全文获取类型
收费全文 | 152篇 |
免费 | 10篇 |
国内免费 | 11篇 |
专业分类
化学 | 124篇 |
力学 | 12篇 |
综合类 | 2篇 |
数学 | 12篇 |
物理学 | 23篇 |
出版年
2024年 | 4篇 |
2023年 | 4篇 |
2022年 | 7篇 |
2021年 | 10篇 |
2020年 | 6篇 |
2019年 | 16篇 |
2018年 | 12篇 |
2017年 | 4篇 |
2016年 | 2篇 |
2015年 | 10篇 |
2014年 | 7篇 |
2013年 | 6篇 |
2012年 | 4篇 |
2011年 | 10篇 |
2009年 | 6篇 |
2008年 | 16篇 |
2007年 | 10篇 |
2006年 | 7篇 |
2005年 | 1篇 |
2004年 | 3篇 |
2003年 | 1篇 |
2002年 | 3篇 |
2001年 | 2篇 |
1999年 | 4篇 |
1998年 | 4篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1995年 | 5篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1985年 | 1篇 |
排序方式: 共有173条查询结果,搜索用时 0 毫秒
21.
Dihydroxyalkenes or their monoprotected alcohol derivatives are transformed to 5,5- and 5,6-spiroketals through a sequence involving an initial iodocyclization, followed by a silver triflate mediated spiroketalization step on the derived hydroxy-iodoether. 相似文献
22.
Three charge-transfer chromophore-terminated [2]rotaxanes were synthesized, using a high-yield [2 + 2]cycloaddition reaction in apolar solvent at room temperature. Two solvent-driving molecular shuttles were constructed, which exhibit distinct conformations in different solvent as a result of the shuttling movement of the macrocycle. 相似文献
23.
Zhang J Liu L Ma T Deng X 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2002,58(9):1915-1922
Measurements of rotational temperature as low as several hundred Kelvin have been measured using optical emission spectroscopy (OES) in nitrogen direct current (DC) glow discharge. The strongest band of the first negative system of nitrogen was chosen to deduce the rotational temperature at four different positions in nitrogen DC glow discharge, the back of cathode; cathode sheath; positive column; and anode glow. In positive column the rotational temperature increased apparently with the increasing discharge voltage from 500 to 1000 V when the pressure was 10 Pa. But with pressure of 20 Pa the rotational temperature in positive column increased slightly with the increase of discharge voltage. On the contrary, the rotational temperature in cathode sheath took reverse tendencies when the discharge voltage varies from 500 to 1000 V. As regard the anode glow, the rotational temperature at 10 Pa decreased with the increase of discharge voltage, but that at pressure of 20 Pa increased. We attribute the different tendencies of the rotational temperature to the different discharge statues at different pressures. When the discharge voltage varies from 500 to 1100 V, the discharge with pressure of 10 Pa is normal glow and that with 20 Pa is abnormal glow. 相似文献
24.
Jiang Xin Zhao Dongxiao Chen Jialiang Li Wenting Li Kexin Chen Chao 《Kinetics and Catalysis》2022,63(5):470-479
Kinetics and Catalysis - A ternary synergistic photocatalyst H3PW12O40/Pt/UiO-66-NH2 was successfully fabricated for the first time through a simple solvothermal synthetic strategy. We found that... 相似文献
25.
Hongxun Li Yimin Zhang Zhipeng Dong Jialiang Lv Chun Gu Peijun Yao Lixin Xu Rui Zhang Jingqin Su Wei Chen Yonggang Zhu Qiwen Zhan 《Annalen der Physik》2019,531(10)
An all‐fiber laser generating a cylindrical vector beam is proposed and demonstrated using a home‐made ring‐core Yb‐doped fiber (RC‐YDF). In the RC‐YDF, not only annular doping but also ring‐type beam pump is realized. This is believed to be the first report describing the realization of annular doping and ring‐type beam pump in active fiber simultaneously, which can enhance the efficiency for high‐order mode oscillation. This laser operates in the high‐order mode stably with a slope efficiency of as high as 55.7%. Cylindrical vector modes can be obtained easily through adjusting the polarization controller. This work may have great potential for providing high‐efficiency and high‐power cylindrical vector beam and vortex beam sources. 相似文献
26.
Zhenlu ShenXiaofei He Jialiang DaiWeimin Mo Baoxiang HuNan Sun Xinquan Hu 《Tetrahedron》2011,67(9):1665-1672
An efficient direct amination of quinazolin-4(3H)-ones has been developed. Treatment of quinazolin-4(3H)-ones with HCCP, DIPEA, and N-contained nucleophiles in acetonitrile could be able to form the corresponding 4-aminoquinazoline derivatives. Under the optimal reaction conditions, the amination products were achieved in good yields. 相似文献
27.
利用原位发射光谱表征和在线色谱分析,研究了甲醇介质阻挡放电脱氢偶联一步合成乙二醇反应中氢气的催化作用,考察了放电频率、甲醇和氢气进料量以及反应压力的影响.结果表明,在介质阻挡放电产生的非平衡等离子体中,H2不但能显著提高甲醇转化率,而且能显著提高乙二醇的选择性.在300°C,0.1 MPa,反应器注入功率为11 W,放电频率为12.0 k Hz,甲醇气体进料量为11.1 m L/min,氢气进料量为80–180 m L/min的条件下,甲醇转化率接近30%,乙二醇选择性大于75%.乙二醇收率与激发态氢原子的Hα谱线强度之间存在同增同减关系.由此推测,氢原子是起催化作用的活性氢物种.活性氢物种的生成途径是:基态氢分子通过与电子碰撞变成激发态,激发态氢分子通过第一激发态氢自动解离为基态氢原子.放电反应条件通过影响氢分子解离来影响氢气的催化作用.氢气在非平衡等离子体中显示的催化作用有可能为开辟新的化学合成途径提供重要机遇. 相似文献
28.
29.
Tracking the correct directions of monotonicity in multi-dimensional modeling plays an important role in interpreting functional associations. In the presence of multiple predictors, we provide empirical evidence that the observed monotone directions via parametric, nonparametric or semiparametric fit of commonly used multi-dimensional models may entirely violate the actual directions of monotonicity. This breakdown is caused primarily by the dependence structure of covariates, with negligible influence from the bias of function estimation. To examine the linkage between the dependent covariates and monotone directions, we first generalize Stein’s Lemma for random variables which are mutually independent Gaussian to two important cases: dependent Gaussian, and independent non-Gaussian. We show that in both two cases, there is an explicit one-to-one correspondence between the monotone directions of a multi-dimensional function and the signs of a deterministic surrogate vector. Moreover, we demonstrate that the second case can be extended to accommodate a class of dependent covariates. This generalization further enables us to develop a de-correlation transform for arbitrarily dependent covariates. The transformed covariates preserve modeling interpretability with little loss in modeling efficiency. The simplicity and effectiveness of the proposed method are illustrated via simulation studies and real data application. 相似文献
30.
Chun Tao Yue Yu Zhenzhen Chen Minxin Zhang Linlin Liu Zhihong Liu Jialiang Zhang Qian Zhang Hongtao Song 《中国化学快报》2018,29(12):1849-1852
The mesoporous silica materials had a high loading efficiency of sirolimus-SMEDDS. The length of the mesopores played a more important role than the pore diameter in drug dissolution and in vivo absorption. 相似文献