反相液体色谱中饱和醇保留行为的研究 Ⅰ.低碳醇保留行为与溶质分子结构的关系

本文从吸附-疏溶剂理论出发,根据热力学平衡观点,导出了一定固定相和流动相时,描述溶质保留行为与其分子结构关系的理论模型,并用之预测了饱和醇的保留值,获满意结果。从而表明本模型不但能用于同系物,而且亦可用于同分异构体及立体异构体保留行为的预测。     

Synthesis and magnetic properties of novel polymeric complexes containing bithiazole rings

A novel linear polymer (PFABT) containing bithiazole rings was synthesized by polycondensation of 2,2′‐diamino‐4,4′‐bithiazole (DABT) and formaldehyde. The complexes of PFABT with two transition metal ions (Fe²⁺, Cu²⁺) were prepared for the first time. The polymer was determined through FT‐IR, ¹H‐NMR and elemental analysis (EA), and the complexes were characterized by FT‐IR. The magnetic behaviors of these complexes were measured as a function of magnetic field strength (0–50 kOe) at 4 K and as a function of temperature (4–300 K) under an applied magnetic field of 30 kOe. The results show that PFABT‐Cu²⁺ is a ferromagnet while PFABT‐Fe²⁺ is an anti‐ferromagnet. Copyright © 2007 John Wiley & Sons, Ltd.     

壳聚糖衍生物的制备及其吸附性能

壳聚糖衍生物的制备及其吸附性能曲荣君，马千里，郑秀丽，孙言志（烟台师范学院化学系烟台２６４０２５）关键词壳聚精衍生物，制备，吸附壳聚糖（ＣＴＳ）是重金瞩离子的吸附剂￣［１，２］，由于壳聚精分子中的－ＮＨ＿２在ｐＨ较低的水溶液易形成而使ＣＴＳ溶于水，造...     

三氯化钛存在下碘酸钾滴定法测定锡

提出了采用铝加铁混合还原剂还原,三氯化钛存在下碘酸钾滴定法测定锡的绝对测量方法,研究了三氯化钛抑制氧的作用效果及作用机理。应用于巴氏合金中锡含量的测定,方法简便、快速,结果准确可靠。     

Photodynamic therapy of human glioma spheroids using 5-aminolevulinic acid

The response of human glioma spheroids to 5-aminolevulinic acid (ALA)-mediated photodynamic therapy (PDT) is investigated. A two-photon fluorescence microscopy technique is used to show that human glioma cells readily convert ALA to protoporphyrin IX throughout the entire spheroid volume. The central finding of this study is that the response of human glioma spheroids to ALA-mediated PDT depends not only on the total fluence, but also on the rate at which the fluence is delivered. At low fluences (< or = 50 J cm-2), lower fluence rates are more effective. At a fluence of 50 J cm-2, near-total spheroid kill is observed at fluence rates of as low as 10 mW cm-2. The fluence rate effect is not as pronounced at higher fluences (> 50 J cm-2), where a favorable response is observed throughout the range of fluence rates investigated. The clinical implications of these findings are discussed.     

吸附溶出催化伏安法测定痕量锗

利用吸附溶出伏安法、极谱催化法测定痕量锗已有报道。但将吸附溶出伏安法与极谱催化法结合进行测定,尚未见报道。我们选择适当的体系和配位体3,4-二羟基苯甲醛(DHB)及氧化剂钒(V),首先使Ge(Ⅳ)-DHB络合物在悬汞电极上于一定电位处吸附富集一定时间,然后电位向负的方向扫描。当达到Ge(Ⅳ)-DHB络合物的还原电位时,Ge(Ⅳ)还原     

具有C2对称轴的手性配体及其不对称催化反应

按配位原子的数目进行分类，综述了近年来研究较多的具有Ｃ２对称轴的手性配体及其相关的不对称催化反应，并对该类手性配体的设计做了分析和总结。参考文献７９篇。     

植物胞外钙调素与拮抗剂W7-Agarose结合作用的荧光光谱法研究

W 7-agarose是常用的细胞外CaM功能的拮抗剂,本实验采用荧光光谱法研究了水溶液中钙调素拮抗剂W 7-agarose与植物胞外钙调素的相互结合反应。W 7-agarose是一种将W 7-共价连接到颗粒型agarose(琼脂糖)的粒子。W 7-agarose颗粒较大且容易沉淀,静置5m in后,溶液中的荧光强度完全由游离的CaM产生。在溶液中加入W 7-agarose后,溶液中一部分CaM与其结合后沉降至荧光比色皿底部,导致溶液中CaM的荧光强度下降。由此可以确定溶液中游离CaM的浓度。根据公式lg{[Q]t(F0-F)/F0}=nlg{[Q]tF/F0} lgnK[B]t,从而计算出配位体系的结合常数和配比。研究表明:二者以摩尔比1∶1结合,其平衡常数为4.9×105。由此进一步计算了W 7-agarose对胞外钙调素的拮抗率,在拮抗剂W 7-agarose浓度达到15~20μmol/L时,拮抗率可达到90%以上,与文献报道的生物学体内实验结果一致,从分子水平上解释了W 7-agarose与CaM的结合作用。     

Ag(Ⅰ)与Co(Ⅱ)离子对阳极析氧过程的电催化作用

关于Co（Ⅱ）离子对PbO2和Pt电极上阳极析氧过程的催化作用，以及Ag（Ⅰ）离子对阳极氧化过程的催化作用，文献上已早有报导［1－4］，但大都是仅通过总的极化曲线进行对比研究得出的结果．由于在氧析出的同时往往有其它阳极氧化过程同时进行（例如，Co（Ⅱ）或Ag（Ⅰ）的阳极氧化），因此，很难从总的极化曲线得出正确的结论．本文用气体电量计法直接测量氧析出速度，并对Pt和PbO2电极进行了对比，得出了一些新的结果．1实验方法为了直接测量氧析出过程的分电流，实验时串联了一专收集O2的气体库仑计．电解槽和库仑计阳极均安装在各自…