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951.
A new lanostanoid, ganoderic acid SZ (1), isolated from a lipophilic extract of the fruiting body of Ganoderma lucidum, is a geometric Z-isomer of the known ganoderic acid S (2). The structure of ganoderic SZ (1) was deduced mainly by 1D and 2D NMR studies. During the course of this study, 12 known lanostanoids have also been isolated and characterized. 相似文献
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The mutual catalytic effect between iron(II) and antimony(III) on the chromium(VI)-iodide kinetic reactions has been studied by stopped-flow FIA. The concept of mutual catalytic coefficient is defined. The deviations from additive principles of absorbance within certain concentration ranges in previous procedures can be compensated effectively, by introducing the mutual catalytic coefficient into the simultaneous determination of a binary mixture with stopped-flow-FIA method. The linear concentration ranges have been enlarged, 0–3.5 g/ml Fe(II) and 0–3.7 g/ml Sb(III) compared with 0–1.2 g/ml Fe(II) and 0–2.0 g/ml Sb(III) without use of the coefficient. Iron and antimony contents in wastewater, a simulated sample and a zinc standard were determined, the recoveries and relative standard deviations being, respectively, 99.8–101.3% and 2.7–3.6% for iron and 95.4–100.3% and 2.3–5.3% for antimony compared with 95.2–98% and 3.0–4% for iron and 96–104% and 4.5–4.8% for antimony, assuming additivity. 相似文献
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957.
协同系数补偿—动力学两次标准加入法测定相互干扰的双组份 总被引:3,自引:2,他引:3
本提出了协同铲应补偿的动力两次标准加入法,讨论了相互干扰双组份同时测定的原理,研究了钙(Ⅵ)和钨(Ⅵ)催化的H2O2-I^-动力学反应,确定了同时测定条件:[H2O2]=9.×10^-3mol/L,[I^-]=1.0×10mol/L,PH3.0,25℃;为补偿钼和钨之间的协同催化效化效应,引入了协同催化系数的概念,有效地消除了吸江度对加和性的偏离。用本法同时测定样品中的钼和钨含量,回收率分别为9 相似文献
958.
Lunn MR Root DE Martino AM Flaherty SP Kelley BP Coovert DD Burghes AH Man NT Morris GE Zhou J Androphy EJ Sumner CJ Stockwell BR 《Chemistry & biology》2004,11(11):1489-1493
Most patients with the pediatric neurodegenerative disease spinal muscular atrophy have a homozygous deletion of the survival motor neuron 1 (SMN1) gene, but retain one or more copies of the closely related SMN2 gene. The SMN2 gene encodes the same protein (SMN) but produces it at a low efficiency compared with the SMN1 gene. We performed a high-throughput screen of approximately 47,000 compounds to identify those that increase production of an SMN2-luciferase reporter protein, but not an SMN1-luciferase reporter protein. Indoprofen, a nonsteroidal anti-inflammatory drug (NSAID) and cyclooxygenase (COX) inhibitor, selectively increased SMN2-luciferase reporter protein and endogenous SMN protein and caused a 5-fold increase in the number of nuclear gems in fibroblasts from SMA patients. No other NSAIDs or COX inhibitors tested exhibited this activity. 相似文献
959.
Guisun Zhuang Yinson Wang Min Zhi Wei Zhou Jianhua Yin Mingguang Tan Yuandi Cheng 《Journal of Radioanalytical and Nuclear Chemistry》1989,129(2):459-464
In this work, a simple group separation scheme based on extraction for NAA determination of trace of As, Cd, Hg, Cu and Zn in biological materials is described. For this purpose, zinc-diethyldithiocarbamate, Zn(DDC)2, and methyl isobutyl ketone-iodide have been chosen as reagents. The elements can be extracted successively and quantitatively from strong mineral acids without adjusting pH of the solution, and separated into two groups suitable for gamma-ray spectrometry. Samples of 100–200 mg dry weight were double-sealed into polyethylene bags and irradiated in a swimming pool reactor with a thermal neutron flux of 1013n·cm–2·s–1 for 44 hours. After a cooling period of 1–3 days, the samples were digested with microgram quantities of carrier in concentrated nitric acid and sulfuric acid at 150°C for 3.5 hours in a teflon bomb, then extracted as described above. The reliability of the analytical method was checked using reference materials Horse Kidney IAEA H-8, Human Hair NIES-5 and Tomato Leaves NBS-1573. Most of the results obtained for reference materials agreed with the certified values12. Chinese autopsy samples of hair and liver were presented. 相似文献
960.