Classification and identification of recorded and synthesized impact sounds by practiced listeners, musicians, and nonmusicians

Three experiments were conducted to test the viability of a low-parameter modal model for synthesizing impact sounds to be used in commercial and psychoacoustic research. The model was constrained to have four physically based parameters dictating the amplitude, frequency, and decay of modes. The values of these parameters were selected by ear to roughly match the recordings of ten different resonant objects suspended by hand and struck with different mallets. In experiment 1, neither 35 professional musicians nor 187 college undergraduates could identify which of the two matched sounds was the real recording with better than chance accuracy, though significantly better than chance performance was obtained when modal parameters were selected without the previously imposed physical constraints. In experiment 2, the undergraduates identified the source corresponding to the recorded and synthesized sounds with the same level of accuracy and largely the same pattern of errors. Finally, experiment 3 showed highly practiced listeners to be largely insensitive to changes in the acoustic waveform resulting from an increase in the number of free parameters used in the modal model beyond 3. The results suggest that low-parameter, modal models might be exploited meaningfully in many commercial and research applications involving human perception of impact sounds.     

Quantitative conditions do not guarantee the validity of the adiabatic approximation

In this Letter, we point out that the widely used quantitative conditions in the adiabatic theorem are insufficient in that they do not guarantee the validity of the adiabatic approximation. We also reexamine the inconsistency issue raised by Marzlin and Sanders [Phys. Rev. Lett. 93, 160408 (2004)] and elucidate the underlying cause.     

Kinematic approach to the mixed state geometric phase in nonunitary evolution

A kinematic approach to the geometric phase for mixed quantal states in nonunitary evolution is proposed. This phase is manifestly gauge invariant and can be experimentally tested in interferometry. It leads to well-known results when the evolution is unitary.     

Consistent resolution of possible anomalies in B0-->phi K(S) and B+ --> eta'K+ Decays

In the framework of R-parity violating (R(p)) supersymmetry, we try to find a consistent explanation for both recently measured CP asymmetry in B0 --> phi K(S) decay and the large branching ratio of B+/- --> eta'K+/- decay, which are inconsistent with the standard model (SM) prediction. We also investigate other charmless hadronic B -- >PP and B --> VP decay modes whose experimental data favor the SM: for instance, recently measured CP asymmetries in B0 --> eta(')K(S) and B0 -- >J/Psi K(S). We find that all the observed data can be accommodated for certain values of R(p) couplings.     

Time-resolved PIV investigation on the unsteadiness of a low reynolds number confined impinging jet

The flow characteristics in a confined slot jet impinging on a flat plate were investigated in low Reynolds number regime by using time-resolved Particle Image Velocimetry technique. The jet Reynolds number was varied from 404 to 1026, where it is presumed that the transient regime exists. We found that the vortical structures in the shear layer are developed with increase of Reynolds number and that the jet becomes remains steady at the Reynolds number of 404. Vortical structures and their temporal evolution are verified and the results were compared with previous numerical studies.     

Pep-1 Peptide-modified liposomal carriers for intracellular delivery of gold nanoparticles

A Pep-1 peptide-modified liposomal (Pep1-Lipo) carrier system was investigated to increase the intracellular delivery of gold nanoparticles (Au NPs). Au NPs with a mean diameter of 13 nm were successfully encapsulated into the inner aqueous compartment of the novel carrier using an ethanol injection technique, reserving the distinctive optical characteristics of the surface plasmon resonance peak around 530 nm. The Au NP-loaded liposomal carrier was physically characterized as 150-170 nm in size and 45 mV in zeta potential. Dark field microscopic observation demonstrated that in vitro cellular association and/or translocation of the nanoprobes into the cells was increased by Pep1-Lipo carriers compared to bare Au NPs. In conclusion, this novel liposomal formulation is a promising platform for the intracellular delivery of metallic nanoprobes including Au NPs.     

Theoretical studies on the mechanism of acid-promoted hydrolysis of N-formylaziridine in comparison with formamide

[reaction: see text] We present an ab initio study of the acid-promoted hydrolysis reaction mechanism of N-formylaziridine in comparison with formamide. Since the rate of amide hydrolysis reactions depends on the formation of the tetrahedral intermediate, we focused our attention mainly on the reactant complex, the tetrahedral intermediate, and the transition state connecting these two stationary points. Geometries were optimized using the density functional theory, and the energetics were refined using ab initio theory including electron correlation. Solvent effects were investigated by using polarizable continuum method calculations. The proton-transfer reaction between the O-protonated and N-protonated amides was investigated. In acidic media, despite that the N-protonated species is more stable than the O-protonated one, it is predicted that both N-protonated and O-protonated pathways compete in the hydrolysis reaction of N-formylaziridine.     

Flow Dynamics of \hbox {CO}_{2}/brine at the Interface Between the Storage Formation and Sealing Units in a Multi-layered Model

Pressure distribution and \(\hbox {CO}_{2}\) plume migration are two major interests in \(\hbox {CO}_{2}\) geologic storage as they determine the injectivity and storage capacity. In this study, we adopted a three-layer model comprising a storage formation and the over- and underlying seals and determined three distinct flow regions based on the vertical flux exchange of \(\hbox {CO}_{2}\) and native brine. Regions 1 and 2 showed \(\hbox {CO}_{2}\) flowing from the storage formation to adjacent seals with counter-flowing brine. The characteristics of these fluxes in Region 1 were governed by permeability change due to salt precipitation whereas buoyancy force controlled the flux pattern in Region 2. Region 3 showed brine flowing from storage formation toward the over- and underlying seals, which enabled the displaced brine to escape from the storage formation and make room for \(\hbox {CO}_{2}\) to store as well as reduce the pressure build-up. In the multi-layered model, the counter-flowing brine in flow Region 1 resulted in localized salt precipitation at the upper and lower boundary of storage formation. We assessed the bottom-hole pressure and \(\hbox {CO}_{2}\) mass in caprock with respect to reservoir size. While the formation thickness influenced the bottom-hole pressure in the early stage of injection, the horizontal extension of the reservoir was more influential to pressure build-up during the injection period, and to the stabilized pressure during the post-injection period. The \(\hbox {CO}_{2}\) mass in caprock gently increased during the injection period as well as during the post-injection period and reached about 4–5 % of injected \(\hbox {CO}_{2}\) . The percentage of escaped brine from the storage formation ranged from 80–100 % of the \(\hbox {CO}_{2}\) mass stored in the storage formation depending on the reservoir scale.