TiO_2/CuPc/NiFe-LDH photoanode for efficient photoelectrochemical water splitting

Photoelectrochemical(PEC) water splitting is a promising approach for renewable hydrogen production.However,the practical PEC solar-to-fuel conversion efficiency is still low owing to poor light absorption and rapid recombination of charge carriers in photoelectrode.In this work,we report a ternary photoanode with simultaneously enhancement of light absorption and water oxidation efficiency by introducing copper phthalocyanine(CuPc) and nickel iron-laye red double hydroxide(NiFe-LDH) on TiO_2(denoted as TiO_2/CuPc/NiFe-LDH).An experimental study reveals that CuPc loading on TiO_2 bring strong visible light absorption;NiFe-LDH as an oxygen evolution reaction catalyst efficiently accelerates the surface water oxidation reaction.This synergistic effect of CuPc and NiFe-LDH gives enhanced photocurrent density(2.10 mA/cm2 at 0.6 V vs.SCE) and excellent stability in the ternary TiO_2/CuPc/NiFeLDH photoanode.     

Some Finite Time Ruin Problems in Markov-Modulated Risk Model

This paper studies the distribution of finite-time ruin quantities. It gives the probability mass function of finite time number of claims, and find the distribution function of aggregate claims by using discretise method and compared with exact distribution function, which shows that the approximation works very well. In addition, by applying decomposition for density function, it gives the explicit expression for joint density of ruin time and deficit at ruin.     

线式惠斯登电桥测量电阻的误差计算

本文通过引人线式惠斯登电桥的调节灵敏度，解决了用线式惠斯登电桥测量电阻时误差计算中存在的问题。     

Synthesis of β,β′‐Porphyrin Dimer Linked by Vinylene

Synthesis of a novel β,β′‐tetraalkylporphyrin dimer linked by vinylene was discribed, in which the dimer was readily prepared from a porphyrin‐derived Wittig reagent and a mono‐formylated porphyrin via Wittig reaction. No π‐conjugation between the two porphyrin rings was obserbed, and the dimer was in trans form.     

手性席夫碱配合物用于催化不对称环氧化

手性席夫碱过渡金属配合物可以高效催化烯烃不对称环氧化反应,因此其合成及催化性能研究一直以来受到广泛的关注.本文较详细地综述了最近十年来合成的手性席夫碱过渡金属配合物及其对烯烃环氧化反应的催化性能的研究进展.重点讨论了新型的对称和非对称salen型配体过渡金属配合物的合成及其应用,分析探讨了手性席夫碱过渡金属配合物作为催化剂的优缺点、催化机理和未来发展方向.     

GC-MS with ethyl chloroformate derivatization for comprehensive analysis of metabolites in serum and its application to human uremia

An optimized method based on GC-MS with ethyl chloroformate derivatization has been developed for the comprehensive analysis of endogenous metabolites in serum. Twenty-two reference standards and serum samples were used to validate the proposed method. The correlation coefficient was higher than 0.9900 for each of the standards, and the LOD varied from 125 to 300 pg on-column. The analytical equipment exhibited good repeatability (RSD<10%) for all of the standards. Both the repeatability and the within-48-h stability of the analytical method were satisfactory (RSD<10%) for the 18 metabolites identified in the serum samples. Mean recovery was acceptable for the 18 metabolites, ranging from 70% to 120% with RSDs of less than 10%. Using the optimized protocol and a subsequent multivariate statistical technique, complete differentiation was achieved between the metabolic profile of uremic patients and that of age- and sex-matched normal subjects. Significantly decreased levels of valine, leucine, and isoleucine and increased levels of myristic acid and linoleic acid were observed in the patient group. This work demonstrated that this method is suitable for serum-based metabolic profiling studies.     

刚性块轴向撞击杆的弹塑性动力屈曲

用特征线法分析了刚性块轴向撞击弹塑性直杆时应力波传播的全过程,得到了杆冲击端与固定端应力的变化规律及刚性块与杆首次分离的时间.基于能量原理,考虑了弹塑性应力波的传播与反射,建立了弹塑性杆在刚性块轴向撞击下的横向扰动方程,给出了问题的级数解,由解的稳定性得到了发生屈曲时的临界条件;通过数值计算和分析,给出了临界速度与冲击质量、线性强化模量及临界时间间的关系.     

负载脯氨酸及其衍生物催化的不对称C-C键形成反应研究进展

近年来脯氨酸及其衍生物催化的不对称有机反应受到了广泛关注,将其负载于载体上使用也引起了人们的极大兴趣.负载方式大致分为3种:共价键负载,离子对结合或物理吸附等作用负载,以及在离子液体中的两相催化剂.本文对近年来出现的负载脯氨酸及其衍生物催化的不对称反应(Aldol反应、Michael加成反应)研究进展进行了综述.     

A Multinomial Approximation Approach for the Finite Time Survival Probability Under the Markov-modulated Risk Model

In this paper, we consider the problem of computing different types of finite time survival probabilities for a Markov-Modulated risk model and a Markov-Modulated risk model with reinsurance, both with varying premium rates. We use the multinomial approximation scheme to derive an efficient recursive algorithm to compute finite time survival probabilities and finite time draw-down survival probabilities. Numerical results show that by comparing with MCMC approximation, discretize approximation and diffusion approximation methods, the proposed scheme performs accurate results in all the considered cases and with better computation efficiency.

     

Macrocyclic Ethers by Free Radical Cyclizations

Tin hydride reduction of ω-iodo-polyoxaalkyl acrylates 1 using syringe pump addition of both reactants to a solution of AIBN in benzene at 80°C afforded the corresponding cyclic polyethers in excellent yields.