首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   12643篇
  免费   2188篇
  国内免费   2519篇
化学   10524篇
晶体学   255篇
力学   668篇
综合类   145篇
数学   1194篇
物理学   4564篇
  2024年   56篇
  2023年   289篇
  2022年   549篇
  2021年   565篇
  2020年   603篇
  2019年   669篇
  2018年   546篇
  2017年   546篇
  2016年   645篇
  2015年   681篇
  2014年   811篇
  2013年   1004篇
  2012年   1082篇
  2011年   1088篇
  2010年   888篇
  2009年   799篇
  2008年   823篇
  2007年   688篇
  2006年   701篇
  2005年   659篇
  2004年   557篇
  2003年   467篇
  2002年   499篇
  2001年   460篇
  2000年   316篇
  1999年   260篇
  1998年   173篇
  1997年   116篇
  1996年   141篇
  1995年   94篇
  1994年   110篇
  1993年   107篇
  1992年   67篇
  1991年   77篇
  1990年   47篇
  1989年   34篇
  1988年   27篇
  1987年   27篇
  1986年   24篇
  1985年   16篇
  1984年   13篇
  1983年   12篇
  1982年   1篇
  1981年   1篇
  1980年   2篇
  1979年   2篇
  1971年   1篇
  1959年   3篇
  1957年   1篇
  1936年   3篇
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
11.
增湿活化反应器内喷水脱硫试验研究   总被引:4,自引:0,他引:4  
本文介绍在热态脱硫试验台上进行的生石灰和消石灰的喷水活化脱硫试验,研究了Ca/S比、饱和温距、入口烟气SO2浓度、烟气速度及水喷嘴雾化风对脱硫效率和钙利用率的影响规律,对两种脱硫剂的脱硫活性进行了比较,并对喷水增湿提高脱硫效率的机理进行了分析。研究表明,喷水增湿使两种脱硫剂的活性都有明显提高,生石灰具有价格优势。  相似文献   
12.
介绍了采用MATLAB V5.2提供的模糊逻辑工具箱来设计研究电孤纺电极调节系统中的模糊--PD控制器,讨论了在SIMULINK环境下模糊-PD控制器的参数自调速原理、结构、建立模糊控制规则库和模糊推论方法,并给出仿真结果与结论。  相似文献   
13.
A Promising MoO_x-based Catalyst for n-Heptane Isomerization   总被引:1,自引:0,他引:1  
The increasing demand for higher-octane gasoline and the regulations limiting the amount of aromatics in the fuel motivate the interest in catalytic isomerization of n-alkanes. In the last ten years, transition metal oxides or oxycarbides based on molybdenum or tungstate have attracted much attention due to their high activity and isomerization selectivity compared to the conventional bifunctional supported platinum catalyst and high resistance to sulphur and nitrogen catalyst poisons1-5. Ma…  相似文献   
14.
陆路德  汪信 《应用化学》1989,6(1):63-65
双金属催化剂是一类重要的多相催化剂。其中d电子在催化活性方面起着重要的作用.本文在Co_3[Fe(CN)_6]_2的工作基础上,进一步研究了该配合物在硅胶、氧化铝、以及氧化镁上的热性质,同时考察了CN~-在Co-Fe体系双端基配位的活化加氢,探讨了载体的影响.  相似文献   
15.
A new series of copolymers was synthesized through the oxidative polymerization of pyrrole (PY) and o‐phenetidine (PHT) with inorganic oxidants in acidic media. The polymerization parameters including the mixing method of the oxidant with the comonomer, the comonomer ratio, the time, the temperature, the oxidant, the organic medium, and the acid were systematically optimized for the synthesis of copolymers with high yields, intrinsic viscosities, and solubility. The resultant copolymers were characterized by elemental analysis, infrared, ultraviolet–visible, solution high‐resolution 1H NMR and solid‐state high‐resolution 13C NMR, circular dichroism spectroscopy, and cyclic voltammetry. The results showed that the PY observed content in the copolymers was much higher than the PY feed content. The regular variation of the polymerization yield, intrinsic viscosity, solubility, macromolecular structure, and electroactivity of the resulting polymers with the comonomer ratio, together with the complete solubility of a PY/PHT (10/90) polymer in highly polar solvents, indicated the formation of real random copolymers containing both PY and PHT units rather than a mixture of two homopolymers. However, the polymers containing more than 59 mol % PY were not homogeneous copolymers consisting of soluble and insoluble parts. A semiquantitative relationship between the polymerization yield or solubility of the copolymers and the polarity index of the organic solvents was examined. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2073–2092, 2004  相似文献   
16.
1. INTRODUCTION Methionine, namely 2-amido-4-thiomethyl butyric acid with a structure of CH3SCH2CH2CHCOOH, is one of the essential amino acids and has two natural enantionmers, D and L-methionine. The mixture of L- and D-isomers can be used as analeptics or nutritive additives to maintain the equilibrium of amino acids of feed [1,2]. L-methionine can release active methyl and accelerate the synthesis of choline, which further speeds up the conversion of the lipid accumulated in liv…  相似文献   
17.
18.
[1]M.Alford,K.Rajagopal,and F.Wilczek,Phys.Lett.B 422 (1998) 247; Nucl.Phys.B 537 (1999) 443. [2]M.Gyulassy and L.McLerran,arXiv:nucl-th/0405013;E.V.Shuryak,arXiv:hep-ph/0405066. [3]K.Rajagopal and F.Wilczek,hep-ph/0011333. [4]M.Alford,Chris Kouvaris,and K.Rajagopal,hepph/0406137. [5]Y.Nambu and G.Jona-Lasinio,Phys.Rev.122 (1961)345. [6]R.T.Cahill and C.D.Roberts,Phys.Rev.D 32 (1985)2419. [7]R.T.Cahill and Susan M.Ganner,hep-ph/9812491. [8]A.W.Steiner,S.Reddy,and M.Prakash,Phys.Rev.D 66 (2002) 094007. [9]P.Amore,M.C.Birse,J.A.McGovern,and N.R.Walet,Phys.Rev.D 65 (2002) 074005. [10]M.Alford and K.Rajagopal,JHEP 0206 (2002) 031. [11]Xiao-Fu Li,Yu-Xin Liu,Hong-Shi Zong,and En-GuangZhao,Phys.Rev.C 58 (1998) 1195. [12]H.Reinhardt,Phys.Lett.B 244 (1990) 2. [13]Steven Weinberg,The Quantum Theory of Fields,Vol.2,Cambridge University Press,Cambridge (1996) p.348.  相似文献   
19.
Based on the effective-field theory with self-spin correlations and the differential operator technique,physical properties of the spin-2 system with biaxial crystal field on the simple cubic, body-centered cubic, as well as faced-centered lattice have been studied. The influences of the external longitudinal magnetic field on the magnetization,internal energy, specific heat, and susceptibility have been discussed in detail. The phenomenon that the magnetization in the ground state shows quantum effects produced by the biaxial transverse crystal field has been found.  相似文献   
20.
Optimized prefactored compact schemes   总被引:1,自引:0,他引:1  
The numerical simulation of aeroacoustic phenomena requires high-order accurate numerical schemes with low dispersion and dissipation errors. In this paper we describe a strategy for developing high-order accurate prefactored compact schemes, requiring very small stencil support. These schemes require fewer boundary stencils and offer simpler boundary condition implementation than existing compact schemes. The prefactorization strategy splits the central implicit schemes into forward and backward biased operators. Using Fourier analysis, we show it is possible to select the coefficients of the biased operators such that their dispersion characteristics match those of the original central compact scheme and their numerical wavenumbers have equal and opposite imaginary components. This ensures that when the forward and backward stencils are added, the original central compact scheme is recovered. To extend the resolution characteristic of the schemes, an optimization strategy is employed in which formal order of accuracy is sacrificed in preference to enhanced resolution characteristics across the range of wavenumbers realizable on a given mesh. The resulting optimized schemes yield improved dispersion characteristics compared to the standard sixth- and eighth-order compact schemes making them more suitable for high-resolution numerical simulations in gas dynamics and computational aeroacoustics. The efficiency, accuracy and convergence characteristics of the new optimized prefactored compact schemes are demonstrated by their application to several test problems.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号