Quantum Dynamics of Oxyhydrogen Complex-Forming Reactions for the HO2 and HO3 Systems

Complex-forming reactions widely exist in gas-phase chemical reactions.Various complexforming bimolecular reactions have been investigated and interesting phenomena have been discovered.The complex-forming reactions usually have small or no barrier in the entrance channel, which leads to obvious differences in kinetic and dynamic characteristics compared with direct reactions.Theoretically, quantum state-resolved reaction dynamics can provide the most detailed microscopic dynamic mechanisms and is now feasible for a direct reaction with only one potential barrier.However, it is of great challenge to construct accurate potential energy surfaces and perform accurate quantum dynamics calculations for a complex polyatomic reaction involving deep potential wells and multi-channels.This paper reviews the most recent progress in two prototypical oxyhydrogen complex-forming reaction systems, HO₂ and HO₃, which are significant in combustion, atmospheric, and interstellar chemistry.We will present a brief survey of both computational and experimental work and emphasize on some unsolved problems existing in these systems.     

基于扩散函数的内集-外集模型

内集-外集模型用于计算小样本事件的可能性-概率分布(PPD),以表达概率估计的模糊性。基于分配函数的内集-外集模型存在三点不足:①论域步长的选取随意性太大;②PPD值在0.5到1之间无值;③信息过于集中,PPD值在很多区间值为0。本文从解决此三问题入手,对传统模型进行了改进。首先讨论了论域步长选取的合理性问题;其次引入扩散函数替换分配函数,同时解决了问题②和③;最后,仿真实验的结果显示,改进模型的估计比传统模型的估计更接近于真实分布。     

头孢吡肟的合成进展

介绍了第四代抗生素头孢菌素头孢吡肟的各种合成方法,并评价了各种方法的优点和缺点。参考文献26篇。     

Enhanced vacuum Rabi splitting and double dark states in a composite atom-cavity system

The transmission spectrum of four-level atoms in a cavity is calculated. It is shown that the four separate peaks associated with normal mode splitting and intra-cavity double dark states can be observed simultaneously. The position and intensity of the four peaks can be controlled by the intensity of the third interacting light. Therefore, the enhancement of normal mode splitting by a third coupling light of the intra-cavity four-level atoms is developed.      

Recovery of PET-quenched fluorescent conjugated polymers with aza-15-crown-5 as pendant groups on interaction with ions

Novel conjugated polymers with aza-15-crown-5 as pendant groups, P1 were synthesized by the Sonogashira coupling reaction. The polymer P1 was found to show fluorescence en-hancement response towards Ba2＋. The gradual recovery and turning-point of emission intensity of polymers appeared in the addition of Ba2＋, which provided good evidence for the fluorescence amplification mechanism of conjugated polymers.     

连续变量量子纠缠态的非对称量子克隆

该文讨论了连续变量量子纠缠态非对称克隆过程,从理论上讨论了在Local e-cloner方案中,入射和出射分束器的反射率可变情况下的纠缠态克隆,并利用纠缠不可分判据分析了所获得的非对称克隆纠缠态的纠缠特性.结果指出,克隆得到的两组纠缠态的纠缠特性不相同.     

INTERFEROMETRIC DETECTION OF OPTICAL PHASE SHIFT USING TWIN BEAMS

An interferometric detection scheme to measure optical phase shift with sensi tivity beyond the shot noise limit is proposed. The theoretical calculation shows that using the quantum correlated twin beams produced from an optical parametric amplifier as the input fields of a Mach-Zehnder interferometer, the minimum detectable phase shift will exceed the shot noise limit N^-1/2 and approach the Heisenberg limit N^-1. The parametric dependences of the minimum detectable phase shift on the nonlinear interaction, input photon number, and detection efficiency are shown.     

泵浦谱宽和测量带宽对 SPDC过程产生的光子对分布的影响

分析了泵浦光的谱宽以及测量所选用的滤波器的带宽对下转换产生的信号光和闲置光分布范围影响.分别给出当泵浦为单色波和飞秒脉冲时下转换的分布范围和符合宽度范围.并将理论结果与飞秒脉冲泵浦的自发参量下转换(SPDC)实验进行了对比,理论与实验基本吻合.     

带有Neumann边界的方程组多个正解存在性

研究带有Neumann边界条件的拟线性方程组的正解问题.在不同参数条件下,主要利用特征值理论和Nehari流形给出了方程组正解的存在性和多解性.这一结论很好的推广了已有的结果.     

通过λ/2波片外腔同位相弱反馈实现激光二极管激光的强度噪声压缩

由于低温下单模半导体量子阱激光器与准直透镜出现双折射效应,导致输出光场偏振状态发生变化,使单个线偏模的光子数噪声增加.利用λ/4波片补偿双折射,同时采用λ/2波片前后表面的同位相余反射光完成对激光二极管激光器的弱反馈,在抽运电流为34.65mA时,获得压缩度为2.8dB,输出功率约24mW的光子数压缩光 关键词： 噪声压缩 弱反馈 反关联