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排序方式: 共有1185条查询结果,搜索用时 15 毫秒
121.
R. Dietsch Th. Holz H. Mai M. Panzner S. Völlmar 《Optical and Quantum Electronics》1995,27(12):1385-1396
The conventional thin-film deposition equipment of pulsed laser deposition (PLD) has been modified for the preparation of individual thin solid films and nanometer-layer stacks of uniform thickness across 100-mm substrates. The planar target configuration was replaced by a cylindrical one and the target motion regime has been improved to provide precise spatial control of the plasma plume orientation. During thin-film deposition, substrate translation is preferred instead of the usual rotation technique. With this arrangement the emission characteristic of the plasma source can be computer controlled and the desired coating can be tailored via a stepper-motor-driven manipulator for the desired layer thickness profile across an extended substrate. Thus, for example, a homogeneous film thickness is obtained even for lower target/substrate distances, and an appropriate deposition rate can be maintained. In a second version, this cylinder geometry principle of plasma plume control by target surface morphology is extended to a spatial solution. The hemispherical target surface becomes the basic element for inside-wall coating of tubes or even of more complex hollow bodies. First applications of the equipment are explained and compared with typical results of the conventional technique. 相似文献
122.
A bifurcation-based decohesion model for simulating the transition from localization to decohesion with the MPM 总被引:2,自引:0,他引:2
Z. Chen L. Shen Y.-W. Mai Y.-G. Shen 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2005,56(5):908-930
Based on recent experimental observations on the formation of localization before delamination, a bifurcation-based decohesion approach is proposed in this paper to simulate the transition from localization to decohesion involved in the delamination process of compressed films. The onset and orientation of discontinuous failure are identified from the discontinuous bifurcation analysis. A discrete constitutive model is then formulated based on the bifurcation analysis to predict the evolution of material failure as decohesion or separation of continuum. The Material Point Method, that does not employ fixed mesh-connectivity, is developed as a robust spatial discretization method to accommodate the multi-scale discontinuities involved in the film delamination. To demonstrate the potential of the proposed approach, a parametric study is conducted to explore the effects of aspect ratio and failure mode on the evolution of failure patterns under different boundary conditions, which provides a better understanding on the physics behind the film delamination process.Received: January 16, 2003; revised: August 11, 2003 相似文献
123.
Qing‐Xin Zhang Zhong‐Zhen Yu Mingshu Yang Jun Ma Yiu‐Wing Mai 《Journal of Polymer Science.Polymer Physics》2003,41(22):2861-2869
Nylon‐66 nanocomposites were prepared by melt‐compounding nylon‐66 with organically modified montmorillonite (MMT). The organic MMT layers were exfoliated in a nylon‐66 matrix as confirmed by wide‐angle X‐ray diffraction (WAXD) and transmission electron microscopy. The presence of MMT layers increased the crystallization temperature of nylon‐66 because of the heterogeneous nucleation of MMT. Multiple melting behavior was observed in the nylon‐66/MMT nanocomposites, and the MMT layers induced the formation of form II spherulites of nylon‐66. The crystallite sizes L100 and L010 of nylon‐66, determined by WAXD, decreased with an increasing MMT content. High‐temperature WAXD was performed to determine the Brill transition in the nylon‐66/MMT nanocomposites. Polarized optical microscopy demonstrated that the dimension of nylon‐66 spherulites decreased because of the effect of the MMT layers. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 2861–2869, 2003 相似文献
124.
Haiyan Hong Yiyong Mai Yongfeng Zhou Deyue Yan Yan Chen 《Journal of polymer science. Part A, Polymer chemistry》2008,46(2):668-681
A novel amphiphilic thermosensitive star copolymer with a hydrophobic hyperbranched poly (3‐ethyl‐3‐(hydroxymethyl)oxetane) (HBPO) core and many hydrophilic poly(2‐(dimethylamino) ethyl methacrylate) (PDMAEMA) arms was synthesized and used as the precursor for the aqueous solution self‐assembly. All the copolymers directly aggregated into core–shell unimolecular micelles (around 10 nm) and size‐controllable large multimolecular micelles (around 100 nm) in water at room temperature, according to pyrene probe fluorescence spectrometry and 1H NMR, TEM, and DLS measurements. The star copolymers also underwent sharp, thermosensitive phase transitions at a lower critical solution temperature (LCST), which were proved to be originated from the secondary aggregation of the large micelles driven by increasing hydrophobic interaction due to the dehydration of PDMAEMA shells on heating. A quantitative variable temperature NMR analysis method was designed by using potassium hydrogen phthalate as an external standard and displayed great potential to evaluate the LCST transition at the molecular level. The drug loading and temperature‐dependent release properties of HBPO‐star‐PDMAEMA micelles were also investigated by using indomethacin as a model drug. The indomethacin‐loaded micelles displayed a rapid drug release at a temperature around LCST. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 668–681, 2008 相似文献
125.
For almost twenty years, the Ford-Johnson algorithm for sortingt items using comparisons was believed to be optimal. Recently, Manacher was able to show that the Ford-Johnson algorithm is not optimal for certain ranges of values oft. In this paper, we present some new algorithms which achieve much stronger results compared to Manacher's algorithms. 相似文献
126.
127.
芳香族共聚酯液晶的椭圆偏振光谱与光学性质的研究 总被引:1,自引:0,他引:1
应用自动化椭圆偏振光谱和紫外-可见光谱表征了两种芳香族共聚酯液晶的光学性质,发现由于分子结构和受激发电子振动跃迁的不同,使共聚酯液晶薄膜具有不同的折射率变化,产生不的同光学色散现象。 相似文献
128.
Kumondai K Toyoda M Ishihara M Katakuse I Takeuchi T Ikeda M Iwamoto K 《The Journal of chemical physics》2005,123(2):24314
The reaction mechanisms of silver trimer cation, Ag3+, with 12-crown-4 (12C4) were studied experimentally and theoretically. Using a cylindrical ion trap time-of-flight mass spectrometer, gas-phase ion/molecule reactions of Ag3+ with 12C4 were observed. Metal-ligand complexes of [Ag(12C4)]+, [Ag3(12C4)]+ and [Ag3(12C4)2]+, and of [Ag(12C4)2]+ and [Ag3(12C4)3]+, were observed as the reaction intermediates and terminal products, respectively. The formations of the [Ag12C4]+ and [Ag(12C4)2]+ complexes indicated that the neutral dimer (Ag2) had been eliminated from the trimer cation. From the results of ab initio calculations at the HF/LanL2DZ level of theory and the experiments, it is suggested that three 12C4 molecules can attach to Ag3+ through consecutive reactions and that neutral Ag2 can be easily eliminated from [Ag3(12C4)]+. 相似文献
129.
130.
Xinjian Yi Zhihong Mai Xinrong Zhao Fangqiao Zhou Luqin Liu 《International Journal of Infrared and Millimeter Waves》1996,17(4):705-710
8-element linear array IR detectors based on high Tc superconducting films have been fabricated. The thin films were deposited by magnetron sputtering onZrO
2 substrates and patterned by standard photolithographic technique forming microbridge structure. An average detectivity of 1.85 × 109
cmHz
1/2 W–1 with a variance of less than 20% in the detector-to-detector detectivity of the array has been obtained at the operating temperature of 84K. A bolometric response mechanism has been discussed. 相似文献