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21.
R. Takke M. Niksch W. Assmus B. Lüthi R. Pott R. Schefzyk D. K. Wohlleben 《Zeitschrift für Physik B Condensed Matter》1981,44(1-2):33-39
We give experimental results of magnetic susceptibility, thermal expansion and elastic constant measurements for CeSn3 and CePd3. We interpret these results with a phenomenological scaling function for the free energy and we include a brief discussion of CeAl3. The coupling between the electronic system and the lattice can be described by an electronic Grüneisen parameter g associated with the unstable 4f system which turns out to become a system specific constant far below the fluctuation temperatureT
0. The coupling parameter T0g is an order of magnitude larger than the coupling constant for stable valentRE systems extracted from crystal field effects. A generalization to include magnetic field dependent effects is also given. 相似文献
22.
23.
Kritzer JA Tirado-Rives J Hart SA Lear JD Jorgensen WL Schepartz A 《Journal of the American Chemical Society》2005,127(1):167-178
Folded polymers are used in Nature for virtually every vital process. Nonnatural folded polymers, or foldamers, have the potential for similar versatility, and the design and refinement of such molecules is of considerable current interest. Here we report a complete and systematic analysis of the relationship between side chain structure and the 14-helicity of a well-studied class of foldamers, beta(3)-peptides, in water. Our experimental results (1) verify the importance of macrodipole stabilization for maintaining 14-helix structure, (2) provide comprehensive evidence that beta(3)-amino acids branched at the first side chain carbon are 14-helix-stabilizing, (3) suggest a novel role for side chain hydrogen bonding as an additional stabilizing force in beta(3)-peptides containing beta(3)-homoserine or beta(3)-homothreonine, and (4) demonstrate that diverse functionality can be incorporated into a stable 14-helix. Gas- and solution-phase calculations and Monte Carlo simulations recapitulate the experimental trends only in the context of oligomers, yielding insight into the mechanisms behind 14-helix folding. The 14-helix propensities of beta(3)-amino acids differ starkly from the alpha-helix propensities of analogous alpha-amino acids. This contrast informs current models for alpha-helix folding, and suggests that 14-helix folding is governed by different biophysical forces than is alpha-helix folding. The ability to modulate 14-helix structure through side chain choice will assist rational design of 14-helical beta-peptide ligands for macromolecular targets. 相似文献
24.
Richard D. Chambers Julian F. S. Vaughan Steven J. Mullins 《Research on Chemical Intermediates》1996,22(8):703-715
t-Butylhydroperoxide/butyl-lithium is a good reagent for synthesis of epoxides and diepoxides from polyfluorinated-alkenes and-polyenes. This reagent and calcium hypochlorite both give a novel diepoxide 5 from perfluoro-3,4-dimethyl-2,4-diene 1; diepoxide 5 undergoes a novel rearrangement, at 200°C, to the corresponding 1,4-dioxine derivative 18. Possible mechanisms are discussed. 相似文献
25.
Julian Tyson 《Trends in analytical chemistry : TRAC》1985,4(7):IV-V
Professional scientific societies are becoming increasingly aware of the public image of their members' activities. The Analytical Division of the Royal Society of Chemistry, through the activities of its Honorary Publicity Secretary, is making a conscious effort to inform young people about the activities of analytical chemists and to interest them in the profession of analytical chemistry. 相似文献
26.
In this paper, we shall prove several non-existence results for divisible difference sets, using three approaches:
- character sum arguments similar to the work of Turyn [25] for ordinary difference sets,
- involution arguments and
- multipliers in conjunction with results on ordinary difference sets.
27.
Alexander Pott 《Combinatorica》1992,12(1):89-93
In this paper we develop a new method to obtain identities in a group algebraGF(p)G if an abelian difference set of ordern0 (modp) exists inG. We give an explicit formula ifp
2 orp
3 is the exactp-power dividingn. This generalizes the approach of Wilbrink, Arasu and the author. The proof presented here uses some knowledge about field extensions of thep-adic numbers. 相似文献
28.
On abelian difference set codes 总被引:1,自引:0,他引:1
Alexander Pott 《Designs, Codes and Cryptography》1992,2(3):263-271
In this paper we determine the ranks of the incidence matrices that belong to the following types of difference sets: Twin prime power difference sets, biquadratic residues and biquadratic residues with 0. We also prove a conjecture of Assmus and Key on the code generated by the hyperovals of PG(2, q). 相似文献
29.
Kocher N Henn J Gostevskii B Kost D Kalikhman I Engels B Stalke D 《Journal of the American Chemical Society》2004,126(17):5563-5568
The concept of hypervalency in molecules, which hold more than eight valence electrons at the central atom, still is a topic of constant debate. There is general interest in silicon compounds with more than four substituents at the central silicon atom. The dispute, whether this silicon is hypervalent or highly coordinated, is enlightened by the first experimental charge density determination and subsequent topological analysis of three different highly polar Si-E (E = N, O, F) bonds in a hexacoordinated compound. The experiment reveals predominantly ionic bonding and much less covalent contribution than commonly anticipated. For comparison gas-phase ab initio calculations were performed on this compound. The results of the theoretical calculations underline the findings of the experiment. 相似文献
30.
Chromatographic speciation of anionic and neutral selenium compounds in Se-accumulating Brassica juncea (Indian mustard) and in selenized yeast 总被引:1,自引:0,他引:1
Selenium-accumulating plants such as Brassica juncea (Indian mustard) concentrate the element in plant shoots and roots. Such behavior may provide a cost-effective technology to clean up contaminated soils and waters that pose major environmental and human health problems (phytoremediation). Such ability to transform selenium into bioactive compounds has important implications for human nutrition and health. Element selective characterization of B. juncea grown in the presence of inorganic selenium under hydroponic conditions provides valuable information to better understand selenium metabolism in plants. The present work determines both previously observed organoselenium species such as selenomethionine and Se-methylselenocysteine and for the first time detects the newly characterized S-(methylseleno)cysteine in plant shoots and roots when grown in the presence of selenate or selenite as the only selenium source. A key feature of this study is the complementary role of selenium and sulfur specific chromatographic detection by HPLC with interfaced inductively coupled plasma mass spectrometry (ICP-MS) detection and by derivatization GC with interfaced atomic spectral emission. HPLC-ICP-MS limits of detection for such species were in the range 5-50 ng Se mL(-1) in the injected extracts. Speciation profiles are compared with those of selenium-enriched yeast by both HPLC-ICP-MS and GC-AED. 相似文献