首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   300113篇
  免费   1976篇
  国内免费   525篇
化学   143597篇
晶体学   5020篇
力学   14851篇
综合类   12篇
数学   43455篇
物理学   95679篇
  2020年   1748篇
  2019年   1952篇
  2018年   10858篇
  2017年   11738篇
  2016年   7529篇
  2015年   3067篇
  2014年   3738篇
  2013年   9271篇
  2012年   10812篇
  2011年   20349篇
  2010年   12718篇
  2009年   12799篇
  2008年   17564篇
  2007年   21051篇
  2006年   6941篇
  2005年   12790篇
  2004年   8942篇
  2003年   8476篇
  2002年   6312篇
  2001年   6334篇
  2000年   4964篇
  1999年   3590篇
  1998年   2814篇
  1997年   2749篇
  1996年   2773篇
  1995年   2553篇
  1994年   2439篇
  1993年   2262篇
  1992年   2917篇
  1991年   2814篇
  1990年   2765篇
  1989年   2793篇
  1988年   2816篇
  1987年   2823篇
  1986年   2691篇
  1985年   3403篇
  1984年   3435篇
  1983年   2723篇
  1982年   2817篇
  1981年   2867篇
  1980年   2642篇
  1979年   2999篇
  1978年   2991篇
  1977年   3028篇
  1976年   2900篇
  1975年   2633篇
  1974年   2577篇
  1973年   2577篇
  1972年   1762篇
  1968年   1806篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
101.
    
The diversity of products in the reaction of diethyl azodicarboxylate (DEAD)/diisopropyl azodicarboxylate (DIAD) and activated acetylenes with PIII compounds bearing oxygen or nitrogen substituents is discussed. New findings that are useful in understanding the nature of intermediates involved in the Mitsunobu reaction are highlighted. X-ray structures of two new compounds (2-t-Bu-4-MeC6H3O)P (μ-N-t-Bu)2P+[(NH-t-Bu)N[(CO2]-i-Pr)(HNCO2-i-Pr)]](Cl-)(2-t-Bu-4-MeC6H3OH)(23)and [CH2(6-t-Bu-4-Me-C6H2O)2P(O)C(CO2Me)C-(CO2Me)CClNC(O)Cl] (33) are also reported. The structure of23 is close to one of the intermediates proposed in the Mitsunobu reaction.  相似文献   
102.
103.
The stress-strain state in the zone of load transfer in a uniaxially stretched specimen made of a unidirectional epoxy carbon-fiber-reinforced plastic (CFRP) is investigated. A parametric analysis of the influence of geometric and mechanical characteristics of the specimen on its stress-strain state is performed by means of finite-element modeling. The parameters allowing us to significantly reduce the dangerous concentration of transverse and tangential stresses are revealed. The mechanical tensile characteristics of a high-strength pultruded unidirectional CFRP are determined experimentally, and the size effect of its strength is estimated.  相似文献   
104.
A nonlinear (in the cubic approximation) relaxation equation of state is derived for a rod containing cracks partially filled with an incompressible viscous liquid. The nonlinear effects of the self-action and interaction of low-and high-frequency longitudinal elastic waves propagating in such a rod are studied for the cases of identical and size-varied cracks. Linear and nonlinear acoustic parameters characterizing the self-action and interaction of elastic waves in a cracked rod are determined.  相似文献   
105.
We study the relation between the cohomology of general linear and symmetric groups and their respective quantizations, using Schur algebras and standard homological techniques to build appropriate spectral sequences. As our methods fit inside a much more general context within the theory of finite-dimensional algebras, we develop our results first in that general setting, and then specialize to the above situations. From this we obtain new proofs of several known results in modular representation theory of symmetric groups. Moreover, we reduce certain questions about computing extensions for symmetric groups and Hecke algebras to questions about extensions for general linear groups and their quantizations.  相似文献   
106.
The dynamics of the photoinduced differential absorption and excited-state bleaching spectra of single-walled carbon nanotubes suspended in a micellar solution were studied in the spectral range from 40 to 1000 nm within a time interval from 70 fs to 150 ps under excitation by 50-fs pulses with photon energies 2 and 4 eV. The bleaching and absorption bands were observed in the spectra; the positions of the bleaching peaks were independent of the photon energy of the exciting femtosecond pulse in the range 2–4 eV. It was established that, for delay times shorter than 1 ps, the shape of the differential spectrum of excited nanotubes coincided with the shape of the second derivative of the absorption spectrum of unexcited nanotubes in the frequency range of exciting pulse above 18000 cm?1 (the range of absorption bands of metallic nanotubes). In the frequency range below 16000 cm?1 (the range of absorption peaks of semiconducting nanotubes), the bleaching peaks in the differential spectrum of excited nanotubes undergo a high-frequency shift of 200–300 cm?1 with respect to the second-derivative spectrum of unexcited nanotubes. The excited-state relaxation rate constants were measured. They are well approximated by the exponential dependences and depend on the probe-pulse wavelength. An assumption was made about the nature of the observed spectra of excited nanotubes and about the excitation relaxation.  相似文献   
107.
Photorefractive scattering occurs in rhodium-doped lithium niobate crystals irradiated by coherent light. The photorefractive scattering has both wide-angle and selective components. The results of experimental investigation of selective photorefractive scattering in LiNbO3:Rh crystals and calculation of the spatial structure of scattering are reported. The selective scattering is regarded as a kind of a frequency-degenerate fourwave vector interaction.  相似文献   
108.
In order to study the influence of seeded impurities on ITER like reactor operation the COREDIV code has been extended to include the transport of several sputtered and/or injected impurities. In the COREDIV code the core plasma is treated in the frame of 1D radial transport model whereas in the edge the 2D multifluid code EPIT is used. The EPIT code solves in the slab geometry the MHD equations for densities and velocities for all ions species as well as for electron and ion temperatures. The iteration scheme in the code leads to steady state solution of coupled core and SOL system. The numerical results for Carbon and Nickel plate and seeded impurities Silicon and Neon are presented.  相似文献   
109.
Glazebrook  K.D.  Lumley  R.R.  Ansell  P.S. 《Queueing Systems》2003,45(2):81-111
We consider the optimal service control of a multiclass M/G/1 queueing system in which customers are served nonpreemptively and the system cost rate is additive across classes and increasing convex in the numbers present in each class. Following Whittle's approach to a class of restless bandit problems, we develop a Langrangian relaxation of the service control problem which serves to motivate the development of a class of index heuristics. The index for a particular customer class is characterised as a fair charge for service of that class. The paper develops these indices and reports an extensive numerical investigation which exhibits strong performance of the index heuristics for both discounted and average costs.  相似文献   
110.
This paper deals with a singular perturbation of the stationary Stokes and Navier-Stokes systems. The term ε2Δp is added to the continuity equation, where ε is a small parameter. For a domain with cylindrical outlets to infinity and exponentially decaying data, existence and uniqueness of solutions under flux conditions at infinity are established for the linear problem and also for the nonlinear problem in the case of small data. Asymptotically exact estimates are proved for ε tending to zero. For sufficiently regular data, these estimates imply the convergence in H loc 5/2−δ for the velocity parts and in H loc 3/2−δ for the pressure parts, respectively. Bibliography: 17 titles.Dedicated to V. A. Solonnikov on the occasion of his 70th birthday__________Published in Zapiski Nauchnykh Seminarov POMI, Vol. 306, 2003, pp. 107–133.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号