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81.
We provide numerically exact photoexcitation cross sections of rubidium Rydberg states in crossed, static electric, and magnetic fields, in quantitative agreement with recent experimental results. Their spectral backbone underpins a clear transition towards the Ericson regime, associated with a universal, fluctuating behavior of the cross section of strongly coupled, fragmenting quantum systems. 相似文献
82.
Intermodal dispersion between the supermodes of a directional coupler may induce undesirable pulse breakup in a sufficiently large device. When this happens the device will no longer exchange power between its arms, and the extinction ratio is completely canceled. It is shown that, by carefully designing the coupling area of the directional coupler, one may compensate for intermodal dispersion. The compensating device should accomplish three basic requirements: inverse intermodal dispersion, balanced coupling of each supermode, and maximum power transfer while preserving the sign of the slope of the coupling coefficient with frequency for multiplexing-demultiplexing applications. This structure is designed and optimized with a genetic algorithm. 相似文献
83.
We introduce the concept of topological finite-determinacy for
germs of analytic functions within a fixed ideal
I, which provides a notion of topological finite-determinacy
of functions with non-isolated singularities. We prove the following statement
which generalizes classical results of Thom and Varchenko: let
A be the complement in the ideal I of the space
of germs whose topological type remains unchanged under a
deformation within the ideal that only modifies sufficiently
large order terms of the Taylor expansion. Then A has infinite
codimension in I in a suitable sense. We also prove the
existence of generic topological types of families of germs of
I parametrized by an irreducible analytic set. 相似文献
84.
85.
Planar micropumps utilizing vortices shed by an oscillating ferromagnetic bar are presented. The movement of the bar is induced by magnetic coupling with an external spinning magnet. Thus, energy transfer is achieved without physical contact or need of any on-chip power source. To create vortices inside the chip, the Reynolds number is locally increased with the oscillation of the bar. The utilization of the vortices as a tool for efficient transfer of energy is inspired by the behaviour of swimming animals and flying insects in nature. The pumps operate in two different scales (milli-scale and micro-scale) in order to take advantage of both. Experiments are presented characterizing the pumps and their flow patterns. The range of operation of the pumps is from 3 microl min(-1) to 600 microl min(-1), though smaller flow rates are also possible. 相似文献
86.
For problems in the calculus of variations with
isoperimetric side constraints, we provide in this paper a set of
points whose emptiness, independently of nonsingularity assumptions,
is equivalent to the nonnegativity of the second variation along
admissible variations. The main objective of introducing a
characterization of this condition should be, of course, to obtain a
simpler way of verifying it. There are two other sets of points
available in the literature, introduced by Loewen and Zheng (1994)
and Zeidan (1996), for which this necessary condition implies their
emptiness. However, we show that verifying membership of these sets
may be more difficult than checking directly if that condition
holds. Contrary to this behavior, we prove that the desired
objective of characterizing that condition is achieved by means of
the set introduced in this paper. 相似文献
87.
Subías G García J Blasco J Grazia Proietti M Renevier H Concepción Sánchez M 《Physical review letters》2004,93(15):156408
We have investigated the charge ordering (CO) in magnetite below the Verwey transition. A new set of half-integer and mixed-integer superlattice reflections of the low-temperature phase have been studied by x-ray resonant scattering. None of these reflections show features characteristic of CO. We demonstrate the absence of CO along the c axis with the periodicity of either the cubic lattice q=(001) or the doubled cubic lattice q=(001/2). This result suggests that the Verwey transition is caused by strong electron-phonon interaction instead of an electronic ordering on the octahedral Fe atoms. 相似文献
88.
A method is proposed for designing a two-dimensional randomly rough Dirichlet surface that, when illuminated at normal incidence, scatters a scalar plane wave with a specified angular distribution of its intensity. The method is validated by computer simulation calculations. 相似文献
89.
Transient isotopic experiments reveal that the mechanism of N2O formation in the high-temperature NH3 oxidation over Pt-Rh gauze involves the reaction of adsorbed ammonia intermediate species (NHx) and NO. 相似文献
90.
Curutchet C Salichs A Barril X Orozco M Javier Luque F 《Journal of computational chemistry》2003,24(1):32-45
This study examines the transferability of fragmental contributions to the octanol/water partition coefficient. As a previous step, we report the parameterization of the AM1 and PM3 versions of the MST model for n-octanol. The final AM1 and PM3 MST models reproduce the experimental free energy of solvation and the octanol/water partition coefficient (log P(ow)) with a root-mean-square deviation of around 0.7 kcal/mol and 0.5 (in units of log P), respectively. Based on this parameterization, an NNDO-based procedure is presented to dissect the free energy of transfer between octanol and water in contributions directly associated with specific atoms or functional groups. The application of this procedure to a set of representative molecular systems illustrates the dependence of the log P(ow) fragmental contribution due to electronic, hydrogen bonding, and steric effects, which cannot be easily accounted for in simple additive-based empirical schemes. The results point out the potential use of theoretical methods to refine the fragmental contributions in empirical methods. 相似文献