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961.
A. O. Manyashin A. I. Fomenko V. N. Storozhenko N. T. Berberova 《Russian Journal of Electrochemistry》2003,39(11):1240-1244
Stoichiometry and kinetics of reactions of 2,6-diphenyl-4-chloropyrylium, 4-chloroflavylium, 4-bromoflavylium, and 4-iodoflavylium perchlorates with nucleophiles N,N-dimethylaniline and n-phenylenediamine are studied using cyclic voltammetry and spectroscopy. Nucleophilic substitution in these compounds proceeds via the formation of a charge-transfer complex, which converts into a radical ion pair as a result of the electron transfer. Heterolytic clevage of the C–Hal bond occurs at the stage of pyranyl (flavanyl) radical. 相似文献
962.
Xia Yin Weiguang Zhang Qijiao Zhang Jun Fan Chian Sing Lai Edward R. T. Tiekink 《应用有机金属化学》2004,18(3):139-140
The centrosymmetric structure of {Cd[S2CN(CH2Ph)2]2}2 features both bridging and chelating dithiocarbamate ligands so that a square pyramidal S5 coordination geometry results. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
963.
We introduce the notion of normal torsion of a surface at a point along a given direction in a Riemannian space. We give a complete classification of surfaces in four-spaces of constant curvature having zero normal torsion. 相似文献
964.
965.
I T Vieira P R Harper A K Shahani V De Senna 《The Journal of the Operational Research Society》2003,54(7):713-722
Mother-to-child transmission (MTCT) of HIV is the most significant source of HIV infection in children below the age of 15 years. In 2000 alone, about 600 000 new infections occurred, the vast majority from mothers living in developing countries who were not aware of their HIV-positive status. To date, at least 4.3 million children have died from AIDS. In this paper, we discuss the development of an operational model that can be used to evaluate intervention options for the prevention of MTCT of HIV. The problem was approached by defining suitable pregnancy risk groups, prevention options and the required model outputs to evaluate different intervention strategies. The method chosen to approach the problem was a discrete-event, three-phase simulation, built in Visual Basic, with a stochastic semi-Markov structure. The developed model takes individual pregnant women through each stage of their pregnancy, labour and birth. Different intervention strategies may be modelled at any time, including short-course antiretroviral drugs and cessation of breastfeeding. The model is demonstrated with data from Botswana, which has one of the highest HIV-infection rates in the world. 相似文献
966.
967.
Stephen P. Humphries 《Israel Journal of Mathematics》2004,143(1):189-222
We prove that (with two possible exceptions) the Hurwitz braid group action on the sequence of standard generators of an irreducible
Artin group has a finite orbit if and only if the Artin group is of finite type (i.e., the corresponding Coxeter group is
finite). 相似文献
968.
We study computable trees with distinguished initial subtree (briefly, I-trees). It is proved that all I-trees of infinite height are computably categorical, and moreover, they all have effectively infinite computable dimension. 相似文献
969.
Oleg Safronov 《Arkiv f?r Matematik》2004,42(2):363-377
We study the spectral properties of Jacobi matrices. By combining Killip's technique [12] with the technique of Killip and
Simon [13] we obtain a result relating the properties of the elements of Jacobi matrices and the corresponding spectral measures.
This theorem is a natural extension of a recent result of Laptev-Naboko-Safronov [17].
The author thanks Sergei Naboko for useful discussions and Barry Simon for pointing out the conjecture. 相似文献
970.
On the characterisation of paired monotone metrics 总被引:1,自引:1,他引:0
Paolo Gibilisco Tommaso Isola 《Annals of the Institute of Statistical Mathematics》2004,56(2):369-381
Hasegawa and Petz introduced the notion of paired monotone metrics. They also gave a characterisation theorem showing that
Wigner-Yanase-Dyson metrics are the only members of the paired family. In this paper we show that the characterisation theorem
holds true under hypotheses that are more general than those used in the above quoted references. 相似文献