表面等离极化激元对电荷输运影响的自洽场理论研究Ⅱ——MIM体系分子轨道场的计算与分析

采用自洽场方法计算MIM体系在电场作用下分子场系数、态密度和局域电子态密度的变化.结果表明，分子场系数分布呈现弦函数形式；随电场增大，能带向深能量延伸并且能级峰间分离的更明显，以及构成电流通道的3d_m群原子轨道交叠态的重叠量增大，提高 了电荷输运的能力.该分析为探讨SPP对电荷输运影响的建立奠定了基础. 关键词： 分子轨道场系数 电流通道 态密度 局域电子态密度     

Anisotropic defect reduction in non-polar a-plane GaN grown by hydride vapor phase epitaxy on maskless patterned templates

Several non-polar a-plane GaN films had been grown by hydride vapor phase epitaxy (HVPE) on different designed metal organic chemical deposition (MOCVD) GaN templates, which exhibited various ridge-like sidewall facets surface morphologies. The templates induced a lateral growth at the early stage of the HVPE growth, and resulted in a kind of maskless epitaxy lateral overgrown (ELO) process. It is found that the dislocation reduced differently along [1 0 0 0] and [] directions in these HVPE a-plane GaN layers. In [0 0 0 1] direction, the dislocation reduction resulted from the optimal surface roughness value of the template. In [] direction, the inclined facet might be a main factor for the dislocation reduction in HVPE-GaN films. The maskless ELO process had a significant influence on decreasing the dislocation density.     

Structure evolution and stoichiometry control of Pb(Zr, Ti)O3 thick films fabricated by electrospray assisted vapour deposition

Well-crystallized and stoichiometric Pb(Zr, Ti)O₃ (PZT) films, typically ∼5 μm thick, with pure perovskite-type rhombohedral structures have been successfully prepared via an electrospray assisted vapour deposition (ESAVD) method. Control of the deposition temperature within a narrow range of 300-400 °C resulted in films with the most desirable phases. PZT films with close stoichiometric match with the expected composition ratio and uniform element distribution were obtained by adding the appropriate levels of excess Pb in the precursor solutions. The annealed films were uniform, dense, compact and adherent to the substrates. The dielectric constant, ?_r, and loss tangent, tan δ, of the fabricated PZT films measured at 10 kHz were 442 and 0.09, respectively. The ESAVD deposited PZT films showed a remanent polarization, P_r, of 15.3 μC/cm² and coercive field, E_c, of 86.7 kV/cm. These results demonstrate the clear potential of the ESAVD method as a promising technique for the fabrication of thick PZT films.     

频闪及Matlab技术验证机械能守恒实验装置

利用摄像头频闪技术及Matlab软件组装了一个利用单摆验证机械能守恒的实验装置,主要解决学生在缺乏打点计时器的情况下,利用简便设备进行探究的难题,并将验证推广到二维.利用数据采集量大的优点,解决了传统实验只能验证机械能相等而不能验证机械能守恒的问题.     

有耗异向介质层覆盖普通介质圆柱电磁特性的研究

研究了线电流源平行放置在有耗异向介质层覆盖的无限长介质圆柱附近模型的电磁特性.首先,提出电磁模型并给出此电磁模型的精确解.其次,利用精确解进行数值计算,得到不同电磁参数情况下该电磁模型的近场分布图形,并通过方向性系数和归一化辐射阻抗研究其远场特性.由于有耗异向介质的负折射特性和损耗的同时作用,相比于无耗异向介质层以及有耗普通介质层,得到了有耗异向介质层覆盖普通介质圆柱模型在近场和远场特性上极为不同的电磁特性. 关键词： 线电流源 异向介质 方向性系数 辐射阻抗     

An efficient Bi(NO<Subscript>3</Subscript>)<Subscript>3</Subscript> · 5H<Subscript>2</Subscript>O catalyzed multi component one-pot synthesis of novel Naphthyridines

An efficient and environmentally friendly multicomponent synthesis of substituted 1,8-naphthyridines catalyzed by bismuth(III) nitrate pentahydrate [Bi(NO(3))(3) . 5H(2)O] under solvent-free microwave irradiation is described. This procedure has such advantages as short reaction time, high yields, and simple workup. The catalyst could be reused several times, keeping its initial activity recycled reactions.     

Predictions and experimental studies of the tail pipe noise of an automotive muffler using a one dimensional CFD model

The tail pipe noise from a commercial automotive muffler was studied experimentally and numerically under the condition of wide open throttle acceleration in the present research. The engine was accelerated from 1000 to 6000 rpm in 30 s at the warm up condition. The transient acoustic characteristics of its exhaust muffler were predicted using one dimensional computational fluid dynamics. To validate the results of the simulation, the transient acoustic characteristics of the exhaust muffler were measured in an anechoic chamber according to the Japanese Standard (JIS D 1616). It was found that the results of simulation are in good agreement with experimental results at the 2nd order of the engine rotational frequency. At the high order of engine speed, differences between the computational and experimental results exist in the high revolution range (from 5000 to 6000 rpm at the 4th order, and from 4200 to 6000 rpm at the 6th order). According to these results, the differences were caused by the flow noise which was not considered in the simulation. Based on the theory of one dimensional CFD model, a simplified model which can provide an acceptable accuracy and save more than 90% of execution time compared with the standard model was proposed for the optimization design to meet the demand of time to market.     

Dynamics of remote entanglement in one-dimensional Ising chains with Dzyaloshinskii-Moriya interactions

With the introduction of Dzyaloshinskii-Moriya (DM) interaction, dynamics of the remote entanglement in one-dimensional Ising chains is investigated. It is found that the DM interaction can excite the remote entanglement from an initial Néel state. For a given strength of DM interaction, the concurrence between the end spins oscillates and decreases simultaneously with the increase of the chain’s length, and drops to zero at a critical length. For the chains with two and three spins, it is very interesting that the dynamics of the staggered magnetization (or the chiral parameter) can be used to qualitatively estimate the evolution of the remote concurrence between the end spins. At last, we discuss the generation of W state from the Ising chain with DM interactions, and it is obtained that W state can only be prepared in the three-qubit and four-qubit chains with a specific strength of DM interaction.     

The characteristics of self-assemble N2O monolayer

The first-principle technique has been employed to determine the atomic structure of nitrous oxide (N₂O) monolayer. The potential structures of N₂O monolayer have been proposed. The calculation shows that the monolayer is a self-assembly system, in which the basic structure unit is the dislocated molecular chain.