Effect of Hydrogen Binding on Selective Recognition of Halide Anions

The interplay of molecular rigidity enforced by interior or exterior hydrogen bonding and affinity for binding halide anions is described to demonstrate the effect of intramolecular hydrogen bonding in anion recognition process. To this end pyridine‐2,6‐dicarboxamides 1 and 2 , and aromatic oligoamides 3 and 4 containing intramolecular hydrogen bonds were explored for their ability in associating with tetrabutylammonium halide (Cl^?, Br^?, and I^?). Binding constants in chloroform solution were calculated using nonlinear curve‐fitting method based on ¹H NMR titration experiments. The trimeric amide 3 , which adopts a crescent conformation as revealed by single‐crystal X‐ray diffraction analysis, strongly binds chloride anion with binding constant as high as 379 L·mol^?1. This is more than 6 times greater than the binding constant for the control receptor 2 with a backbone that is only partially rigidified. The comparative data provided supportive information for rationalizing the observed affinity difference in binding halide anions in terms of local preorganization effected by interior or exterior hydrogen bonding.     

Study of Static Adsorption Capacity of ACF for Xenon at 201 K

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保持因子交换性的可加映射

设x和y是代数中的两个元.如果存在某个数ξ,使得xy=ξyx,称x和y关于因子ξ交换.给出了标准算子代数间双边保关于因子交换的可加满射的刻画和分类以及C*-代数间保关于因子交换的有界线性满射的刻画和分类.     

Additive maps preserving rank-one operators on nest algebras

In this article, we give a thorough discussion of additive maps between nest algebras acting on Banach spaces which preserve rank-one operators in both directions.     

A NE102A+CsI(T1)+PMT Detector Telescope for Intermediate Energy Heavy Ion Reactions

This paper describes the structure and performance of the phoswich telescope made of lmm thick scintillator NE102A and 40mm thick CsI(T1).The front area of CsI(T1) is 24mm×24mm and back area is 37mm×37mm.The p,d and t of isotope and all fragments have been separated clearly using QDC method.     

完全液相法制备中原料配比对二甲醚合成催化剂结构和性能的影响

利用完全液相法制备了Cu-Zn-Al双功能催化剂,考察了原料配比对催化剂结构和催化CO加氢合成二甲醚反应性能的影响,用XRD,N2吸附,XPS和H2-TPR等方法对催化剂进行了表征.结果表明,在Cu-Zn-Al基二甲醚合成催化剂中,Zn和Al在催化剂表面的竞争富集是主要过程,增加投料中Cu的比例并不能显著增加Cu在催化剂表面的含量,因为在反应环境中,Al也会富集,并且在Cu含量高时富集得更快.当投料组成为n(Cu)∶n(Zn)∶n(Al)=2∶1∶4时,催化剂的体相结构和表面性质最好(Cu晶粒度最小,Cu分散度最高,还原性能最佳,组分间相互作用最强,最可几孔径最大),催化剂的综合性能最好.     

Split aptamer-based sandwich fluorescence resonance energy transfer assay for 19-nortestosterone

In order to develop an aptamer based fluorescence resonance energy transfer (FRET) assay for 19-nortestosterone, a 76-mer 17β-estradiol aptamer was split into two pieces (referred to as P1 and P2, respectively). P1 was labeled with a quencher (BHQ), and P2 with a fluorophore (6FAM). The two aptamer pieces were employed to detect NT via FRET quenching in a homogeneous solution. This method has a low detection limit (5 μM) within a wide dynamic range (5 to 1000 μM). The approach was used to analyze spiked urine samples, and the results showed that the average recovery of three samples containing different NT concentrations ranged from 58 to 118 % with a relative standard deviation (RSD) of less than 1 %. In our perception, the method has a wide scope for future applications to other analytes by using dually labeled split aptamers.

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Graphical abstract A split aptamer-based fluorescence resonance energy transfer assay for 19-nortestosterone was developed with a wide dynamic range of 5 to 1000 μM and low detection limit (5 μM). The average recovery from spiked urine samples ranged from 58 to 118 %, with a relative standard deviation (RSD) of less than 1 %.

     

Taylor补丁对新型动脉旁路移植流场影响的数值分析

为了研究Taylor补丁对新型(S型)动脉旁路移植术中吻合口处流场的影响,使用数值方法研究了采用Taylor补丁和未采用该补丁的两个S型旁路移植模型内流场的血流动力学差异. 对流速、壁面切应力和切应力梯度等参数进行了比较分析. 结果表明,Taylor补丁对吻合口的流场有显著影响. 采用Taylor补丁的模型其下游吻合口处的流场分布较未采用补丁的模型更均匀,二次流平均流速减小约34.48%,壁面切应力梯度减小约52.22%,从壁面切应力梯度方面分析,这将有助于改善血流动力学分布,抑制动脉粥样硬化. 但从壁面切应力值分析,其动脉底部的壁面低切应力区明显增大,平均壁面切应力值减小30.33%,这又将促使动脉粥样硬化. 因此,Taylor补丁是否对S型搭桥术具有治疗优越性,仅从血流动力学分析尚不能定论,配合数值计算结果进行动物和临床实验研究是十分必要的.      

Pore size control of Pitch-based activated carbon fibers by pyrolytic deposition of propylene

In this paper, we attempted to narrow the pore size of Pitch-based activated carbon fiber (Pitch-ACF) by chemical vapor deposition (CVD) of propylene at 700 °C. The BET equation was used to estimate the specific surface areas. The micropore volumes were determined using DR equation, t-plot and _s-plot, and mesopore surface areas were determined by t-plot and _s-plot. The pore size distribution (PSD) of micropores and mesopore was investigated by micropore analysis method (MP method) and MK method, respectively. The relation between the graphite-like crystal interlayer distance and pore size was analyzed by X-ray diffraction (XRD). The results showed that the pore size of Pitch-ACF was gradually narrowed with increasing deposition time. The catalytic activation of Ni was attempted when Pitch-ACF was modified simultaneously by pyrolysis of propylene. The results obtained from the analysis of PSD of micropores, mesopores and macropores in Ni–P-ACF by density function theory (DFT) showed that the pore structure and surface chemistry were greatly changed due to introducing nickel catalyst.     

套代数上保秩一幂零性的可加映射

${\cal N}$和${\cal M}$分别是实或复Banach空间$X$ ($\dim X >5$)和$Y$中的两个套且Alg${\cal N}$和Alg${\cal M}$分别是与套${\cal N}$和${\cal M}$相关的套代数.符号Alg加映射;秩一幂零算子;套代数Additive map,Rank one nilpotent operator,Nest algebra国家自然科学基金;清华大学校科研和教改项目;教育部高等学校博士点教育基金;国家自然科学基金;山西省自然科学基金2005-02-082007年4月25日${\cal N}$和${\cal M}$分别是实或复Banach空间$X$ ($\dim X >5$)和$Y$中的两个套且Alg${\cal N}$和Alg${\cal M}$分别是与套${\cal N}$和${\cal M}$相关的套代数.符号Alg加映射;秩一幂零算子;套代数Additive map,Rank one nilpotent operator,Nest algebra国家自然科学基金;清华大学校科研和教改项目;教育部高等学校博士点教育基金;国家自然科学基金;山西省自然科学基金2005-02-082007年4月25日令N和M分别是实或复Banach空间X(dim X>5)和Y中的两个套且AlgN和AlgM分别是与套N和M相关的套代数．符号AlgFN表示AlgN中所有有限秩算子全体．设Φ:AlgFN→AlgFM是可加映射,且值域包含AlgFM中的所有秩一幂零元．如果Φ-双边保秩一幂零性,作者证明了存在一个域自同构τ及τ-线性算子A和C使得要么对所有的秩一幂零元x(?)f∈AlgFN,Φ(x(?)f)=Ax(?)Cf,要么对所有的秩一幂零元x(?)f∈AlgFN,Φ(x(?)f)=Af(?)Cx．特别地,当X和Y是Hilbert空间且Φ是连续映射时,作者得到这类可加映射Φ的完全刻画．