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151.
H. Dijkstra R. Bailey E. Belau T. Böhringer M. Bosman V. Chabaud C. Damerell C. Daum G. de Rijk S. Gill A. Gillman R. Gilmore Z. Hajduk C. Hardwick W. Hoogland B. D. Hyams R. Klanner S. Kwan U. Kötz G. Lütjens G. Lutz J. Malos W. Männer E. Neugebauer H. Palka M. Pepé J. Richardson K. Rybicki H. J. Seebrunner U. Stierlin R. J. Tapper H. G. Tiecke M. Turala G. Waltermann S. Watts P. Weilhammer F. Wickens L. W. Wiggers A. Wylie T. Zeludziewicz ACCMOR Collaboration 《Zeitschrift fur Physik C Particles and Fields》1986,32(3):353-358
The joint production of ? mesons andπ ±,π 0,p, \(\bar p\) ,K s 0 andK ± is investigated using a sample of 600,000 inclusive ? meson events obtained in hadron Be interactions with incidentπ ±,p, \(\bar p\) andK ± beams. Evidence is presented for the joint production of ? mesons and strange particles produced with non-strange incident beams. With incidentK ± beam the number of additional strange particles is suppressed. The results are found to be in agreement with the qualitative predictions of a parton fusion model. The comparison with the Lund model for lowp T processes is fair. 相似文献
152.
We have investigated the suitability of poly-(alkyl--cyanoacrylates) (p-(alkyl-CAc)) for two-photon four-level holographic recording. It is shown that these materials follow indeed a two-photon four-level mechanism with the second absorption step in the near infrared. Light induces the polymerization of residual monomer in the matrix. The reaction is associated with positive density changes. The sensitivity ofp-(alkyl-CAc) depends strongly on composition and age of the sample. Maximum sensitivities achieved are comparable to the so far best-known two-photon four-level ir-sensitive systems. 相似文献
153.
H. Müller 《Theoretical chemistry accounts》1971,21(1):110-114
The linear ions Br
4
2–
which has been discovered for the first time by Siepmann and Schnering [13] in W6Br16 have been studied theoretically using the free electron model for the valence electrons. Electronic structure, binding energy and charge distribution show that Br
4
2–
is a typical electron deficient compound stabilized by a 4c-6e bond.
Herrn Prof. Dr. H. Dunken bin ich für sein stetes Interesse und die rege Anteilnahme an diesen Modellrechnungen zu großem Dank verpflichtet. 相似文献
Herrn Prof. Dr. H. Dunken bin ich für sein stetes Interesse und die rege Anteilnahme an diesen Modellrechnungen zu großem Dank verpflichtet. 相似文献
154.
The quantum efficiency of photooxidation of a number of xanthene dyes at ZnO single crystal electrodes has been found to depend on the solution concentration of a triplet quenching agent, FeCN4?6, providing evidence for triplet state participation in the oxidation reaction. 相似文献
155.
2-Deoxy-2-[18F]fluoro-D-glucose ([18F] FDG), the most popular positron emitting radiopharmaceutical, may oxidise by autoradiolysis in aqueous solution. The aim of this work was to use LC-MS for determination of the oxidation products of fluorodeoxyglucose and glucose (Glc) obtained by oxidation with Fenton's reagent. Asahipak NH2P-50 polyamide silica column and acetonitrile-0.025% aqueous ammonium formate (80:20 (v/v)) eluent were utilised with an Agilent 1100 HPLC-MS instrument. Ten major oxidation products of FDG and Glc were separated and identified by mass spectrometry: 2-fluorogluconic acid, 2-fluoroglucuronic acid, 2-oxoerythronic acid, arabinose, arabonic acid, araburonic acid, erythrose, erythrulose, gluconic acid, and glucuronic acid. The most intensive electrospray ionisation signals were found in the negative ion spectra and were due to HCOO- adducts, the other acids being in their lactone forms. 相似文献
156.
The hydrogenation of unsaturated organic substrates such as olefins and ketones is usually effected by homogeneous or heterogeneous transition-metal catalysts. On the other hand, a single case of a transition-metal-free and purely base-catalyzed hydrogenation of ketones was reported by Walling and Bollyky some 40 years ago. Unfortunately, the harsh reaction conditions (ca. 200 degrees C, >100 bar H(2), potassium tert-butoxide as base) limit the substrate spectrum of this reaction to robust, nonenolizable ketones such as benzophenone. We herein present a mechanistic study of this process as a basis for future rational improvement. The base-catalyzed hydrogenation of ketones was found to be irreversible, and it shows first-order kinetics with respect to the substrate ketone, hydrogen, and catalytic base. The rate of the reaction depends on the type of alkali ion present (Cs > Rb - K > Na > Li). Using D(2) instead of H(2) revealed a rapid base-catalyzed isotope exchange/equilibration between the gas phase and the solvent as a concomitant reaction. The degree of deuteration of the product alcohols did not indicate a significant kinetic isotope effect. It is proposed that both ketone reduction and isotope exchange proceed via similar six-membered cyclic transition states involving the H(2)(D(2))-molecule, the alkoxide base, and the ketone (solvent alcohol in the case of isotope exchange). Mechanistic analogies are pointed out which apparently exist between the base-catalyzed hydrogenation of ketones studied here and the Ru-catalyzed asymmetric ketone hydrogenation developed by Noyori. In both cases, heterolysis of the hydrogen molecule appears to be assisted by a Br?nsted-base (i.e., alkoxide), the latter being bound to the substrate ketone or the catalyst ligand, respectively, by a bridging Lewis-acidic alkali ion. 相似文献
157.
K. Müller R. Henkelmann J. P. Biersack P. Mertens 《Journal of Radioanalytical and Nuclear Chemistry》1977,38(1-2):9-17
The isotopes3He,6Li,7Be and10B exhibit extremely large cross sections, between 1 and 48 kilobarn, for (n, p) or (n, α) reactions with thermal neutrons.
Together with now available extracted thermal neutron fluxes of 10( n·cm−2·sec−1 or more, these reactions present a highly sensitive method of detecting the mentioned light elements in any heavy matrix
material. Through the experimentally determined energy losses of the emitted protons or α-particles, also well resolved depth
profiles can be obtained, as demonstrated here for some relevant examples from semiconductor and fusion technology. 相似文献
158.
Günter Haufe Manfred Mühlstädt Dr. Jürgen Graefe 《Monatshefte für Chemie / Chemical Monthly》1977,108(4):803-811
In addition totrans-2-bromocyclooctanol andtrans-1,2-dibromocyclooctane,cis-4-bromocyclooctanol,cis-1,4-dibromocyclooctane,trans-1,4-dibromocyclooctane, and (Z)-5-bromocyclooctene are obtained, when (Z)-cyclooctene is treated with N-bromosuccinimide in the presence of water. Similarly the methoxybromination of (Z)-cyclooctene gives transanular products. 相似文献
159.
The effect of substituted hydroxybenzophenone, benzotriazole and organic metal complexes on the photooxidation of PP films has been studied. It has been established that NiDBTC added in 1.0 wt. % is the most effective photostabilizer.While in the case of other stabilizers there is a slight increase in the Co content even during the induction period, with the application of NiDBTC practically no oxidation can be observed before the stabilizer completely disappears. This means that NiDBTC inhibits the photooxidation of the polymer even in low concentration.
, - . , Ni, 1,0 . %. . , Ni , . , Ni .相似文献
160.
Türkan Gürkan 《Mikrochimica acta》1976,65(2-3):165-171
Summary The condensation products of 4 sympathomimetic amines with 1,2-naphthoquinone-4-sulphonic acid have been prepared and examined. A spectrophotometric procedure based on the chloroform-soluble orange-red condensation product is described. The same products were investigated fluorimetrically after reduction with sodium borohydride. The results obtained are satisfactory.
Zusammenfassung Die Kondensationsprodukte vier sympathicomimetischer Amine mit 1,2-Naphthochinon-4-sulfonsäure wurden dargestellt und untersucht. Ein spektralphotometrisches Verfahren auf der Grundlage des chloroformlöslichen, orangeroten Kondensationsproduktes wurde beschrieben. Die gleichen Produkte wurden auch fluoreszenzanalytisch nach ihrer Reduktion mit Natriumborhydrid untersucht. Die Ergebnisse sind befriedigend.相似文献