Improving Photocatalytic Performance through the Construction of a Supramolecular Organic Framework

A supramolecular organic framework-type photocatalyst, named TM-SOF, is constructed by the self-assembly of cucurbit[8]uril and a tetra-arm monomer containing four N, N’-dimethyl 2,5-bis(4-pyridinium)thiazolo[5,4-d]thiazole (MPT) moieties. Benefiting from the multivalent assembly, a photocatalytically active supramolecular MPT dimer can be stably formed in TM-SOF. In addition, TM-SOF exhibits better stability against temperature, substrate, and light irradiation. As a result, TM-SOF shows a significantly improved performance for the photocatalytic aerobic oxidation of aryl boronic acids and thioethers. It is anticipated that this line of research will provide a facile approach for fabricating high-performance supramolecular photocatalysis systems.     

Synthesis of deuterium-labeled DL-threo-thiamphenicol

Journal of Radioanalytical and Nuclear Chemistry - A convenient and inexpensive approach for the synthesis of deuterium-labeled thiamphenicol was described. DL-threo-Thiamphenicol-methyl-d3 was...     

无轴承旋翼柔性梁载荷特性研究

应用Hamilton原理建立了双路传力的无轴承旋翼运动方程。采用均匀入流模型,基于直升机飞行平衡条件,建立了无轴承旋翼柔性梁载荷的计算模型,并通过算例验证了模型的精度。利用该模型,研究了全机重心位置、机身气动阻力以及平尾安装角对柔性梁载荷特性的影响,给出了各因素对柔性梁载荷的影响趋势,得出了降低柔性梁载荷的方法。数值结果表明:2cm左右重心位置的变化能够引起9%~11%的柔性梁载荷变化量,15%气动阻力的增加会导致约9%的柔性梁载荷的增大;2°平尾安装角的变化引起约10%柔性梁载荷的变化量,3°平尾安装角的变化引起约26%柔性梁载荷的变化。     

Anisotropic Conductive Membrane with Superparamagnetism and Color-Tunable Luminescence

Russian Journal of Physical Chemistry A - A new nanostructure of luminescent-magnetic-electrical trifunctionality Janus nanofibers with [Fe3O4/polyvinyl pyrrolidone...