Iodine catalyzed pyrolysis of dimethyl sulfide. Heats of formation of CH3SCH2I,the CH3SCH2 radical,and the pibond energy in CH2S

A kinetic study has been made of the gas phase, I₂-catalyzed decomposition of (CH₃)₂S at 630–650 K. Some I₂ is consumed initially, reaching a steady-state concentration. The initial major products are CH₄ and CH₂S together with small amounts of CH₃SCH₂I, CH₃I, HI, and CS₂. The initial reaction corresponds to a pseudo-equilibrium: accompanied by: and which brings (I₂) into steady state and a final complex reaction: From the initial rate of I₂ loss it is possible to obtain Arrhenius parameters for the iodination: We measure k₁, (644 K) = 150 L/mol s and from both the Arrhenius plot and independent estimates A₁ (644 K) = 10^{11.2 ± 0.3} L/mol s. Thus, E₁ = 26.7 ± 1 kcal/mol. From the steady-state I₂ concentration, an assumed mechanism and the known rate parameters for the CH₃I/HI system. It is possible to deduce K_A (644) = 3.8 × 10^?2 with an uncertainty of a factor of 2. Using an estimated ΔS (644) = 4.2 ± 1.0 e.u. we find ΔH_A (644) = 7.0 ± 1.1 kcal. With 〈ΔC_PA〉644 = 1.2 this becomes: ΔH_A(298) = 6.6 ± 1.1 kcal/mol. Then ΔH (CH₃SCH₂I) = 6.3 ± 1 kcal/mol. Making the assumption that E_?1 = 1.0 ± 0.5 kcal/mol we find ΔH (644) = 25.7 ± 0.7 kcal/mol and with 〈ΔC_PI〉 = 1.2; ΔH = 25.3 ± 0.8 kcal/mol. This gives ΔH (CH₃S?H₂) = 35.6 ± 1.0 kcal/mol and DH (CH₃SCH₂? H) = 96.6 ± 1.0 kcal/mol. This then yields E_π(CH₂S) = 52 ± 3 kcal. From the observed rate of pressure increase in the system and the preceding data k₃, is calculated for the step CH₃SCH₂ → CH₃ + CH₂S. From an estimated A-factor E₃ is deduced and from the overall thermochemistry values for k_?3 and E_?3. A detailed mechanism is proposed for the I-atom catalyzed conversion of CH₂S to CS₂ + CH₄.     

All optical microwave photonic filters with a round-trip configuration

We propose novel photonic microwave multi-tap filters using a section of Hi-Bi fiber in a round-trip configuration, together with their application in a 20 km single mode fiber (SMF) radio-over-fiber (RoF) link. We demonstrate for the first time that the effect of chromatic dispersion in these multi-tap filters can be reduced in an RoF link when a linearly chirped fiber Bragg grating (FBG) is adopted. This result can be used to combat radio frequency power fading in an RoF link. The configurations are free from optical coherent interference and phase noise. Measured results show 3-tap filters with notch rejections greater than 35 dB and suppression of the level of secondary sidelobes by adjusting a polarization controller. PACS 42.81.-I; 42.81.Gs; 07.50.Qx     

A Survey on Single-Valued Neutrosophic $K$-Algebras

In this survey, we first present a brief overview of logical algebras. We then discuss concepts of single-valued neutrosophic $K$-subalgebras, single-valued neutrosophic soft $K$-algebras and single-valued neutrosophic topological $K$-algebras. Moreover, we discuss various fundamental concepts which include interior, closure, $C{_5}$-connectivity, super connectivity, compactness and Hausdorffness of single-valued neutrosophic topological $K$-algebras.     

Correction of CT burst array errors in the generalized-lee-RT spaces

In [Jain, S.： Array codes in the generalized-Lee-RT-pseudo-metric （the GLRTP-metric）, to appear in Algebra Colloq.], Jain introduced a new pseudo-metric on the space Matm×s（Zq）, the module space of all m × s matrices with entries from the finite ring Zq, generalized the classical Lee metric [Lee, C. Y.： Some properties of non-binary error correcting codes. IEEE Trans. Inform. Theory, IT-4, 77- 82 （1958）] and array RT-metric [Rosenbloom, M. Y., Tsfasman, M. A.： Codes for m-metric. Prob. Inf. Transm., 33, 45-52 （1997）] and named this pseudo-metric as the Generalized-Lee-RT-Pseudo-Metric （or the GLRTP-Metric）. In this paper, we obtain some lower bounds for two-dimensional array codes correcting CT burst array errors [Jain, S.： CT bursts from classical to array coding. Discrete Math., 308-309, 1489-1499 （2008）] with weight constraints under the GLRTP-metric.     

Spin polarization dependent optical transition rates observed in the integer quantum Hall region

We report on a field-dependent photoluminescence (PL) emission rate for the transitions between band states in modulation-doped CdTe/Cd_1−xMg_xTe single quantum wells in the integer quantum Hall region. The recombination time observed for the magneto-PL spectra varies in concomitance with the integer quantum Hall plateaus. Furthermore, different PL decay times were observed for the two circular polarizations, i.e. for the transitions between the Zeeman split subbands of the Landau levels. We analyzed the data in comparison with the experimentally determined spin polarization of the conduction electrons and the Zeeman splitting of the valence band. Furthermore, we discuss the relevance of the spin polarization of the conduction electrons, the electron–hole exchange interaction and the spin-flip processes of the hole states for the PL decay time.     

Single SOA based all-optical adder assisted by optical bandpass filter: Theoretical analysis and performance optimization

A simple and compact configuration of all-optical adders implemented with a single semiconductor optical amplifier (SOA) and optical bandpass filter (OBF) is presented in this paper. A comprehensive SOA model is put forward to investigate the output characteristics of the all-optical adders. The numerical simulation results demonstrate the influence of these key parameters, including input pulse peak power, pulsewidth, repetition rate, and OBF characteristics. Moreover some design rules are extracted for the proper selection of these parameters so as to ensure optimum performance. The obtained results confirm the feasibility of our configuration.     

On solubility and supersolubility of some classes of finite groups

Let G be a finite group and H a subgroup of G. Then H is said to be S-permutable in G if HP = PH for all Sylow subgroups P of G. Let HsG be the subgroup of H generated by all those subgroups of H which are S-permutable in G. Then we say that H is S-embedded in G if G has a normal subgroup T and an S-permutable subgroup C such that T ∩ H HsG and HT = C. Our main result is the following Theorem A. A group G is supersoluble if and only if for every non-cyclic Sylow subgroup P of the generalized Fitting subgrou...     

Concentration-induced nonuniform power in tunable erbium-doped fiber lasers

We report, for the first time to our knowledge, the presence of concentration-induced nonuniform power in tunable erbium-doped fiber lasers. A theoretical model is proposed with pair-induced quenching taken into account. We obtain good agreement between numerical and experimental results of a high-concentration erbium-doped fiber ring laser with a large tuning range of over 100 nm. These findings are useful for the design of lasers with doped fibers.     

Resonance-temperature-insensitive phase-shifted long-period fiber gratings induced by surface deformation with anomalous strain characteristics

Received February 18, 2005 We report the fabrication of phase-shifted long-period fiber gratings by use of a CO2 laser with a surface deformation technique and a point-by-point method. Due to periodicities that are structurally induced by a heat source and refractive-index modulation caused by a perturbational photoelastic effect, the results of thermal testing show a grating temperature coefficient of 28 pm/ degrees C at a range from 22 to 180 degrees C, indicating that the band rejections of the grating that is formed remain unchanged in their resonant strengths even at temperatures up to the fictive point of fiberglass. It is found for what is believed to be the first time that such a grating possesses an anomalous strain behavior of resonance with -1.52 x 10(-4) dB/muepsilon for the right notch and 7.05 x 10(-5) dB/muepsilon for the left notch.