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101.
Summary Synthesis of acetanilide and analogs in good yields has been carried out ing amounts by reacting the aromatic amines with an acetic anhydride-acetic acid mixture. After TLC separation on the same vehicle, the products can be visualized by ultraviolet radiation or by color reactions. A procedure is also described to recover the acetanilides for obtaining infrared spectra by the attenuated total reflection technique.
For Part VIII see Mikrochim. Acta [Wien]1971, 662. 相似文献
Zusammenfassung Die Synthese von Acetanilid und analogen Substanzen wurde mit guter Ausbeute in Mikrogrammengen durchgeführt. Man läßt das aromatische Amin mit einer Mischung von Acetanhydrid und Essigsäure reagieren. Nach DC-Trennung in diesem Laufmittel kann man die Reaktionsprodukte im UV oder durch eine Farbreaktion sichtbar machen. Außerdem wurde ein Verfahren beschrieben, die Acetanilide für die IR-Spektroskopie nach der ATR-Methode wiederzugewinnen.
For Part VIII see Mikrochim. Acta [Wien]1971, 662. 相似文献
102.
Three polymers have been prepared by the condensation of benzo[1,2-b;5,4-b ′]-dipyrrolo-2,3,4,5-tetraone (I) with 1,2,4,5-tetraaminobenzene (II), 3,3 ′-diaminobenzidine (III), and 3,3 ′,4,4 ′-tetraaminodiphenyl ether (IV) in polyphosphoric acid (PPA) solution. The polymer structures were substantiated by comparison of their infrared and ultraviolet spectra with spectra of the model compounds and elemental analysis. The polymers had inherent viscosities of 0.86-0.90 (H2SO4) and thermal stabilities of 460°C and up to 700°C in air and nitrogen atmospheres, respectively. 相似文献
103.
Generalised diffusion processes are discussed using the theory of stochastic processes and several elementary results are proved for the survival probability of a pair of particles with an arbitrary potential. The reaction probability conditioned on reaction ultimately occurring is considered and its backward equation is determined. In the case of the Coulomb potential the probability is shown analytically to be identical in both the attractive and repulsive cases for a given absolute value of rc. The utility of this result in numerical solutions of the Debye—Smoluchowski equation is discussed. 相似文献
104.
Nmr and UV studies show that -dimethylamino--bromostyrene, I, undergoes SNl reaction in H2O and HClO4 (kSNl = 6 × 10?1sec.?1 at 25°). The vinyl cation has an extraordinary selectivity for capture by aromatic amines relative to H2O, including I itself to give the dimer II. 相似文献
105.
The first isocyanide ligated hexanuclear zirconium halide cluster is reported. The unoxidized [(Zr6Be)Cl12(CNXyl)6] (CNXyl = 2,6-dimethylphenyl isocyanide) was obtained from the solid state precursor K3Zr6Cl15Be by dissolution in CH3CN in the presence of CNXyl. The CNXyl ligands occupy all the axial positions on the cluster. The compound was recrystallized from CH2Cl2 and Et2O. [(Zr6Be)Cl12(CNXyl)6].2CH2Cl2 crystallizes in the space group
(#2) with a = 12.092(5) Å, b=12.728(5) Å, c = 14.102(8) Å, = 104.98(4)°, =107.11°, = 100.94°, V = 1919(2) Å3, Z = l, R = 11.3% and R
W
= 27.0%. For the bound isocyanide ligands, v
CN increases to 2140 cm–1. 相似文献
106.
Kokh DB Buenker RJ Liebermann HP Pichl L Whitten JL 《The journal of physical chemistry. B》2005,109(38):18070-18080
Configuration interaction calculations of the ground and excited states of the H2CO molecule adsorbed on the Ag(111) surface have been carried out to study the photoinduced dissociation process leading to polymerization of formaldehyde. The metal-adsorbate system has been described by the embedded cluster and multireference configuration interaction methods. The pi electron-attachment H2CO- and n-pi* internally excited H2CO* states have been considered as possible intermediates. The calculations have shown that H2CO* is only very weakly bound on Ag(111), and thus that the dissociation of adsorbed formaldehyde due to internal excitation is unlikely. By contrast, the H2CO- anion is strongly bound to Ag(111) and gains additional vibrational energy along the C-O stretch coordinate via Franck-Condon excitation from the neutral molecule. Computed energy variations of adsorbed H2CO and H2CO- at different key geometries along the pathway for C-O bond cleavage make evident, however, that complete dissociation is very difficult to attain on the potential energy surface of either of these states. Instead, reneutralization of the vibrationally excited anion by electron transfer back to the substrate is the most promising means of breaking the C-O bond, with subsequent formation of the coadsorbed O and CH2 fragments. Furthermore, it has been demonstrated that the most stable state for both dissociation fragments on Ag(111) is a closed-shell singlet, with binding energies relative to the gas-phase products of approximately 3.2 and approximately 1.3 eV for O and CH2, respectively. Further details of the reaction mechanism for the photoinduced C-O bond cleavage of H2CO on the Ag(111) surface are also given. 相似文献
107.
Jennifer Albaneze-Walker Jerry A. Murry Arash Soheili Scott Ceglia Shawn A. Springfield Charles Bazaral Peter G. Dormer David L. Hughes 《Tetrahedron》2005,61(26):6330-6336
An efficient synthesis of a potent PDE IV inhibitor 1 is described. The synthesis is highlighted by two practical and efficient catalytic reactions: a highly selective catalytic palladium mediated carbonylation of the pyridine side chain and an efficient palladium-catalyzed Suzuki-Miyaura coupling of a chloropyridine-N-oxide. 相似文献
108.
Jerry E. White Robert E. Singler 《Journal of polymer science. Part A, Polymer chemistry》1977,15(5):1169-1178
A series of polyarylaminophosphazene copolymers have been prepared and are described. In each preparation, two arylamines were allowed to competitively react with polydichlorophosphazene, and the substituent ratios of the resulting copolymers, determined by high-temperature 1H-NMR spectroscopy, generally reflect expected steric and electronic effects on the relative reactivities of the arylamines studied. The copolymers have intrinsic viscosities of 0.64–1.25 dl/g, glass transition temperatures of 75–104°C, and decomposition temperatures of 220–260°C. These properties, which are comparable to those of polyarylaminophosphazene homopolymers, are discussed in regard to what they may reflect about the structure of the polymers. 相似文献
109.
本文回顾了在羰基引发剂的作用下烯烃单体光引发聚合的最新机理。报道了有关多种当前通用的新型羰基引发剂的光物理和光化学的近期工作,其中包括 UV 吸收,发光光谱和闪光光解的研究。还报道了油溶性引发剂对丙烯酸丁酯的光聚合效应。证明油溶性引发剂实质上是经过三重态来起作用,其中包含一个从溶剂中攫取氢的引发步骤。对于硫杂蒽酮衍生物来说,它们从叔胺接受电子的能力及其光聚合效应之间有一定的关系。从闪光光解获得的证据说明在这种情况下存在着自由基阴离子,但是基于二苯酮和苯基酮的引发剂则没有。预料后者直接从胺攫氢是通过三重态羰基或是引发剂的自由基。有证据表明联苯甲酰主要是通过光裂解来起作用。水溶性硫杂蒽酮引发剂的作用主要是经过单重态,其中包含引发时攫氢一步。在这种情况下,自由基的形成不受氧的影响。 相似文献
110.
Cycloheptyne-dicobalt hexacarbonyl complexes, substituted by propargylic ether functions, undergo 2 + 2 + 2 cycloaddition reactions with alkynes to give tricyclic benzocycloheptanes; an all-intramolecular version of this transformation is also possible. 相似文献