalyzed more effectively by Montmorillonite K10 clay than Montmorillonite KSF clay, and proceeded with greatest ortho-selectivity in carbon tetrachloride at room temperature. 相似文献
80.
Hunka DE Herman DC Lormand KD Jaramillo DM Land DP 《Langmuir : the ACS journal of surfaces and colloids》2005,21(18):8333-8337
The decomposition of 1,1-dichloroethene on Pd(111) is investigated using conventional thermal desorption, laser-induced thermal desorption (LITD), and FT reflection absorption infrared spectroscopy (FT-RAIRS). The decomposition mechanism produces at least three hydrocarbon surface intermediates, including ethylidyne. Thermal desorption results differ between high and low coverages because of relative surface concentrations of Cl and H in combination with kinetic effects. 相似文献