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181.
Fabien Durola Jean-Pierre Sauvage Oliver S. Wenger 《Coordination chemistry reviews》2010,254(15-16):1748-1759
The use of 8,8′-diaryl-substituted 3,3′-biisoquinolines allows the construction of new multi-component assemblies that are inaccessible with the 2,9-diaryl-substituted 1,10-phenanthroline ligands previously developed by the Sauvage group. This is due to the sterically non-hindering nature of the new chelates, which makes three-component entanglements around octahedral metal centres such as iron(II), cobalt(II) and ruthenium(II) readily possible. Among the newly synthesized molecular assemblies are [3]rotaxanes and [3]pseudorotaxanes in which two molecular strings pass through a single macrocycle, as well as molecular shuttles that exhibit greatly improved shuttling kinetics when compared to previously investigated molecular machines that are based on copper(I)/copper(II) redox chemistry. 相似文献
182.
Two original dinuclear (LnYb, 3 and LnEr, 4) and one trinuclear CuIILnIIICuII (LnGd, 5) complexes derived from a polydentate non symmetrical Schiff base ligand H2L have been prepared. The ligand possesses two functions (phenol and oxime) able to coordinate the Ln ions, but structural studies (X-ray diffraction and powder X-ray diffraction) show that the CuII and LnIII ions are only bridged by the oximato (NO) pair. The missing phenoxo bridge is replaced by a surprising pseudo-bridge involving one oxygen atom of the nitrato anion linked to the Cu and Ln ions according to a η2: η1: μ mode. Although this latter contact has no role from the magnetic point of view, it introduces a large deformation of the unique bridging network. The CuYb complex 3 and the trinuclear CuGdCu complex 5 present antiferromagnetic interactions, with a JCuGd interaction equal to ?1.25 cm?1 in 5. The genuine single bridge can be considered as responsible for the antiferromagnetic character of the interaction. 相似文献
183.
Jean-Yves Raty Céline Otjacques Jean-Pierre Gaspard Christophe Bichara 《Solid State Sciences》2010,12(2):193-198
Ge1Sb2Te4 is one of the most commonly used phase change materials, due to the large optical and electrical contrast between a metastable crystalline phase and the amorphous phase. We use ab initio molecular dynamics to generate an amorphous Ge1Sb2Te4 structure. By analysing the distance distributions, we show that the structure can be analysed in terms of 21% of tetrahedrally coordinated Ge atoms and 79% of 3-fold Ge atoms. These are involved in distorted octahedral shells with bond length correlations that are similar to the a-GeTe structure as a consequence of a Peierls-distortion. The electronic properties are shown to be in reasonable agreement with the experiment with an electronic gap of 0.45 eV with. The optical conductivity curve is also in agreement with the experiment, with a maximal conductivity at an energy of ~3 eV. 相似文献
184.
Mamadalieva NZ Janibekov AA Girault JP Lafont R 《Natural product communications》2010,5(10):1579-1582
Chemical investigations of Silene viridiflora (L.) yielded a new ecdysteroid, 20-hydroxyecdysone 20,22-monoacetonide-25-acetate (1), and a known ecdysteroid, 2-deoxypolypodine B-3-beta-D-glucoside (2). The elucidation of the chemical structures was established by 1D and 2D NMR experiments. 相似文献
185.
This paper presents a mathematical design methodology for determining the shape of a trumpet air column that has near-perfect harmonicity, whose components are discontinuity-free, and whose input impedance peak heights are balanced over the playing range. The simulation model employed assumes linear wave propagation and uses cylindrical element discretization with a plane wave approximation. Acoustic measurements are made using a test set-up with an estimated relative measurement error of ±3 cents. Comparisons of measured results are given for the presented design (Macaluso trumpet) and the same trumpet air column with the bell replaced by a commercially used generic trumpet bell of unknown shape (Generic trumpet). For acoustic resonance modes 2-13 (233-1515 Hz), the measured root-mean-square (rms) harmonicity deviation is 5 cents for the Macaluso trumpet, whereas it is 18 cents for the Generic trumpet. However, considering the estimated measurement uncertainty, each of those deviations is somewhat over-stated. For that same range of resonances, the rms deviation between measured and calculated resonance frequencies for the Macaluso trumpet is 3 cents, thus validating the presented simulation model and equations. 相似文献
186.
Spectral Measures Associated with the Factorization of the Lebesgue Measure on a Set via Convolution
Let \(Q\) be a fundamental domain of some full-rank lattice in \({\mathbb {R}}^d\) and let \(\mu \) and \(\nu \) be two positive Borel measures on \({\mathbb {R}}^d\) such that the convolution \(\mu *\nu \) is a multiple of \(\chi _Q\) . We consider the problem as to whether or not both measures must be spectral (i.e. each of their respective associated \(L^2\) space admits an orthogonal basis of exponentials) and we show that this is the case when \(Q = [0,1]^d\) . This theorem yields a large class of examples of spectral measures which are either absolutely continuous, singularly continuous or purely discrete spectral measures. In addition, we propose a generalized Fuglede’s Conjecture for spectral measures on \({\mathbb {R}}^1\) and we show that it implies the classical Fuglede’s Conjecture on \({\mathbb {R}}^1\) . 相似文献
187.
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189.
Optimized conditions for copper-catalyzed N-arylation of methyl pyroglutamate are described. These studies permitted the synthesis of methyl N-naphthylpyroglutamate, which was then cyclized to a ketone. The known dehydration of amidoketones by PPA was extended to this new scaffold to lead to a novel condensed benzo[de]quinoline with potential antioxidative activity. 相似文献
190.
Anne-Marie Caminade Régis Laurent Cédric-Olivier Turrin Cyrille Rebout Béatrice Delavaux-Nicot Armelle Ouali Maria Zablocka Jean-Pierre Majoral 《Comptes Rendus Chimie》2010,13(8-9):1006-1027
This review emphasizes the role of phosphorus for the elaboration of dendrimers and of various highly sophisticated dendritic structures, and the invaluable role played by 31P NMR for their characterization and to ascertain their purity. A few properties, highlighting the importance of phosphorus are reported at the end of this review. 相似文献