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111.
Valry Shibaev Sergey Kostromin Sergey Ivanov Lutz Lsker Thomas Fisher Joachim Stumpe 《Macromolecular Symposia》1995,96(1):157-159
Action of the laser illumination on optical properties of liquid crystalline (LC) comb-shaped acrylic and methacrylic copolymers containing cyanobiphenyl mesogenic groups and azo dye fragments has been studied. Under an illumination the cis-trans configurational changes of dye fragments take place and reorientation of the side groups towards a direction perpendicular to the electric vector of the actinic light occurs. As a result the photoinduced optical birefringence (δn = 0.05-0.11) appears. The detailed study of dichrotic and optical properties of polymeric films, kinetics and relaxation of δn, as well as mechanism of orientational transformations during a laser illumination are discussed. The induced optical anisotropy of the films can be changed reversibly by rotating the electric vector of the laser beam in respect to the film that may be used in reversible optical data storage. 相似文献
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Evgen V. Govor Andrey B. Lysenko Alexander N. Chernega Judith A.K. Howard Andriy A. Mokhir Joachim Sieler Konstantin V. Domasevitch 《Polyhedron》2008
Reaction of copper(II) acetate, lanthanium(III) or gadolinium(III) nitrate (1/5 equiv.) with pyrazinohydroxamic acid (H2Pyzha) in DMF led to a series of new heterobimetallic 15-metallacrown-5 complexes. In a MeOH/H2O solution the complexes exist as molecular unassociated metallacrowns. In solid state their structures are more complicated as it has been confirmed by X-ray analysis: discrete molecular metallacrowns [Gd(NO3)2{Cu(pyzha)}5(DMF)4(NO3)] · 0.5C6H6 · H2O (1), [Gd(NO3)2{Cu(pyzha)}5(DMF)5](NO3) · 1.5DMF · 0.5H2O (2), [La(NO3)2{Cu(pyzha)}5(DMF)5]NO3 · 1.5DMF · 2C6H6 (3) are solvates, whereas compound [{La(NO3)2{Cu(pyzha)}5(DMF)5}2(μ2-NO3)](NO3) · 3DMF (4) is a dimer, where μ-bridged nitrate links two copper centres of the adjacent metallamacrocycles. Complex [Gd(NO3)2{Cu(pyzha)}5(DMF)2(H2O)(NO3)] · CH2Cl2 · DMF (5) self-associates into a polymer chain by means of one pyrazine moiety and the copper ring atom. Reaction of the molecular metallacrowns with excess of inorganic salts CdBr2 or Cu(OAc)2 proceeds as anion methathesis process affording heteroanionic metallacrowns: molecular [Gd(NO3)2{Cu(pyzha)}5(DMF)5] [Gd(NO3)2{Cu(pyzha)}5(DMF)4(H2O)][CdBr4] · 1.5DMF (6), and 3D hydrogen bonded polymer [La(μ2-OAc)(H2O)3{Cu(pyzha)}5 (H2O)4(NO3)](NO3) · 4H2O (7). 相似文献
117.
Anton Amadeus Hrmann Elisabeth Plhak Maximilian Klingler Christine Rangger Joachim Pfister Gert Schwach Herbert Kvaternik Elisabeth von Guggenberg 《Molecules (Basel, Switzerland)》2022,27(6)
The new minigastrin analog DOTA-MGS8 targeting the cholecystokinin-2 receptor (CCK2R) used in this study displays the combination of two site-specific modifications within the C-terminal receptor binding sequence together with an additional N-terminal amino acid substitution preventing fast metabolic degradation. Within this study, the preparation of 68Ga-labeled DOTA-MGS8 was validated using an automated synthesis module, describing the specifications and analytical methods for quality control for possible clinical use. In addition, preclinical studies were carried out to characterize the targeting potential. [68Ga]Ga-DOTA-MGS8 showed a high receptor-specific cell internalization into AR42J rat pancreatic cells (~40%) with physiological expression of rat CCK2R as well as A431-CCK2R cells transfected to stably express human CCK2R (~47%). A favorable biodistribution profile was observed in BALB/c nude mice xenografted with A431-CCK2R cells and mock-transfected A431 cells as control. The high tumor uptake of ~27% IA/g together with low background activity and limited uptake in non-target tissue confirms the potential for high-sensitivity positron emission tomography of stabilized MG analogs in patients with MTC and other CCK2R-related malignancies. 相似文献
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Summary We present an approximation method of a space-homogeneous transport equation which we prove is convergent. The method is very promising for numerical computation. Comparison of a numerical computation with an exact solution is given for the Master equation. 相似文献
119.
Characteristic parameter sets and limits of circulant Hermitian polygon transformations 总被引:1,自引:0,他引:1
Polygon transformations based on taking the apices of similar triangles constructed on the sides of an initial polygon are analyzed as well as the limit polygons obtained by iteratively applying such transformations. In contrast to other approaches, this is done with respect to two construction parameters representing a base angle and an apex perpendicular subdivision ratio. Furthermore, a combined transformation leading to circulant Hermitian matrices is proposed, which eliminates the rotational effect of the basic transformation. A finite set of characteristic parameter subdomains is derived for which the sequence converges to specific eigenpolygons. Otherwise, limit polygons turn out to be linear combinations of up to three eigenpolygons. This leads to a full classification of circulant Hermitian similar triangles based polygon transformations and their limit polygons. As a byproduct classical results as Napoleon’s theorem and the Petr-Douglas-Neumann theorem can be easily deduced. 相似文献
120.
Redinger A Ricken O Kuhn P Rätz A Voigt A Krug J Michely T 《Physical review letters》2008,100(3):035506
The growth of spiral mounds containing a screw dislocation is compared to the growth of wedding cakes by two-dimensional nucleation. Using phase field simulations and homoepitaxial growth experiments on the Pt(111) surface we show that both structures attain the same large scale shape when a significant step-edge barrier suppresses interlayer transport. The higher vertical growth rate of the spiral mounds on Pt(111) reflects the different incorporation mechanisms for atoms in the top region and can be formally represented by an enhanced apparent step-edge barrier. 相似文献