全文获取类型
收费全文 | 25756篇 |
免费 | 3945篇 |
国内免费 | 2380篇 |
专业分类
化学 | 17896篇 |
晶体学 | 309篇 |
力学 | 1530篇 |
综合类 | 109篇 |
数学 | 2912篇 |
物理学 | 9325篇 |
出版年
2024年 | 70篇 |
2023年 | 523篇 |
2022年 | 946篇 |
2021年 | 962篇 |
2020年 | 1006篇 |
2019年 | 991篇 |
2018年 | 826篇 |
2017年 | 727篇 |
2016年 | 1200篇 |
2015年 | 1149篇 |
2014年 | 1343篇 |
2013年 | 1788篇 |
2012年 | 2399篇 |
2011年 | 2406篇 |
2010年 | 1577篇 |
2009年 | 1499篇 |
2008年 | 1641篇 |
2007年 | 1504篇 |
2006年 | 1355篇 |
2005年 | 1151篇 |
2004年 | 838篇 |
2003年 | 642篇 |
2002年 | 607篇 |
2001年 | 442篇 |
2000年 | 434篇 |
1999年 | 513篇 |
1998年 | 425篇 |
1997年 | 436篇 |
1996年 | 451篇 |
1995年 | 358篇 |
1994年 | 306篇 |
1993年 | 234篇 |
1992年 | 234篇 |
1991年 | 198篇 |
1990年 | 169篇 |
1989年 | 143篇 |
1988年 | 97篇 |
1987年 | 109篇 |
1986年 | 87篇 |
1985年 | 82篇 |
1984年 | 47篇 |
1983年 | 43篇 |
1982年 | 35篇 |
1981年 | 18篇 |
1980年 | 11篇 |
1979年 | 10篇 |
1978年 | 6篇 |
1976年 | 9篇 |
1975年 | 11篇 |
1957年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
<正>We demonstrate a photonic band gap(PBG) from one-dimensional(1D) periodic structures created by a double-layer unit cell with an air layer and an anisotropic nonmagnetic left-handed metamaterial(LHM) layer whose permittivity elements are partially negative.The requirements imposed on the materials and structures to realize a PBG are derived when the frequency is above or below the cutoff frequency,and the transmission properties of the PBG are discussed by utilizing 4×4 transfer-matrix method with dispersive semiconductor metamaterial. 相似文献
992.
Tianyu Sun Jianyong Ma Xiaoyong Fu Jianpeng Wang Yunxia Jin Jianda Shao Zhengxiu Fan 《中国光学快报(英文版)》2010,(5):447-448
<正>A guided-mode resonance(GMR) filter with the same material(Ta_2O_5) for both the grating layer and the waveguide layer is designed and fabricated.This simple structure is easy to fabricate and can avoid the defects at the grating/waveguide interface using different materials.The spectral response measured with a Lambda 900 spectrophotometer under normal incidence for TE waves exhibits a peak reflectance exceeding 80%at the wavelength of 1040 nm with a full-width half-maximum(FWHM) linewidth of 23 nm.We evaluate the deviations of the fabricated structure from the designed parameters. 相似文献
993.
<正>Two new cage compounds,4-trinitroethyl-10-nitro-2,6,8,12-tetraacetylhexaazaisowurtzitane(3) and 4-trinitroethyl- 2,6,8,10,12-pentanitrohexaazaisowurtzitane(4),containing trinitromethyl group were synthesized by a novel method,and their structures were confirmed by IR,~1H NMR,MS and single crystal X-ray.DSC result shows that compound 4 has surprising thermal stability and could be a potential energetic compound. 相似文献
994.
A reliable and validated LC–MS method was established for a hexokinase inhibitor study based on adenosine 5′-triphosphate (ATP) determination. By adding 5 mM ammonium acetate in the aqueous phase, this method enabled the determination of ATP by LC–MS and greatly increased the MS signal of ATP. This method was used in the study of the anticancer mechanism of Momordica cochinchinensis, an exact ingredient which had exhibited certain hexokinase inhibitor activity. This might reveal the anticancer mechanism of Momordica cochinchinensis. 相似文献
995.
Chiral cinchona-based primary amine A was found to catalyze the asymmetric direct conjugate addition of prochiral 3-oxindoles with enones to afford 3,3-disubstituted oxindoles in good yields, moderate to high diastereoselectivities, and excellent enantioselectivities. 相似文献
996.
通过浸渍法制备了Pt/SAPO-11催化剂, 分步浸渍法制备了Zn-Pt/SAPO-11双金属催化剂. 通过X射线衍射、低温氮物理吸附、氨程序升温脱附和吡啶吸附红外等手段对所得样品进行了表征. 实验结果表明, 助剂Zn的引入导致了催化剂的比表面积和孔容降低, B酸量减少而L酸量增加, 总酸量有所增加. 在300~380 ℃范围内对正庚烷的临氢异构化反应考察发现, 引入金属助剂Zn可以明显改变正庚烷的转化率, 而对C7异构体的选择性影响不明显. 当Zn质量分数为0.2%, Pt质量分数为0.2%时, Zn-Pt/SAPO-11催化剂的正庚烷转化率及C7异构体收率达到最大值; Zn含量继续增加时, 正庚烷转化率及C7异构体收率均随之下降. 实验结果表明, 双功能催化剂中金属功能与酸性功能的匹配对正庚烷临氢异构化反应非常重要. 相似文献
997.
Shupeng Liu Ye Sun Heng Chen Suxian Song Yuhong Xu 《Applied biochemistry and biotechnology》2010,162(4):1206-1213
Salvianolic acid B is one of the effective components from the Chinese traditional drug Salvia miltiorrhiza (Danshen), which is widely used as a usual clinic drug for atherosclerosis-related disorder patients in China. But the targeting protein of salvianolic acid B is still not known. The possible targeting proteins of salvianolic acid B were explored by high throughput screening in this paper. Attached to the magnetic nanoparticles, salvianolic acid B was used for screening the high-affinity protein from the displaying cDNA peptide library phage. After biopanning, the selected protein or peptide sequences were used to explore the whole proteins containing the selected sequences in the National Center for Biotechnology Information website using blast. One of the selected phages was carried out by affinity analysis with salvianolic acid B using capillary electrophoresis (CE). The CE results indicated that the protein or peptide on the surface of the selected phages could bind the drug salvianolic acid B. The results are helpful to preliminarily explain the pharmacology of salvianolic acid B. 相似文献
998.
Interfacial area transport equation (IATE) is considered promising to evaluate dynamic changes of the interfacial area concentration in gas–liquid two-phase flows, which is of significance in characterizing the interfacial structure of the flows. Efforts were made by the authors in the past on the implementation of the IATE into computational fluid dynamics codes, such as Fluent. However, it remained unclear whether the IATE model coefficients derived from one-dimensional IATE model calibrations can be applied to three-dimensional simulations. The current study aimed to examine, primarily by investigating the lateral profiles of phase distributions, the applicability of the coefficients obtained from the one-dimensional IATE model calibration to a three-dimensional simulation of bubbly flow in a pipe. In addition, effects of the lift force on the lateral phase distributions were studied. A new set of the IATE model coefficients was suggested for a three-dimensional bubbly flow simulation. Good agreement was obtained with the updated coefficients between the predicted and measured flow parameters. 相似文献
999.
Elastic collisions of sulfur and hydrogen in their ground states at low temperatures and spectroscopic parameters of SH(X^2∏) radical 下载免费PDF全文
This paper constructs the interaction potential of the SH(X^2∏) radical by using the coupled-cluster singlesdoubles-approximate-triples theory combining the correlation-consistent quintuple basis set augmented with the diffuse functions, aug-cc-pV5Z, in the valence range. Employing the potential, it accurately determines the spectroscopic parameters. The present De, Re, ωe, ωeχe, ae and Be values are of 3.7767eV, 0.13424nm, 2699.846 cm^-1, 47.7055 cm^-1, 0.2639cm^-1 and 9.4414 cm^-1, respectively, which are in excellent agreement with those obtained from the measure- ments. A total of 19 vibrational states has been found when J = 0 by solving the radial SchrSdinger equation of nuclear motion. The complete vibrational levels, classical turning points, initial rotation and centrifugal distortion constants when J = 0 are reported for the first time, which are in good accord with the experimental results. The total and various partial-wave cross sections are computed for the elastic collisions of sulfur and hydrogen in their ground states at low temperatures when two atoms approach each other along the SH(X^2∏) potential energy curve. Over the impact energy range from 1.0×10^-11 to 1.0×10^-4 a.u., eight shape resonances have been found in the total elastic cross sections. For each shape resonance, the resonant energy is accurately calculated. Careful investigations have pointed out that these resonances result from the 1 = 0, 1, 2, 3, 4, 6, 7, 8 partial-wave contributions. 相似文献
1000.
Water wave diffraction by two parallel closely spaced rectangular barges is investigated, to characterise the general problem of LNG offloading from a floating plant into a shuttle tanker. It is well known that large free-surface motions, in the gap between the hulls, are predicted by diffraction theory; in model tests amplitudes of at least five times that of the incident wave amplitude have been observed. A second-order diffraction calculation is used, based on a quadratic boundary element method, to examine the behaviour of this characteristic configuration and to examine the influence of spacing between the hulls. The free-surface near-resonant behaviour at first and second order is interpreted in the context of simple linear analytical solutions for three-dimensional flow in an open-ended gap. 相似文献