带有齐次核的分数次积分交换子在Herz型Hardy空间上的有界性

算子[b,TΩ,α]表示由lipschitz函数b与带有齐次核的分数次积分算子TΩ,α生成的交换子．本文主要研究该交换子在Herz型Hardy空间上的有界性,得到了它是从HKq1^η,p（R^n）到Kq2^η,p（R^n）有界的．     

约束锥内部为空时向量均衡问题的最优性条件

在约束锥拓扑内部为空时利用集合的拟内部的概念给出了带约束的向量均衡问题的弱有效解的充分性和必要性条件。作为它的应用,还给出了带约束的向量变分不等式、向量优化问题的弱有效解的最优性条件。     

Directed Evolution of L-Aspartase by Mobility of Domains

To enhance the relative movement of domains, we inserted a random sequence of fifteen-peptide into the three domains of L-aspartase. By means of directed screening, the three isoforms of monomeric, dimmeric and tetrameric enzymes were obtained. Compared to the wild-type tetrameric L-asparease, these mutants remained 19. 7%, 42.3%, and 92% of the enzyme activity, respectively. Moreover, the examination of enzyme properties revealed that their kcat, and KM changed in varying degrees, and the optimum pH shifted towards acidic pH, while the dependence of the activity of enzyme on Mg^2 concentration and thermostability increased. Therefore this strategy provides a novel approach to directed evolution of enzymes.     

共轭聚合物中的量子限制效应和能量传递

在共混的两种共轭聚合物中,采用分子自级装技术制备了嵌段共轭聚合物量子线的异质结构,通过室温下吸收光谱、发光光谱和激姨光谱的研究证实了在这种嵌段共轭聚合物量子线的异质结构中存在很强的激子限制效应以及链内和链间的有效能量传递。     

液柱冲击式湿法脱硫装置的试验研究

本文提出了一种液柱冲击式湿法脱硫装置,对该装置的吸收段阻力特性和脱硫特性进行了试验研究,对试验结果进行了分析．分析发现了在塔内风速为２ｍ／ｓ～２．９ｍ／ｓ范围内,脱硫效率随塔内风速的增大而增加这一不同于其它装置的特点,得到了在塔内风速 ２．６ ｍ／ｓ,喷液量３０ｍ３／ｈ时脱硫效率高、阻力低这个比较经济的工况点．     

固相萃取-高效液相色谱法测定辣椒中甲基硫菌灵的残留量

甲基硫菌灵的化学名称为1,2-双(3-甲氧羰基-2-硫脲基)-苯,是内吸性杀菌剂,对蔬菜、水果、麦类等的真菌病害有良好的防治效果。它在生物体内和环境中不稳定,因而增加了测定的难度。已报道的分析方法有生物测定法、紫外分光光度法、气相色谱法和液相色谱法。这些方法的样品前处理繁琐,有机溶剂用量多,分析时间长。本文采用中性氧化铝固相萃取小柱净化样品,     

Cross-Section Measurements for Reactions on Platinum Isotopes in the Neutron Energy Range of 13.5 to 14.6MeV

Cross-sections for (n,2n) and (n,p) reactions have been measured on platinum isotopes at the neutron energies of 13.5 to 14.6 MeV using the activation technique. Data were reported for the following reactions: Pt(n,2n)197m+gPt,198Pt(n,2n)197mPt,192Pt(n,2n)191Pt, 194Pt(n,p)194Ir, 195Pt(n, p)195mIr, and 196Pt(n,p)196mIr. At the neutron energies of 13.5, 14.1 and 14.6 MeV, the cross sections in mb are 2038±159, 1919±73 and 1836±68 for 198Pt(n,2n)197m+gPt reaction; 974±37, 1055±39 and 1042±39 for 198Pt(n, 2n)197mPt reaction, respectively. The cross sections are 1680±103, 1810±67 and 2047±97 for 192Pt(n,2n)191Pt reaction, and 1.0±0.2, 1.6±0.2 and 1.8±0.2 for 195Pt(n, p)195mIr reaction, respectively, at energies of 14.1, 14.4 and 14.6MeV. At 14.1 and 14.4 MeV neutron energies, the cross sections are 3.8±0.4 and 5.4±0.5 for 194Pt(n,p)194Ir reaction. While, the data are (1.13±0.07) and (1.18±0.06) mb at energies of 13.5 and 14.4 MeV, respectively, for 196Pt(n,p)196mIr reaction.The neutron fluences were determined using the monitor reaction 93Nb(n, 2n)92mNb or 27Al(n, a)24Na. A comparison was made between the present cross sections and the collected data for the measured reactions.     

硅-硫团(SiS_2)_n~+(n=4,5)的结构和振动光谱的量子化学研究

用密度泛函（ＤＦＴ） 方法研究了硅硫团簇（ＳｉＳ２） ｎ＋（ ｎ ＝ ４ ,５） 的各种可能几何构型和电子结构,并计算了相应的振动光谱,得到了（ＳｉＳ２）ｎ＋ 的形成规律,即（ＳｉＳ２）ｎ ＋ 以硅、硫交错形成四元环链的形式增长．     

几种野生蔬菜重金属积累状况的调查研究

通过野外调查和室内分析测定,研究了几种常见野生蔬菜被铜、锌、铅、镉污染的状况。结果表明,在调查的16个样品中,铅的超标率达87.5%,镉的超标率是12.5%,铜和锌无超标现象。把野生蔬菜笼统地视为绿色食品是不确切的。     

基于对烟酰胺腺嘌呤二核苷酸光致电化学响应的胆汁酸传感器

将硫堇电聚合在多壁碳纳米管修饰电极上,然后在其表面固定3α-羟类固醇脱氢酶制备了胆汁酸传感器。 由于该传感器具有光敏和电子受体功能的光电界面,同时偶合了光致电化学效应和酶促反应,能与3α-羟类固醇脱氢酶催化胆汁酸产生的电子供体NADH(烟酰胺腺嘌呤二核苷酸)产生光致电化学反应,通过测量反应产生的光电流实现了对胆汁酸的检测。 探讨了胆汁酸传感器对胆汁酸的光致电化学响应机理,研究了多壁碳纳米管、酶固定量和硫堇初始浓度对光电极性能的影响。 在优化了电解质溶液pH值、辅酶用量和偏压的测试条件下,该传感器对胆汁酸的测定范围为1.80~40.0 μmol/L,检出限为0.67 μmol/L。 应用该传感器对药品胆酸钠片和人尿中胆汁酸进行的检测结果显示,相对标准偏差小于5.64%,加标回收率为96%~104%。 该传感器的制备和对胆汁酸的检测不需要除氧,有经济、简便等优点。