Heterocyclic diazo compounds as starting materials in organic synthesis (review)

Data on the structures and reactions of heterocyclic diazo compounds that lead to the formation of new heterocyclic systems as a result of intra- or intermolecular cyclization and rearrangements are systematized.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 579–603, May, 1980.     

Symmetry of electronic states in garnets

The paper presents the classification of the electronic empty lattice eigenvalues and the classification of the Bloch sums for the garnet structureIa3d (O _h ¹⁰ ) at the symmetry points, H, P, andN of the Brillouin zone. This provides a starting point for the energy band studies of these technologically important materials.The author thanks Dr. V. Frei for useful comments.     

The class reconstruction number of maximal planar graphs

The reconstruction numberrn(G) of a graphG was introduced by Harary and Plantholt as the smallest number of vertex-deleted subgraphsG _i =G – v _i in the deck ofG which do not all appear in the deck of any other graph. For any graph theoretic propertyP, Harary defined theP-reconstruction number of a graph G P as the smallest number of theG _i in the deck ofG, which do not all appear in the deck of any other graph inP We now study the maximal planar graph reconstruction numberrn(G), proving that its value is either 1 or 2 and characterizing those with value 1.     

160Tb nuclear orientation in yttrium single crystal

First experimental results of¹⁶⁰Tb nuclear orientation in yttrium single crystal matrix are described. The influence of external magnetic field in combination with the crystal field interaction is discussed.     

Path integrals on half-line

In the framework of path integrals we present a solution to the Schrödinger equation for a free particle confined to the half-linex > 0. A solution in question corresponds to the boundary condition (/x) (0,t)= (0,t) where is a real constant.     

Present state and future development of instrumental techniques for solution thermochemical (thermometric) analysis

A review of instruments for thermochemical (thermometric) solution analysis is given, including new types of isoperibol reaction of bomb calorimeters, the design of which can influence the future development of thermochemical measuring techniques. The new type of Dithermanal (Vaskut-EMG, Hungary, and Herrmann- Morris, France) controls the individual steps of the thermochemical analysis, adding memory and computing capabilities. Similar programming units with microprocessors for bomb and/or reaction calorimetry have been developed by Parr Comp. and Leco Comp. (USA). The latest modification of the Technicon flow analyzer permits on-line analysis of solid samples. For thermochemical titrations, the Sanda titrator (USA) and Vaskut automatic titrator (Hungary) are available. In the USA, the Tronac isothermal or isoperibol calorimeters are widely used. At the Technical University of Brno, ?SSR, smaller table instruments with a water-bath are applied for different modes of solution thermochemical analysis, and also for the reactions of solid samples in liquids. For the measurement of very small temperature differences, PTC thermistors are used. The possibilities of the future development of measuring techniques are outlined.     

Strukturelle Untersuchungen einiger neutraler Komplexe des zweiwertigen Molybdäns

Unit cell parameters have been calculated from x-ray powder diffraction data of Mo₂Br₄ Py ₄ (A), Mo₂I₄ Py ₄ (B), Mo₂I₄ Pic ₄ (C), Mo₂(SCN)₄ Py ₄ (D) and Mo₂(SCN)₄ Pic ₄ (E), A, B and C crystallize tetragonal. A witha=9,4₂,c=15,O₂ Å; B witha=9,4₆,c=14,9₈ Å and C witha=9,6₆ andc=15,7₂ Å D and E crystallize orthorhombic. D witha=10,0₉,b=9,1₄,c=15,0₈ Å; E witha=10,2₂,b=9,4₁ andc=15,1₅ Å.Py=pyridine,Pic=4-methylpyridine.