全文获取类型
收费全文 | 279篇 |
免费 | 10篇 |
国内免费 | 2篇 |
专业分类
化学 | 187篇 |
晶体学 | 1篇 |
力学 | 14篇 |
数学 | 31篇 |
物理学 | 58篇 |
出版年
2023年 | 5篇 |
2022年 | 7篇 |
2021年 | 4篇 |
2020年 | 8篇 |
2019年 | 3篇 |
2018年 | 7篇 |
2017年 | 5篇 |
2016年 | 14篇 |
2015年 | 7篇 |
2014年 | 16篇 |
2013年 | 15篇 |
2012年 | 19篇 |
2011年 | 33篇 |
2010年 | 12篇 |
2009年 | 7篇 |
2008年 | 8篇 |
2007年 | 21篇 |
2006年 | 12篇 |
2005年 | 8篇 |
2004年 | 10篇 |
2003年 | 4篇 |
2002年 | 2篇 |
2001年 | 10篇 |
2000年 | 5篇 |
1999年 | 5篇 |
1998年 | 5篇 |
1997年 | 4篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1985年 | 2篇 |
1982年 | 6篇 |
1981年 | 3篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1975年 | 3篇 |
1966年 | 1篇 |
1959年 | 1篇 |
1958年 | 1篇 |
排序方式: 共有291条查询结果,搜索用时 15 毫秒
21.
G. Venkatesh J. Thulasidhasan N. Rajendiran 《Journal of inclusion phenomena and macrocyclic chemistry》2014,78(1-4):225-237
The inclusion complexation behavior of orciprenaline (ORC) and terbutaline (TER) with α-CD, β-CD, HP-α-CD and HP-β-CD are examined by absorption, fluorescence, life time and molecular modeling methods. ORC and TER forms 1:1 (CD/drug) inclusion complexes in lower CD concentrations and 1:2 (CD/drug) inclusion complexes with higher CD concentrations. The inclusion of both drugs with HP-CDs was stronger than that of native CDs. Both drugs exhibit dual emission (excimer) in the CD solution, whereas in water single emission is seen. The hydrogen bonding and van der Waals interaction between the drugs and the CD plays an important role in the inclusion complexes. Computational results show the side chain of the drugs encapsulated in the CD cavity. The molecular modeling results by PM3 were in good agreement with the experimental results. 相似文献
22.
U. Pandey A. Mukherjee G. Samuel S. Banerjee H. D. Sarma M. Venkatesh 《Journal of Radioanalytical and Nuclear Chemistry》2008,275(2):243-246
Lanreotide, a somatostatin analogue, was radioiodinated with 125I to explore the possibility of using 123I labeled lanreotide as a diagnostic radiopharmaceutical for tumors overexpressing somatostatin (SST) receptors. Radioiodination
was carried out with 125I using chloramine T as the oxidant. The labeling yield was >90%. Characterization of 125I-Lanreotide was carried out by paper electrophoresis as well as HPLC. 125I-Lanreotide was purified by chromatography using a C18 Sep-Pak column. Radiochemical purity of the purified 125I-Lanreotide thus obtained was >99%. Significant tumor uptake of 125I-Lanreotide was observed in C57BL/6 mice bearing melanoma. 相似文献
23.
This paper is mainly concerned with elastic and acoustic properties of vitrous silica besides the computation of phonon frequencies.
Thus the phonon frequencies of vitrous silica have been calculated assuming the electronic bulk modulus,K
e, as equal to zero. New equations have been derived to relate the pressure derivatives of second order elastic constants to
the acoustic Gruneisen’s parameters using both Bhatia-Singh’s parameters and Schofield’s equations. The calculated longitudinal
and transverse Gruneisen’s parameters and the predicted absorption band spectra from Nagendranath’s equation and Bhatia Singh’s
parameters are in good agreement with experiment. The calculated mean acoustic mode Gruneisen’s parameter evaluated from the
pressure derivative of Nagendranath’s equation is also in good agreement with experiment.
An erratum to this article is available at . 相似文献
24.
25.
Venkatapuram Padmavathi Sanapalli Nagi Reddy Guda Dinneswara Reddy Bhumireddy Chinnachennaiahgari Venkatesh Adivireddy Padmaja 《Journal of heterocyclic chemistry》2011,48(5):1197-1201
A new class of bis heterocycles—sulfone linked pyrazolyl oxadiazoles thiadiazoles were prepared from E‐phenylsulfonylethenesulfonylacetic acid and studied their antimicrobial activities. J. Heterocyclic Chem., (2011). 相似文献
26.
Anodic dissolution of copper in glycine solution at various hydrogen peroxide concentrations was investigated. The dissolution
rate increases, reaches a maximum, and then decreases with hydrogen peroxide concentration. Anodic polarization studies and
electrochemical impedance spectroscopy (EIS) studies were carried out to determine the mechanistic pathway of anodic dissolution
of copper in glycine system at three different hydrogen peroxide concentrations: one at low hydrogen peroxide concentration
in the active dissolution region, another in the maximum dissolution region, and the third at the high hydrogen peroxide concentration
in the post-peak-dissolution region. The EIS data in complex plane plots show presence of two capacitance loops and one negative
capacitance loop. The impedance plot patterns strongly depend on the hydrogen peroxide concentration in solution. Reaction
mechanism analysis technique was employed to model the EIS data. A three-step mechanism with two intermediate adsorbates and
a parallel dissolution by catalytic mechanism simulates EIS patterns which match the experimental trends. The intermediates
are likely to be cupric and cuprous oxides. The essential features of impedance spectra at various overpotentials at three
different hydrogen peroxide concentrations are captured by the proposed mechanism. The results also show that the film present
on the copper surface in glycine and hydrogen peroxide solutions does not passivate the surface. 相似文献
27.
We prove a local-global principle for the problem of representations of quadratic forms by quadratic forms over ℤ, in codimension
≥5. The proof uses the ergodic theory of p-adic groups, together with a fairly general observation on the structure of orbits of an arithmetic group acting on integral
points of a variety. 相似文献
28.
Venkatesh Vasudevan Robert D. Cook Ronald K. Hanson Craig T. Bowman David M. Golden 《国际化学动力学杂志》2008,40(8):488-495
The reaction between methyl and hydroxyl radicals has been studied in reflected shock wave experiments using narrow‐linewidth OH laser absorption. OH radicals were generated by the rapid thermal decomposition of tert‐butyl hydroperoxide. Two different species were used as CH3 radical precursors, azomethane and methyl iodide. The overall rate coefficient of the CH3 + OH reaction was determined in the temperature range 1081–1426 K under conditions of chemical isolation. The experimental data are in good agreement with a recent theoretical study of the reaction. The decomposition of methanol to methyl and OH radicals was also investigated behind reflected shock waves. The current measurements are in good agreement with a recent experimental study and a master equation simulation. © 2008 Wiley Periodicals, Inc. 40: 488–495, 2008 相似文献
29.
R. Renganath Rao M. Vimudha N. R. Kamini M. K. Gowthaman B. Chandrasekran P. Saravanan 《Applied biochemistry and biotechnology》2017,182(2):511-528
Enzyme-based unhairing in replacement of conventional lime sulfide system has been attempted as an alternative for tackling pollution. The exorbitant cost of enzyme and the need for stringent process control need to be addressed yet. This study developed a mechanism for regulated release of protease from cheaper agro-wastes, which overcomes the necessity for stringent process control along with total cost reduction. The maximum protease activity of 1193.77 U/g was obtained after 96 h of incubation with 15% inoculum of the actinomycete strain Brevibacterium luteolum (MTCC 5982) under solid-state fermentation (SSF). The medium after SSF was used for unhairing without the downstream processing to avoid the cost involved in enzyme extraction. This also helped in the regulated release of enzyme from bran to the process liquor for controlled unhairing and avoided the problem of grain-pitting. Unhairing process parameters were standardized as 20% enzyme offer, 40% Hide-Float ratio at 5 ± 1 rpm, and process pH of 9.0. The cost of production of 1000 kU of the protease was calculated as 0.44 USD. The techno-economic feasibility studies for setting up an SSF enzyme production plant showed a high return on investment of 15.58% with a payback period of 6.4 years. 相似文献
30.
Spectral characteristics of 1-(2,4-diamino phenylazo) naphthalene (FBRR, fat brown RR) and 4-aminoazobenzene (AAB) have been
studied in various solvents, varying hydrogen ion concentrations and in β-cyclodextrin (β-CD). The inclusion complex of FBRR
and AAB with β-CD were analysed by UV-visible, fluorometry and CAche-DFT methods. Solvent study reveals that only azo tautomer
is present in both compounds and the large red shifted absorption and emission maxima of FBRR indicate naphthalene ring effectively
increases the π-π* transition. Unusual red shift is observed in acid solutions suggests azonium-ammonium tautomer is present
in both molecules. In β-CD solutions, the large hypsochromic shift is observed in S0 and S1 states indicates ortho amino group of FBRR molecule is entrapped in the β-CD cavity and the large bathochromic shift for AAB in the S1 state indicates 1:1 inclusion complex is formed. 相似文献