2-氰基苄基诱导的葡萄糖醛酸β糖苷键立体选择性

以2,3-O-(2-氰基苄基)-4-O-氯乙酰基-β-对甲基苯基-D-葡萄糖醛酸硫苷等7个单糖模块作为糖基供体, 以甲醇等醇类化合物作为糖基受体, 分别在二氯甲烷和甲苯溶剂中进行了糖基化反应, 研究了葡萄糖醛酸C2位引入2-氰基苄基(BCN)以及溶剂效应对糖苷键α/β选择性的影响. 通过对糖基产物的 ¹H NMR, ¹³C NMR和HSQC等谱图分析发现, BCN可以有效提高糖苷键的β选择性, 其中部分糖基化产物的糖苷键α/β比例最高可达1/50. 为磺达肝癸钠分子中葡萄糖醛酸的β糖苷键的构建方法做出了初步探索.     

复Banach空间单位球上几类映射的增长掩盖定理

对α次的殆β型螺形映射,α次的β型螺形映射和α次的强β型螺形映射,给出了定义,并且在复Banach空间中的单位球上分别得到它们的增长掩盖定理．     

金纳米棒的生长及与FeCl_3的作用

采用三氯化铁选择性刻蚀法获得了预定长径比的金纳米棒.相比于晶种生长法,三氯化铁选择性刻蚀法可以更加简便快捷地调控金纳米棒形貌.以三氯化铁为刻蚀剂的刻蚀反应优先发生在金纳米棒尖端,这是因为金纳米棒尖端反应活性更高且表面活性剂钝化作用更弱.通过控制刻蚀反应时间及刻蚀剂浓度,可以精确调控金纳米棒的长径比.实验结果表明,增加刻蚀剂浓度、卤素离子浓度以及升高反应温度可以加快刻蚀反应速率.进一步讨论了金属离子的刻蚀作用机理.     

An adapted isotope dilution 1H–13C heteronuclear single-quantum correlation (ID-HSQC) for rapid and accurate quantification of endogenous and exogenous plasma glucose

Analytical and Bioanalytical Chemistry - A wide variety of methods, such as enzymatic methods, LC-MS, and LC-MS/MS, are currently available for the concentration determination of plasma glucose in...     

Incorporating Transition-Metal Phosphides Into Metal-Organic Frameworks for Enhanced Photocatalysis

Metal-organic frameworks (MOFs) have been shown to be an excellent platform in photocatalysis. However, to suppress electron–hole recombination, a Pt cocatalyst is usually inevitable, especially in photocatalytic H₂ production, which greatly limits practical application. Herein, for the first time, monodisperse, small-size, and noble-metal-free transitional-metal phosphides (TMPs; for example, Ni₂P, Ni₁₂P₅), are incorporated into a representative MOF, UiO-66-NH₂, for photocatalytic H₂ production. Compared with the parent MOF and their physical mixture, both TMPs@MOF composites display significantly improved H₂ production rates. Thermodynamic and kinetic studies reveal that TMPs, behaving similar ability to Pt, greatly accelerate the linker-to-cluster charge transfer, promote charge separation, and reduce the activation energy of H₂ production. Significantly, the results indicate that Pt is thermodynamically favorable, yet Ni₂P is kinetically preferred for H₂ production, accounting for the higher activity of Ni₂P@UiO-66-NH₂ than Pt@UiO-66-NH₂.     

Probing molecular orientation at bulk heterojunctions by polarization-selective transient absorption spectroscopy

A bulk heterojunction in organic solar cells is where charge separation and recombination occur. Molecular orientation at the interface is one of the key factors that dictate solar cell efficiency. Although X–ray scattering-based methods can determine donor/acceptor domain orientations between an anisotropic phase and an isotropic fullerene-based phase, the rise of nonfullerene solar cells presents a new challenge in delineating local molecular directions at the interface between two anisotropic donor/acceptor domains. Here, we determine interfacial molecular orientations of three high-efficiency small molecule solar cells(ZR1:Y6, B1:BO–4 Cl, and BTR:BO–4 Cl) using polarization-selective transient absorption spectroscopy. The polarization anisotropy of charge separation dynamics indicates an angle of ～90° between ZR1 and Y6 molecules at the interface, an angle close to 0° between B1 and BO–4 Cl, and random orientations between BTR and BO–4 Cl. These observations provide complementary information to X–ray scattering measurements and highlight polarization-selective transient absorption spectroscopy as a tool to probe interfacial structure and dynamics of key photophysical steps in energy conversion.     

Thermal design and simulation of space-borne membrane antenna

Thermal deformation of space-borne radar antenna caused by dramatic changes in orbit thermal environment has a serious effect on image qualities. In this paper, the NX TMG module was used to simulate the orbit thermal environment of the antenna, and a thermal control design was proposed. The thermal control structure consists of three layers; the top is a radiator with high emissivity surface, the middle is a multi-layer insulation, and the bottom is a highly reflective layer. The simulation results show that the thermal design could reduce the temperature gradient from 238.1 to 31.4 °C effectively.

     

Gallium Oxide Nanorods: Novel,Template‐Free Synthesis and High Catalytic Activity in Epoxidation Reactions

Gallium oxide nanorods with unprecedented small dimensions (20–80 nm length and 3–5 nm width) were prepared using a novel, template‐free synthesis method. This nanomaterial is an excellent heterogeneous catalyst for the sustainable epoxidation of alkenes with H₂O₂, rivaling the industrial benchmark microporous titanosilicate TS‐1 with linear alkenes and being much superior with bulkier substrates. A thorough characterization study elucidated the correlation between the physicochemical properties of the gallium oxide nanorods and their catalytic performance, and underlined the importance of the nanorod morphology for generating a material with high specific surface area and a high number of accessible acid sites.     

Homogeneous and stable carbon nanotube dispersion assisted by cellulose in NaOH/thiourea aqueous solution

Cellulose - Carbon nanotubes (CNTs) have been proposed as next-generation lightweight structural materials, yet their application is facing challenges due to the poor dispersity in most solvents,...     

TDDFT investigation on electronically excited-state hydrogen-bonding properties and ESIPT mechanism for the 2-(1H-imidazol-2-yl)-phenol compound

Structural Chemistry - In this work, DFT and TDDFT approaches have been executed to make a detailed exploration about the excited state luminescent properties as well as excited state...