利用直接核反应研究轻丰中子核的奇特结构

直接核反应(包括弹性散射、非弹性散射、转移反应等)是研究丰中子核奇特结构的常用实验手段之一。以6,8He、11Li、11,12Be、14,15B、15,16C等N=8附近核的结构研究为例,综述了如何利用这几种反应从实验上研究丰中子核的奇特结构。利用6,8He,11Be等晕核在质子和氘靶上的弹性散射数据,拟合得到了这些反应体系的有效相互作用(光学势)。利用16C在质子和氘靶上的非弹性散射数据,抽取了16C 的形变参数,结果表明16C的形变不可忽略。利用单核子转移反应,定量研究了8He, 11,12Be等丰中子核基态及低占据态中的p-,s-,以及d-波成分的强度。结果表明:8He基态中的4个价中子,除了可以构成正常的 (0p_3/2)4 组态外,还有一定的几率构成($ 0 p_{3/2} $)2(0p_1/2)2组态;12Be的基态以d波闯入为主,而其临近的11Be的基态以s波闯入为主。     

The g-ZnO/Hf2CO2 vdW heterostructure: A novel two-dimensional material for sunlight-driven photocatalytic water splitting

In this work, by first-principles calculations, we investigate the structural, photoelectric, and catalytic properties of g-ZnO/Hf₂CO₂ vdW heterostructures to explore highly efficient photocatalysts of water splitting. Results show that the AA-stacking g-ZnO/Hf₂CO₂ vdW heterostructure (AA-HS) with an indirect bandgap of 1.738 eV has a typical type-II band alignment, which is benefit to effectively separate the photogenerated carriers into different layers and prevent their recombination. The conduction band minimum (CBM) and valence band maximum (VBM) of AA-HS straddling the water redox potentials makes it satisfies the requirements of photocatalytic water splitting at pH = 7. In addition, to evaluate the photocatalytic performance of AA-HS during oxidation evolution reaction (OER) process in water splitting, we calculated the change of Gibbs free energies of the intermediates on heterostructure under different conditions. Results show the Gibbs free energy decreases continuously at pH = 7 and U = 1.93 V. What's more, the AA-HS has good sunlight-absorption ability. External biaxial strain is not conducive to improving catalytic performance of AA-HS.     

胶束毛细管电泳在线扫集技术同时分离测定穿心莲内酯和脱水穿心莲内酯的研究

采用胶束毛细管电泳在线扫集技术分离测定了中药穿心莲中脱水穿心莲内酯和穿心莲内酯.电泳条件:以20 mmol/L H3BO310 mmol/L NaH2PO4-50mmol/L SDS(含体积分数20%甲醇,pH 2.4)为电泳运行缓冲溶液,未涂层石英毛细管(58 cm×50 μm i.d.,有效长度为41.2 cm)为分离通道,重力进样,进样高度为11 cm,-20 kV恒压,检测波长为246 nm.富集倍数可以达到200倍以上.在5.70～91.20 mg/L,和3.96～31.68 mg/L范围内呈良好的线性关系,对两种内酯分别进行了定量分析.加标平均回收率脱水穿心莲内酯为100.80%,穿心莲内酯为98.06%.     

拟半(E,F)}——凸函数及拟半(E,F)——凸规划的性质

简、胡及唐等(Int. J. Pure Appl. Math., 2004, 14(4): 439-454)于2004年提出了拟半(E,F)--凸函数的概念. 本文进一步深入讨论拟半(E,F)--凸函数及与之相应的拟半(E,F)--凸规划的一些重要性质, 建立了此类广义凸性的若干重要结论.     

Preparation and formation mechanism of microporous spheric zinc phosphate

In this paper, we investigate the formation of microporous spheric zinc phosphate by anodization method. Zinc phosphate microporous spheres with diameters of 5–23 μm were prepared in H₃PO₄ and NH₄H₂PO₄ aqueous electrolyte when the applied voltage was 1 V. Microstructure was characterized by scanning electron microscopy. Composition and crystal structure were confirmed through energy dispersive spectrum and X-ray diffraction analysis. The formation mechanism of this special structure was also discussed in this paper.     

Synthesis and growth mechanism of zirconia nanotubes by anodization in electrolyte containing Cl−

The formation and growth of a self-organized zirconia porous layer can be achieved directly by anodization of Zr in chloride containing electrolytes. The morphology of the porous layers is affected by electrochemical conditions such as Cl⁻ concentration. Zirconia nanotubes with diameters ranging from 250 to 300 nm and a length of 33 μm were formed under proper conditions. The nanotubes have smooth and straight walls. The composition of the nanotubes was characterized by using an energy dispersive spectrometer. Selected area electron diffraction investigation reveals that the as-anodized zirconia nanotubes have an amorphous structure. Crystal phase transition and structural stability of the ZrO₂ nanotubes after heat treatment were characterized. A possible growth mechanism is presented.     

Photoelectrocatalytic Oxidation of Glutathione Based on Porous TiO(2)-Pt Nanowhiskers

The performance of TiO(2) nanoparticles is extremely attractive in various areas of chemical and biochemical engineering as they can effectively work by combining the photocatalytic property with various superior properties of the related nanostructure. The relevant photoelectrochemical detection has attracted considerable interest and shown potential applications in a wide range of areas. In this study, we have prepared new nanowhiskers of platinum-doped titanium dioxide (TiO(2)-Pt), which could be further used to fabricate a novel nanointerface for the sensitive detection of biomolecules including glutathione (GSH). Our observations demonstrate that the sensitive TiO(2)-Pt nanowhiskers biointerface could be readily fabricated by casting the TiO(2)-Pt nanowhiskers suspension on a glassy carbon electrode (GCE), which could readily combine the photocatalytic and eletrocatalytic properties of TiO(2) nanocomposites to introduce a novel photoelectrocatalytic biosensor for GSH detection in real samples. Compared to other analysis strategies, the TiO(2)-Pt nanowhiskers-modified GCE showed a considerably high sensitivity for the detection of GSH due to the excellent photoelectrocatalytic ability of the porous TiO(2)-Pt nanowhiskers. Scanning electron microscopy (SEM), Raman spectroscopy, and electrochemical impedance spectroscopy have shown that Pt can readily blend with porous TiO(2) nanowhiskers and facilitate the relevant catalysis property of TiO(2), resulting in the enhanced photoelectrocatalytic effect. Thus, through the new strategy of the utilization of the excellent photoelectrocatalytic property of TiO(2)-Pt nanocomposites, it is possible to realize the rapid electrochemical detection of glutathione with high sensitivity, low cost, and good reproducibility.