正交信号校正用于傅里叶变换红外光谱的模型传递

利用正交信号校正（OSC）实现了4组分气体混合物的PLS模型,在两台傅里叶变换红外光谱（FTIR）仪上的传递,并与直接标准化（DS）、分段直接标准化（PDS）、多元分散校正（MSC）和有限脉冲响应（FIR）的传递效果进行了比较,确立了以源机的校正模型直接对目标机数据进行预测的传递方式。经过OSC校正,预测均方根误差（RMSEP）为10^-3左右。OSC可以有效地减小测量仪器间的差异,同时使PLS模型的潜变量个数降为4,使模型简单化。与DS和PDS相比,OSC不需要同一样品在两台仪器上测量,在支集大小为3时,得到一致的预测准确度,表现出稳健性。MSC和FIR处理的RMSEP为10^-1左右,效果远差于OSC。     

Field Extension of Real Values of Physical Observables in Classical Theory can Help Attain Quantum Results

Physical quantities are assumed to take real values, which stems from the fact that an usual measuring instrument that measures a physical observable always yields a real number. Here we consider the question of what would happen if physical observables are allowed to assume complex values. In this paper, we show that by allowing observables in the Bell inequality to take complex values, a classical physical theory can actually get the same upper bound of the Bell expression as quantum theory. Also, by extending the real field to the quaternionic field, we can puzzle out the GHZ problem using local hidden variable model. Furthermore, we try to build a new type of hidden-variable theory of a single qubit based on the result.     

梯度液相色谱中任意等度、线性和阶梯梯度组合下的保留时间公式

基于线性溶剂强度模型,应用特征线分析的方法求解梯度洗脱模式下的理想液相色谱模型。在考虑到梯度延迟时间会对溶质的保留时间造成影响的情况下,得到适合于梯度液相色谱中任意等度、线性和阶梯梯度组合条件下的保留时间推导公式。应用这些公式计算任意的梯度条件下的保留时间,并将得到的结果与数值计f算的结果进行比较,二者完全一致,从而验证了推导得到的保留时间公式的正确性。由于这些公式具有形式简单、适用范围广等优点,因此可方便地应用于实际应用中,具有较高的实用价值。     

Analysis of trace components in gases by gas chromatography

Summary Relationships are derived describing how the detection limit of a chromatographic system depends on the minimum detectable limit of the detector and the chromatographic parameters such as column length, efficiency, carrier gas flow rate and the capacity factor. Performance data of detectors developed in the last 25 years at the Dalian Institute of Chemical Physics of the Chinese Academy of Sciences are given and a few selected application examples are listed. These include trace analysis by preconcentration and by direct analysis and the utilization of multidimensional gas chromatography with two columns, two detectors, a 12-port valve, and a catalytic conversion reactor.     

On Antosik's Lemma and the Antosik-Mikusinski Basic Matrix Theorem

That Antosik's Lemma is not a special case of the Antosik-Mikusinski Basic Matrix Theorem will be shown and, an equivalent form of the Antosik-Mikusinski Basic Matrix Theorem will also be presented in this paper.

     

Absolute Continuity of Vitali–Hahn–Saks Measure Convergence Theorems

In this paper, we prove the following improved Vitali–Hahn–Saks measure convergence theorem: Let (L, 0, 1) be a Boolean algebra with the sequential completeness property, (G, ) be an Abelian topological group, be a nonnegative finitely additive measure defined on L, {_n: n N} be a sequence of finitely additive s-bounded G-valued measures defined on L, too. If for each a L, {_n(a)}_{n N} is a -convergent sequence, for each nN, when { (a)} convergent to 0, {_n(a)} is -convergent, then when { (a)} convergent to 0, {_n(a)} are -convergent uniformly with respect to nN     

Quantum-Logics-Valued Measure Convergence Theorem

In this paper, the following quantum-logic valued measure convergence theorem is proved: Let (L ₁, 0, 1) be a Boolean algebra, (L ₂, , , 0, 1) be a quantum logic and { _n : n N} be a sequence of s-bounded (L ₂, , , 0, 1)-valued measures which are defined on (L ₁, 0, 1). If for each a (L ₁, 0, 1), { _n (a)} _{n N} is an order topology Cauchy sequence, when {v(a)} convergent to 0, { _n (a)} is order topology convergent to 0 for each n N, where v is a nonnegative finite additive measure which is defined on (L ₁, 0, 1), then when {v(a)} convergent to 0, { _n (a)} are order topology convergent to 0 uniformly with respect to n N.     

非火药驱动的二级轻气炮的发射参数分

介绍了一台５７ｍｍ口径一级压缩气炮驱动的１０ｍｍ口径二级轻气炮，并分析了这种气炮的特点。对其发射参数和发射效果之间的关系进行了数值计算模拟，计算弹速与实测弹速的差异小于１０％。根据计算模拟结果，分析了活塞质量、活塞驱动气压、泵管初充气压和弹丸释放气压等发射参量同弹速和二级气室的气压气温峰值的关系，评估了１０／５７二级轻气炮的发射能力。     

A new membrane inlet interface of a vacuum ultraviolet lamp ionization miniature mass spectrometer for on-line rapid measurement of volatile organic compounds in air

A novel membrane inlet interface coupled to a single-photon ionization (SPI) miniature time-of-flight mass spectrometer has been developed for on-line rapid measurement of volatile organic compounds (VOCs). The vacuum ultraviolet (VUV) light source for SPI was a commercial krypton discharge lamp with photon energy of 10.6 eV and photon flux of 10(10) photons/s. The experimental results showed that the sensitivity was 5 times as high as obtained with the traditional membrane inlet. The enrichment efficiency could be adjusted in the range of 10 to 20 times for different VOCs when a buffer cell was added to the inlet interface, and the memory effect was effectively eliminated. A detection limit as low as 25 parts-per-billion by volume (ppbv) for benzene has been achieved, with a linear dynamic range of three orders of magnitude. The rise times were 6 s, 10 s and 15 s for benzene, toluene and p-xylene, respectively, and the fall time was only 6 s for all of these compounds. The analytical capacity of this system was demonstrated by the on-line analysis of VOCs in single puff mainstream cigarette smoke, in which more than 50 compounds were detected in 2 s.     

一种新型光电离/微型正交加速飞行时间质谱仪的设计和性能测试

介绍了自行研制的光电离/微型正交加速飞行时间质谱仪的设计原理和性能。电离源采用光子能量为10.6 eV真空紫外灯,它可将待测分子电离只产生单电荷母体离子,不产生碎片离子。采用该光电离方法得到的质谱谱图比较简单,气体样品可以不经分离直接进行分析。离子正交引入结构的飞行时间质量分析器有效地提高了质谱分辨率。用32 cm无场飞行管,测量碘甲烷得到的质谱分辨率可达430。在谱图获得频率10 kHz的操作条件下,样品总分析时间20 s,得到苯和碘甲烷的检出限分别为10×10-6,5×10-6。软电离和微型化使得该质谱仪在可挥发性有机物的实时在线监测方面有广泛的应用。