负载型廉价金属催化剂在低温催化氧化甲醛中的应用

甲醛是室内常见的挥发性有机污染物之一,长期接触会严重危害人体健康.负载型廉价金属催化剂在甲醛去除和实际应用方面表现出优异性能,引起研究人员的广泛关注.本文阐述了低温条件下负载型廉价金属催化剂在甲醛热催化氧化、光催化氧化和等离子协同催化氧化方面的研究进展,介绍了甲醛低温催化的影响因素,并讨论了反应机理.反应条件、载体类型...     

双极性固态直线变压器驱动器的研制

在针对脉冲电磁场肿瘤消融的应用场合,双极性脉冲比单极性脉冲效果更均匀,而要产生ns级前沿的双极性高压纳秒或亚微秒脉冲难度大,电磁干扰强,控制要求更高。设计了一台双极性全固态直线型变压器驱动源(SSLTD),双极性SSLTD由结构完全相同的LTD模块经过副边绕组反向串联构成,在负载上实现双极性窄脉冲。双极性SSLTD输出波形稳定的脉冲的关键在于磁芯复位,通过电阻负载实验,重点对比分析了复位电流的形式对复位效果的影响,以及采用直流复位时幅值、脉宽、正负脉冲时间间隔、单级模块中开关管并联数量、复位电流大小对双极性SSLTD输出的影响。实验结果表明,所设计的双极性SSLTD能够在500 Ω负载上稳定产生重频双极性纳秒脉冲,输出电压0～±5 kV可调,脉宽200～400 ns可调,正负脉冲时间间隔0～1 ms可调,上升沿和下降沿20～50 ns;反向串联的直流复位电路结构简单、复位效果好。该脉冲源使用模块化设计,结构紧凑,电气绝缘要求较低,可灵活输出双极性、正极性与负极性高压亚微秒脉冲。     

Enhanced slow light propagation in photonic crystal waveguides using angular properties of scatter elements

Applicability of the angular properties of scatter elements as a tool to achieve improved slow light performance with small group velocity dispersion and large bandwidth in photonic crystal waveguides is investigated. A polyatomic photonic crystal waveguide, including two scatter elements with different geometrical shapes in each primitive cell, is proposed to investigate the feasibility of our method. Numerical results show that a versatile control of the dispersion relation of slow light modes, with large normalized delay-bandwidth products ranging from 0.2085 to 0.3394, can be obtained using a unique geometrical parameter.     

Fibrous Networks with Incorporated Macrocycles: A Chiral Stimuli‐Responsive Supramolecular Supergelator and Its Application to Biocatalysis in Organic Media

A new and versatile, crown ether appended, chiral supergelator has been designed and synthesized based on the bis‐urea motif. The introduction of a stereogenic center improved its gelation ability significantly relative to its achiral analogue. This low‐molecular‐weight gelator forms supramolecular gels in a variety of organic solvents. It is sensitive to multiple chemical stimuli and the sol–gel phase transitions can be reversibly triggered by host–guest interactions. The gel can be used to trap enzymes and release them on demand by chemical stimuli. It stabilizes the microparticles in Pickering emulsions so that enzyme‐catalyzed organic reactions can take place in the polar phase inside the microparticles, the organic reactants diffusing through the biphasic interface from the surrounding organic phase. Because of the higher interface area between the organic and polar phases, enzyme activity is enhanced in comparison with simple biphasic systems.