Thermal bending associated with heat conduction by holographic interferometry

An experimental technique using real-time holographic interferometry combined with digitized image processing has been developed to measure the thermal diffusivity of polymers. This technique uses a cantilever beam or an annular disk with one side subjected to a pulse of radiant energy from a photographic flash. The resulting thermally induced deflection is measured by holographic interferometry. The observed deflection is due to a resultant thermal moment induced by a temperature gradient through the thickness. As time goes on, the heat conducts from the exposed surface through the thickness, resulting in a decrease of the bending moment and transverse deflection. It is shown that the deflection is proportional to the thermal moment, and the thermal diffusivity can be retrieved by moment analysis without deriving the analytical solution to the thermomechanical problem.     

Gold Nanobone/Carbon Nanotube Hybrids for the Efficient Nonenzymatic Detection of H2O2 and Glucose

We report a facile strategy for the synthesis of gold nanobone/carbon nanotube (CNT@GNB) nanoassemblies, which were prepared through hybridization of CNTs and GNBs mediated by a thiolated pyrene derivative. The SEM images confirmed the successful construction of the CNT@GNB nanoassemblies. Screen printed electrodes modified with the CNT@GNB nanoassemblies exhibited decent electrocatalytic activity, large surface‐to‐volume ratios, high electrochemical reversibility, and efficient electron transport properties, thereby enabling stable and sensitive nonenzymatic detection of H₂O₂ and glucose, with detection limits of 0.8 µM and 0.07 mM, respectively. Moreover, no interference was observed at a potential of +0.38 V for the interfering species, such as ascorbic acid and urea, indicating high selectivity toward the glucose detection.     

On heat fluctuations near a critical point

The spatial dependence of the heat fluctuations is examined from a thermodynamic potential for the probability of fluctuations. The corresponding correlation length is seen to diverge near the critical point.     

Polysulfobetaines as extractants for Sr(II) ions from its aqueous solutions

In the present paper, we communicate sorption of Sr(II) ions on novel polysulfobetaines. N‐vinyl imidazole was modified by crosslinking it with four different crosslinkers: N,N‐methylene bisacrylamide, ethylene glycol dimethacrylate, divinyl benzene, and tripropylene glycol diacrylate. All the crosslinked networks were treated with sodium 2‐bromoethane sulfonate to obtain novel polysulfobetaines. The polymers were characterized by FTIR, elemental analysis and SEM to find evidence of network formation and quaternization. These polymers were used as Sr(II) sorbents. Sr(II) uptake was determined by using a colorimetric method using Rose Bengal anionic dye and 0.1 N HCl as the eluent. SEM‐EDS analysis of Sr(II)‐loaded polymers as well as after elution on treatment with 0.1 N HCl was recorded to ascertain the uptake of Sr(II) ions. The experimental isotherm data were analyzed using the Freundlich and Temkin equations. The experimental data also were analyzed using pseudo‐second order sorption kinetic model. Results show that the equilibrium data fit well in the Freundlich isotherm. Copyright © 2010 John Wiley & Sons, Ltd.     

Pyridinyl-Carbazole Fragments Containing Host Materials for Efficient Green and Blue Phosphorescent OLEDs

Pyridinyl-carbazole fragments containing low molar mass compounds as host derivatives H1 and H2 were synthesized, investigated, and used for the preparation of electro-phosphorescent organic light-emitting devices (PhOLEDs). The materials demonstrated high stability against thermal decomposition with the decomposition temperatures of 361–386 °C and were suitable for the preparation of thin amorphous and homogeneous layers with very high values of glass transition temperatures of 127–139 °C. It was determined that triplet energy values of the derivatives are, correspondingly, 2.82 eV for the derivative H1 and 2.81 eV for the host H2. The new derivatives were tested as hosts of emitting layers in blue, as well as in green phosphorescent OLEDs. The blue device with 15 wt.% of the iridium(III)[bis(4,6-difluorophenyl)-pyridinato-N,C2′]picolinate (FIrpic) emitter doping ratio in host material H2 exhibited the best overall characteristics with a power efficiency of 24.9 lm/W, a current efficiency of 23.9 cd/A, and high value of 10.3% of external quantum efficiency at 100 cd/m². The most efficient green PhOLED with 10 wt% of Ir(ppy)₃ {tris(2-phenylpyridine)iridium(III)} in the H2 host showed a power efficiency of 34.1 lm/W, current efficiency of 33.9 cd/A, and a high value of 9.4% for external quantum efficiency at a high brightness of 1000 cd/m², which is required for lighting applications. These characteristics were obtained in non-optimized PhOLEDs under an ordinary laboratory atmosphere and could be improved in the optimization process. The results demonstrate that some of the new host materials are very promising components for the development of efficient phosphorescent devices.     

Transition to ballistic regime for heat transport in helium II

The size-dependent and flux-dependent effective thermal conductivity of narrow capillaries filled with superfluid helium is analyzed from a thermodynamic continuum perspective. The classical Landau evaluation of the effective thermal conductivity of quiescent superfluid, or the Gorter–Mellinck regime of turbulent superfluids, is extended to describe the transition to ballistic regime in narrow channels wherein the radius R is comparable to (or smaller than) the phonon mean-free path ?   in superfluid helium. To do so, we start from an extended equation for the heat flux incorporating non-local terms, and take into consideration a heat slip flow along the walls of the tube. This leads from an effective thermal conductivity proportional to R²$R^2$ (Landau regime) to another one proportional to R? (ballistic regime). We consider two kinds of flows: along cylindrical pipes and along two infinite parallel plates.     

Extended thermodynamics and the Jeffrey's constitutive equation

Extended irreversible thermodynamics provides an evolution equation for the viscous pressure tensor which reduces to the Jeffrey's constitutive equation in the long-wave limit. in contrast with Jeffrey's equation, the equation obtained in extended irreversible thermodynamics leads to finite speed of propagation for shear pulses. The nonlocal effects are included into the theory by allowing the entropy to depend on higher-order fluxes, instead of spatial gradients. The use of the former ones is clearly advantageous in the high-frequency domain.     

Generalized thermodynamic stability of systems under shear

Starting from the extended irreversible thermodynamics (EIT) theory, some corrections to the specific heat and to the thermal compressibility of a nonequilibrium system are obtained. We study the subsequent modifications of the static stability conditions of a system under shear. In some situations, a shear-induced melting transition can be present.