Induced helix formation and stabilization of a meta‐linked polymer containing pyridine units

A new amphiphilic polymer containing pyridine units was synthesized and characterized. The solvent‐dependent conformational transition from extended transoid to helical cisoid was studied by absorption, fluorescence, and ¹H NMR measurements. The polar solvent promoted the formation of the helical structures. A metal ion or H⁺ could stabilize the ordered structure. Moreover, the solvophobically induced helical structure was stable to environmental stimuli. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1403–1412, 2007.     

有阻塞的多级串联排队系统分析

对串联排队系统的应用及研究现状见文[1]，至今对它的研究一般仅限于两级．本文研究有N级，且每级容量都有限（因此会出现堵塞）的串联排队系统，首次技巧性地应用马尔可夫过程的状态空间，Q矩阵及解的表达等一系列的递推表示方法，得到了该系统的队长、忙期、逗留时间等分布的简明精确显式解．由于矩阵及递推的运算在计算机上容易实现，因此本文结论便于应用．     

差示-比色法测定乙醛肟含量的研究

乙醛肟水解产物羟胺将过量Fe^3 部分还原为Fe^3 ，再经邻菲罗啉显色，焦磷酸钾掩蔽剩余Fe^3 后，用差示－比色法进行乙醛肟的含量测定，取得了相当满意的结果。乙醛肟的平均回收率为99.96%（n=19，RSD＝0.7％）     

染料激光色立方模型定态性质的描述

应用一般形式的统一色噪声近似得到了洒料激光色立方模型光强分布的福克－普朗克方程。导出了光强分布函数，描述了光强涨落的实验和数值模拟结果以及色噪声对光强涨落的影响。     

Alkaline-solution-induced crystallization in poly(butylene terephthalate)

Subtle crystalline structure changes of poly(butylene terephthalate) (PBT) specimens treated with an alkali solution at room temperature were investigated with the grazing incidence X-ray diffraction (GIXRD) analysis method. A new phenomenon was found: the aqueous alkali solution induced the crystallization of the PBT polymer. Under the GIXRD analysis condition of an incidence angle of 1°, the penetration depth of the X-ray in PBT was less than 80 μm, and this agreed well with the rough theoretical estimation. The alkali solution adopted in this study was an aqueous sodium hydroxide solution, which had a concentration of 2.5 N. Dissolved quantities of the surface layers during the alkaline treatment were found to be small. No appreciable intrinsic viscosity change due to the alkaline treatment was detected. Possible factors that might contribute to the crystallization, such as water absorption and a chemical reagent effect, were examined, and a plausible explanation for the phenomenon was developed. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1938–1948, 2004     

Synthesis of an A'B' Precursor to Angelmicin B: Product Diversification in the Suárez Lactol Fragmentation

We describe a synthetic strategy for the angelimicin family of anthraquinoid natural products that involves converting a central highly oxygenated decalin intermediate to the AB and A'B' subunits. Herein, we report the synthesis of the bicyclic A'B' subunit that complements our earlier route to the tricyclic AB framework. The differentiating tact in the two syntheses focused on controlling the Suárez radical fragmentation of lactol precursors by modulating the substrate's structural rigidity. A more flexible lactol gave the tricyclic AB framework, whereas a more rigid substrate led to the bicyclic A'B' precursor, presumably through divergent pathways from the radical produced in the initial fragmentation step. These results establish a versatile advanced synthetic precursor for the angelimicins, and on a more general note, illustrate strategies for applying the Suárez fragmentation to diverse and complex molecular frameworks.     

京尼平交联低聚乙烯亚胺智能基因载体的制备与表征

使用京尼平与分子量为1800的超支化低聚乙烯亚胺在70％的乙醇溶液中反应,合成了具有荧光的交联型聚合物.利用核磁、凝胶渗透色谱、粒度仪、zeta电位仪和凝胶阻滞电泳对聚合物载体及其与DNA复合物颗粒进行了表征.研究表明,聚合物载体与DNA复合物颗粒粒径为120 ～150 nm,zeta电位为+20～25 mV,聚合物/...     

Influence of fluoroethylene carbonate on the solid electrolyte interphase of silicon anode for Li-ion batteries:A scanning force spectroscopy study

Silicon is an important high capacity anode material for the next generation Li-ion batteries.The electrochemical performances of the Si anode are influenced strongly by the properties of the solid electrolyte interphase(SEI).It is well known that the addition of flouroethylene carbonate(FEC)in the carbonate electrolyte is helpful to improve the cyclic performance of the Si anode.The possible origin is suggested to relate to the modification of the SEI.However,detailed information is still absent.In this work,the structural and mechanical properties of the SEI on Si thin film anode in the ethylene-carbonate-based(EC-based)and FEC-based electrolytes at different discharging and charging states have been investigated using a scanning atomic force microscopy force spectroscopy(AFMFS)method.Single-layered,double-layered,and multi-layered SEI structures with various Young’s moduli have been visualized three dimensionally at nanoscale based on the hundreds of force curves in certain scanned area.The coverage of the SEI can be obtained quantitatively from the two-dimensional(2D)project plots.The related analysis indicates that more soft SEI layers are covered on the Si anode,and this could explain the benefits of the FEC additive.     

Mechanism of field-like torque in spin-orbit torque switching of perpendicular magnetic tunnel junction

Science China Physics, Mechanics & Astronomy - The exact properties of dark matter remain largely unknown despite the accumulating evidence. If dark matter is composed of weakly interacting...     

气相色谱-质谱法测定蔬菜和水果中193种农药的残留量

在系统优化固相萃取吸附剂填料类型、洗脱溶剂种类及体积的基础上,建立了蔬菜和水果中193种农药残留的气相色谱-质谱(GC-MS)检测方法。样品经乙腈均质提取,C₁₈/PSA固相萃取柱净化,乙腈洗脱,GC-MS选择离子监测(SIM)模式检测,以磷酸三苯酯内标法定量。结果表明,130种农药在10~1000 μg/L、34种农药在20~1000 μg/L、26种农药在50~1000 μg/L、3种农药在100~1000 μg/L范围内线性关系良好,相关系数为0.9967~1.0000,方法检出限(以信噪比为3计)为0.04~8.26 μg/kg,添加回收率为71.6%~117.9%,相对标准偏差为3.0%~11.8%。该方法样品处理简单快速,相比其他多残留分析方法净化效果好,其灵敏度和选择性明显提高,适用于日常检测工作。