首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   170篇
  免费   8篇
化学   151篇
晶体学   4篇
力学   1篇
数学   7篇
物理学   15篇
  2023年   1篇
  2022年   3篇
  2021年   4篇
  2020年   1篇
  2019年   3篇
  2018年   3篇
  2017年   1篇
  2016年   7篇
  2015年   2篇
  2014年   1篇
  2013年   6篇
  2012年   7篇
  2011年   13篇
  2010年   6篇
  2008年   11篇
  2007年   13篇
  2006年   13篇
  2005年   13篇
  2004年   10篇
  2003年   13篇
  2002年   5篇
  2000年   5篇
  1999年   1篇
  1996年   3篇
  1995年   2篇
  1993年   3篇
  1992年   6篇
  1991年   2篇
  1989年   1篇
  1988年   1篇
  1987年   1篇
  1985年   2篇
  1983年   1篇
  1980年   2篇
  1979年   1篇
  1978年   1篇
  1977年   2篇
  1976年   1篇
  1970年   1篇
  1968年   2篇
  1957年   1篇
  1939年   2篇
  1926年   1篇
排序方式: 共有178条查询结果,搜索用时 46 毫秒
101.
When dividing a 1- or 2-dimensional region according to a specified scheme, division points are continually created as the process continues. A measure results from assigning weights to each of these points. In the 1-dimensional setting, results concerning the distribution of division points are well known, and suggest how to study analogous processes in two dimensions. We explore two different division schemes on a triangular region and three different measures based on each subdivision, finding the limiting measures in each case.  相似文献   
102.
Bioassay-guided fractionation of the sub-Arctic ascidian Synoicum pulmonaria collected off the Norwegian coast led to the isolation of a novel family of brominated guanidinium oxazolidinones named synoxazolidinones A and B (1 and 2). The backbone of the compounds contains a 4-oxazolidinone ring rarely seen in natural products. The structure of the compounds was determined by spectroscopic methods. The synoxazolidinones exhibited antibacterial and antifungal activities.  相似文献   
103.
Foods are complex mixtures of lipids, carbohydrates, proteins, vitamins, organic compounds, and other naturally occurring substances. Sometimes added to this mixture are residues of pesticides, veterinary and human drugs, microbial toxins, preservatives, contaminants from food processing and packaging, and other residues. This milieu of compounds can pose difficulties in the analysis of food contaminants. There is an expanding need for rapid and cost-effective residue methods for difficult food matrixes to safeguard our food supply. Bioanalytical methods are established for many food contaminants such as mycotoxins and are the method of choice for many food allergens. Bioanalytical methods are often more cost-effective and sensitive than instrumental procedures. Recent developments in bioanalytical methods may provide more applications for their use in food analysis.  相似文献   
104.
Cationic oxorhenium salen complexes are prepared by the abstraction of bridging oxo ligands with [Et3Si][B(C6F5)4] and [Ph3C][B(C6F5)4]. These complexes catalyze the reduction of 2-butanone with Et3SiH under ambient conditions.  相似文献   
105.
Four rhodium dimers have been synthesized with a bridging diisocyanide ligand, dmb (2,2-dimethyl-1,3-diisocyanopropane): [Rh2(dmb)4](BPh4)2, [Rh2(dmb)4Cl2]Cl2, [Rh2(dmb)4I2](PF6)2, and [Rh2(dmb)2(dppm)2](BPh4)2 (dppm = bis(diphenylphosphino)methane). The complexes have been characterized by elemental analysis and mass spectrometry, as well as UV-visible, IR, and 1H NMR spectroscopies. X-ray crystal structures of the rhodium(I) complexes, [Rh2(dmb)4](BPh4)2 . 1.5CH3CN (3.2330(4), 3.2265(4) A) and [Rh2(dmb)2(dppm)2](BPh4)2.0.5CH3OH . 0.2H2O (3.0371(5) A), confirm the existence of short Rh...Rh interactions. The metal-metal separation for the rhodium(II) adduct, [Rh(2)(dmb)4Cl2]Cl2.6CHCl3 (2.8465(6) A), is consistent with a formal Rh-Rh bond. For the two luminescent rhodium(I) dimers and six previously investigated diisocyano-bridged dimers with and without dppm ligands, the intense spin-allowed dsigma-->psigma absorption band maximum shifts to longer wavelengths with decreasing Rh...Rh separation, and there is an approximate correlation between band energy and the inverse of the metal-metal separation cubed. Both [Rh2(dmb)4]2+ and [Rh2(dmb)4(dppm)2]2+ undergo oxidative addition in the presence of iodine. In the conversion of [Rh2(dmb)4]2+ to [Rh2(dmb)4I2]2+, the observed intermediate is tentatively assigned to a tetramer composed of two rhodium dimers. In the case of [Rh2(dmb)2(dppm)2]2+, no intermediate was detected.  相似文献   
106.
From four Arnica species (A. angustifolia Vahl ssp. attenuata (Greene) Maguire, A. lonchophylla Greene ssp. lonchophylla Maguire (flowerheads), A. chamissonis Less. ssp. foliosa (Nutt.) Maguire, A. montana L. (roots and rhizomes)) a total of twelve lignans of the furofuran-, dibenzylbutyrolactone- and dibenzylbutyrolactol-type were isolated. No report on lignans as constituents of Arnica species exists so far. Besides the known pinoresinol, epipinoresinol, phillygenin, matairesinol, nortrachelogenin and nortracheloside, six dibenzylbutyrolactol derivatives with different stereochemistry and substitution at C-9 were isolated and their structures elucidated by NMR spectroscopic and mass spectral analysis.  相似文献   
107.
The number of transversals in a Latin square   总被引:1,自引:0,他引:1  
A Latin Square of order n is an n × n array of n symbols, in which each symbol occurs exactly once in each row and column. A transversal is a set of n entries, one selected from each row and each column of a Latin Square of order n such that no two entries contain the same symbol. Define T(n) to be the maximum number of transversals over all Latin squares of order n. We show that for n ≥ 5, where b ≈ 1.719 and c ≈ 0.614. A corollary of this result is an upper bound on the number of placements of n non-attacking queens on an n × n toroidal chess board. Some divisibility properties of the number of transversals in Latin squares based on finite groups are established. We also provide data from a computer enumeration of transversals in all Latin Squares of order at most 9, all groups of order at most 23 and all possible turn-squares of order 14.  相似文献   
108.
We report a novel experimental approach to derive quantitative concentration map of light elements in whole cells by combining two complementary nano-probe methods: X-ray fluorescence microscopy (XRFM) and atomic force microscopy (AFM). The concentration is derived by normalizing point-by-point the elemental (here Mg) spatial distribution obtained by XRFM, by the thickness measured using AFM. The considerable difference between the elemental distribution and the concentration maps indicates that this procedure is essential to obtain reliable information on the role and function of elements in whole cells.  相似文献   
109.
Protein kinases are key mediators of cellular signaling, and therefore, their activities are tightly controlled. AGC kinases are regulated by phosphorylation and by N- and C-terminal regions. Here, we studied the molecular mechanism of inhibition of atypical PKCζ and found that the inhibition by the N-terminal region cannot be explained by a simple pseudosubstrate inhibitory mechanism. Notably, we found that the C1 domain allosterically inhibits PKCζ activity and verified an allosteric communication between the PIF-pocket of atypical PKCs and the binding site of the C1 domain. Finally, we developed low-molecular-weight compounds that bind to the PIF-pocket and allosterically inhibit PKCζ activity. This work establishes a central role for the PIF-pocket on the regulation of PKCζ and allows us to envisage development of drugs targeting the PIF-pocket that can either activate or inhibit AGC kinases.  相似文献   
110.
The use of semiconductor photocatalysis for treatment of water and air has been the topic of intense research activity over the past 20 years. This powerful process has also been extended to the disinfection of environments contaminated with pathogenic micro-organisms. This review summarizes recent developments concerned with the photocatalytic treatment of water contaminated with pathogenic micro-organisms presenting a potential hazard to animals and human beings.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号