Liquid chromatographic determination of 4,4'-dinitrocarbanilide, the active component of the infertility agent nicarbazin, in chicken, duck, goose, and snake eggs

4,4'-Dinitrocarbanilide (DNC) was extracted from chicken, duck, goose, and snake eggs and isolated by reversed-phase liquid chromatography. DNC was detected by ultraviolet absorbance at 347 nm and quantitated by comparison with a calibration standard. Recoveries of DNC from fortified control chicken, duck, goose, and snake egg samples were determined for DNC levels of 0.16, 10, and 16 microg/g. The mean recoveries from chicken, duck, goose, and snake eggs were 92 +/- 4, 88 +/- 9, 87 +/- 7, and 95 +/- 6%, respectively. The method limits of detection for DNC in chicken, duck, goose, and snake eggs ranged from 0.015 to 0.035 microg/g. The reported method is much simpler than and equally efficient as previous methods developed for the determination of DNC residues in egg contents.     

Constrained Lot-Sizes under Conditions of Inventory Growth

When average aggregate inventory levels are constrained to equal a constant level over time, optimal lot sizes can be identified which strike a balance between holding costs and set-up costs among items which form the aggregate. However, when it is desirable to change aggregate inventory levels over time, assumptions implicit in the traditional formulation are violated. The procedure proposed generates lot sizes which are consistent not only with the current average aggregate inventory level but also with its projected growth over the planning horizon. Comparison is made to lot sizes generated by the misapplication of traditional lot sizing methods to the inventory growth situation.     

Equilibrium polymerization in a solvent: Solution on the Bethe lattice

The lattice model for equilibrium polymerization in a solvent proposed by Wheeler and Pfeuty is solved exactly on a Bethe lattice (core of a Caylay tree) with general coordination numberq. Earlier mean-field results are reobtained in the limitq, but the phase diagrams show deviations from them for finiteq. Whenq=2, our results turn into the solution of the one-dimensional problem. Although the model is solved directly, without the use of the correspondence between the equilibrium polymerization model and the diluten0 model, we verified that the latter model may also be solved on the Bethe lattice, its solution being identical to the direct solution in all parameter space. As observed in earlier studies of the puren0 vector model, the free energy is not always convex. We obtain the region of negative susceptibility for our solution and compare this result with mean field and renormalization group (-expansion) calculations.     

Critical scaling for monodromy fields

The large scale asymptotics of the correlations for a family of two dimensional lattice field theories is calculated at the critical temperature.     

Intersections of random hypersurfaces and visibility

Summary For a wide class of stationary random hypersurfaces in ^d the notion of the projection body is introduced. It turns out that this convex body, a very special case of which is Matheron's Steiner compact associated with a Poisson process of hyperplanes, contains most of the information concerning certain intersection properties of the random hypersurface, while its polar reciprocal set is closely connected with the behaviour of the random hypersurface in visibility problems. This enables one to give a unified treatment of several intersection and visibility problems for random hypersurfaces. A detailed investigation of the case where the random hypersurface is generated by a Poisson process is given separately.     

Anomalous magnetic moment of theW-bosons and non-standardZ 0 W + W − coupling in polarizede − e + collisions

We study quantitatively the reactions \(e^ + e^ - \to W^ + e\bar \nu _e \) ,e _R ^? e ⁺ and the rare decay \(Z^0 \to W^ \pm l^ \mp \mathop {\nu _e }\limits^{( - )} \) forl=e, μ and τ, as a test for anomalous γW ⁺ W ^? andZ ⁰ W ⁺ W ^? structure. If κ denotes the anomalous magnetic moment of theW-boson and ω its anomalous coupling to theZ ⁰, values of |ω|>2.5 and |κ|>1.5 can be ruled out at LEP and SLC rather easily. This will put constraints on composite model building.     

Rotationally resolved electronic spectra of 1,2-dimethoxybenzene and the 1,2-dimethoxybenzene-water complex

Rotationally resolved S(1) <-- S(0) electronic spectra of 1,2-dimethoxybenzene (DMB) and its water complex have been observed and assigned. The derived values of the rotational constants show that the bare molecule has a planar heavy-atom structure with trans-disposed methoxy groups in its ground and excited electronic states. The transition of DMB is polarized along the b-axis bisecting the methoxy groups, demonstrating that its S(1) state is an (1)L(b) state. Higher energy bands of DMB are also polarized along the b-axis and have been tentatively assigned to different vibrational modes of the (1)L(b) state. The water complex origin appears 127 cm(-1) to the blue of the bare molecule origin. Analyses of the high resolution spectra of DMB/H(2)O and DMB/D(2)O suggest that the water molecule is attached via two O-H...O hydrogen bonds to the methoxy groups in both electronic states. A tunneling motion of the attached water molecule is revealed by a splitting of these spectra into two subbands. Potential barriers to this motion have been determined.     

Ternary rare-earth alumo-silicides—single-crystal growth from Al flux, structural and physical properties

A number of rare-earth alumo-silicides (R-Al-Si) have been synthesized from the corresponding elements by high-temperature reactions, carried out in excess of aluminum to serve as a flux. Under these experimental conditions, large single crystals of all R-Al-Si ternary phases were readily produced. The crystal structures these ternaries adopt were studied by means of powder and single-crystal X-ray diffraction and were classified as follows: (1) the early rare-earths (R=La, Ce, Pr, Nd, Sm, Gd) yield RAl_xSi_2−x, x∼1, non-stoichiometric ternary derivatives of the body-centered α-ThSi₂-type; (2) the late rare-earths (R=Tb, Dy, Ho, Er, Tm) form stoichiometric R₂Al₃Si₂ compounds that crystallize in the C-centered monoclinic Y₂Al₃Si₂-type; (3) the divalent Eu and Yb produce EuAl₂Si₂ and YbAl₂Si₂ with the trigonal CaAl₂Si₂-type, whereas the last lanthanide element, Lu, forms LuAlSi with C-centered orthorhombic YAlGe-type. These structural trends are reviewed, and the evolution of the basic physical properties such as magnetism, heat capacity and electrical resistivity when moving across the series is described in detail.