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31.
P. Quint und H. J. Höhling 《Fresenius' Journal of Analytical Chemistry》1979,296(5):411-412
Ohne Zusammenfassung
Determination of calcium, magnesium, carbonate, and phosphate in biological materials相似文献
32.
Yang DQ Rochette JF Sacher E 《Langmuir : the ACS journal of surfaces and colloids》2005,21(18):8539-8545
The chemical and morphological modifications of multiwalled carbon nanotubes (MWCNTs), by 2 keV Ar(+) treatment, have been followed by field emission scanning (FESEM) and high-resolution transmission (HRTEM) electron microscopies and by X-ray photoelectron (XPS) and Raman spectroscopies. Morphological changes were followed, both in situ and on subsequent air exposure, and the data indicate that free radical defects, initially produced under low Ar(+) treatment doses ( approximately 10(13) ions/cm(2)), act as the nuclei for the formation of localized asperities that form along the walls of the CNTs. Continued treatment results in their stublike elongation that continues with further treatment, forming extensions under heavy treatment doses. The chemical changes that occur, on reaction with air, reveal that the defects initially created are secondary C atoms, formed when a single bond breaks; further treatment breaks an additional bond to form primary C atoms; free radical fragments, lost when the third bond breaks, condense on the free radical defects to form the asperities. The extent of primary and secondary C atoms, and thus their functionalization on air exposure, may be controlled by the extent of treatment, offering a method for the controlled surface functionalization of CNTs by low-energy Ar(+) treatment. 相似文献
33.
34.
With the advent of high-precision frequency combs that can bridge large frequency intervals, new possibilities have opened
up for the laser spectroscopy of atomic transitions. Here, it is shown that laser spectroscopic techniques can also be used
to determine the ground-state g factor of a bound electron. The proposal is based on a double-resonance experiment, where the spin state of a ground-state
electron is constantly being read out by laser excitation to the atomic L shell, while the spin flip transitions are being induced simultaneously by a resonant microwave field, leading to the detection
of the quantum jumps between the ground-state Zeeman sublevels. The magnetic moments of electrons in light hydrogen-like ions
could thus be measured with advanced laser technology. Corresponding theoretical predictions are also presented.
The text was submitted by the authors in English. 相似文献
35.
M. Vogel G. Birkl M. S. Ebrahimi D. von Lindenfels A. Martin G. G. Paulus W. Quint S. Ringleb Th. Stöhlker M. Wiesel 《Hyperfine Interactions》2015,230(1-3):65-71
We present two Penning trap experiments concerned with different aspects of the physics of extreme electromagnetic fields, the ARTEMIS experiment designed for bound-electron magnetic moment measurements in the presence of the extremely strong fields close to the nucleus of highly charged ions, and the HILITE experiment, in which well-defined ion targets are to be subjected to high-intensity laser fields. 相似文献
36.
37.
Photo-induced electron emission from 17beta-estradiol and progesterone and possible biological consequences 总被引:1,自引:0,他引:1
Getoff N Hartmann J Huber JC Quint RM 《Journal of photochemistry and photobiology. B, Biology》2008,92(1):38-41
It was established for the first time, that the sexual hormones 17beta-estradiol (17betaE2) and progesterone (PRG) are able to emit electrons from their excited single state in water-ethanol mixtures. The yield of the "solvated electrons" (e(s)(-)) depends on the substrate concentration, the ratio of water-alcohol-mixtures and the temperature. The e(s)(-) yield obtained from 17betaE2 is by two orders of magnitude higher than this of PRG. The possible relationship of the resulting hormone transients from 17betaE2 leading via specific metabolites to breast cancer is discussed. 相似文献
38.
Vasconcelos F Cristol S Paul JF Tricot G Amoureux JP Montagne L Mauri F Delevoye L 《Inorganic chemistry》2008,47(16):7327-7337
The assignment of high-field (18.8 T) (17)O MAS and 3QMAS spectra has been completed by use of first-principles calculations for three crystalline sodium phosphates, Na 3P 3O 9, Na 5P 3O 10, and Na 4P 2O 7. In Na 3P 3O 9, the calculated parameters, quadrupolar constant ( C Q), quadrupolar asymmetry (eta Q), and the isotropic chemical shift (delta cs) correspond to those deduced experimentally, and the calculation is mandatory to achieve a complete assignment. For the sodium tripolyphosphate Na 5P 3O 10, the situation is more complex because of the free rotation of the end-chain phosphate groups. The assignment obtained with ab initio calculations can however be confirmed by the (17)O{ (31)P} MAS-J-HMQC spectrum. Na 4P 2O 7 (17)O MAS and 3QMAS spectra show a complex pattern in agreement with the computed NMR parameters, which indicate that all of the oxygens exhibit very similar values. These results are related to structural data to better understand the influence of the oxygen environment on the NMR parameters. The findings are used to interpret those results observed on a binary sodium phosphate glass. 相似文献
39.
Hahn U Hirst AR Delgado JL Kaeser A Delavaux-Nicot B Nierengarten JF Smith DK 《Chemical communications (Cambridge, England)》2007,(46):4943-4945
Mixtures of an appropriate carboxylic acid and n-butylstannoic acid constitute modular gelation systems, in which the formation of a well-defined 'tin-drum' nanocluster subsequently underpins the hierarchical assembly of nanostructured fibres, which form self-supporting gel-phase networks in organic solvents. 相似文献
40.
Wiedemair J Serpe MJ Kim J Masson JF Lyon LA Mizaikoff B Kranz C 《Langmuir : the ACS journal of surfaces and colloids》2007,23(1):130-137
The volume phase transition (VPT) behavior of individual thermally responsive poly(N-isopropylacrylamide-co-acrylic acid) (pNIPAm-co-AAc) hydrogel microparticles was studied by in-situ dynamic mode atomic force microscopy (AFM) and force spectroscopy during heating and cooling cycles. Hydrogel samples were prepared by electrostatic immobilization of microparticles to amine-modified gold surfaces. The AFM studies of particle deswelling were performed by varying the force applied on the particles during imaging as a function of the geometry and material of the AFM probe. Aluminum-coated silicon cantilevers were found to influence substantially the behavior of the particles during the VPT, leading to a significant shape change. Low force impact magnetic excitation of the AFM probe (MAC mode) during dynamic mode measurements resulted in an undisturbed deswelling behavior enabling observation of the expected volume changes of the particles without significant tip-sample interaction. Hence, MAC-mode AFM was determined to be the most suitable technique for in-situ AFM studies on volume and shape changes at single hydrogel particles during VPT. Elasticity measurements performed at single particles at temperatures below and above the VPT revealed a 15-fold increase in the Young's modulus after passing the VPT, indicating the transition from a soft, swollen network to a stiffer, deswollen state. 相似文献