Spin transfer torque in the semiconductor/ferromagnetic structure in the presence of Rashba effect

Spin transfer torque in magnetic structure occurs when the transverse component of the spin current that flows from the nonmagnetic medium to ferromagnetic medium is absorbed by the interface. In this paper, considering the Rashba effect on the semiconductor region, we discuss the spin transfer torque in semiconductor/ferromagnetic structure and obtain the components of spin-current density for two models:(i) single electron and(ii) the distribution of electrons. We show that no matter whether the difference in Fermi surface between semiconductor and Fermi spheres for the up and down spins in ferromagnetic increases, the transmission probability decreases. The obtained results for the values used in this article illustrate that Rashba effect increases the difference in Fermi sphere between semiconductor and Fermi sphere for the up and down spins in ferromagnetic. The results also show that the Rashba effect, brings an additional contribution to the components of spin transfer torque, which does not exist in the absence of the Rashba interaction. Moreover, the Rashba term has also different effects on the transverse components of the spin torque transfer.     

A Timoshenko beam reduced order model for shape tracking with a slender mechanism

We consider a flexible bio-inspired slender mechanism, modeled as a Timoshenko beam. It is coupled to the environment by a continuous distribution of compliant elements. We derive a reduced order model by projecting the governing partial differential equations along the linear modal basis of the Timoshenko beam. The coupling with the substrate allows us to formulate the problem in a control framework, and eventually to treat the system as a sensor to reconstruct the profile of the substrate through the deformation of the body. The coupling is modeled in the framework of two parameters elastic foundations. The convergence of the reduced order model with increasing number of basis functions is addressed in a suitable H¹ error norm. A closed loop force control is simulated for shape morphing when the system is coupled with a smooth substrate.     

Using chemometric methods for overlap correction of sodium–zinc spectral lines generated by wavelength dispersive X‐ray fluorescence in mineral samples

Partial least squares, principal component regression and support vector machine multivariate methods were used for overlap correction of sodium–zinc (Na(Kα)–Zn(Lα)) spectral lines generated by means of wavelength dispersion X‐ray fluorescence (WDXRF) combined with standard‐less software (IQ+) technique for the analyses of mineral samples. This methodology uses one scan channel using PX1 analyzer crystal, 550‐µm collimator, flow detector (Ar + CH₄), and rhodium (Rh) tube for determination of Na and Zn in mineral compositions in minimum time. The calibration matrix was made up of 35 samples containing different amounts of Na₂O and ZnO. The considered concentration ranges were 0–5% for both Na₂O and ZnO. The values for 2θ angle were recorded between 25° and 29.9° at every 0.1°. Variable tube powers (kV ? mA) were used to investigate the effect of tube power on the analyses of elements. The validation of the multivariate methods was realized by analyzing soil samples. Atomic absorption and flame photometry methods were used as reference methods for analyzing Zn and Na in the soil samples, respectively. The results of using chemometric methods, WDXRF (standard‐less software) and reference method determined partial least squares and support vector machine models obtained more acceptable results for Na₂O in presence of ZnO than those of WDXRF (standard‐less software). Copyright © 2013 John Wiley & Sons, Ltd.     

An Analytical Solution for 1-D Non-Darcy Flow Through Slanting Coarse Deposits

In this paper, an analytical solution to solve 1-D partial differential equation is presented for fully developed turbulent flow through highly permeable sloping deposited porous medium. The present solution will be applicable for a wide range of slopes varying from zero to relatively steep slopes. To confirm the solution, the analytical results have been validated using two sets of experimental data including rounded and crushed material. To see the compatibility of solution, a Darcy-based form of the solution is derived and compared with proposed solution and experimental data. The results showed a satisfactory agreement with experimental records from water surface profiles through rock cavities for both rounded and crushed rock materials. Finally, it may be concluded that the proposed solution could be used to analyze water surface profiles and normal depth in such slanting permeable porous media. This solution provides a reliable realization of the flow profiles in porous materials which are widely used in open-channel flow concepts.     

Non-affine minimum variance controller design by inverse modeling procedure

The minimum variance lower bound (MVLB) represents the best achievable controller capability in the variance sense. Realization of MVLB for nonlinear systems confronts some difficulties. To realize the MVLB, in this paper, a nonlinear non-affine generalized minimum variance controller is designed. The situations in which the model is not in hand, accurate, or invertible are addressed. Moreover, in order to design minimum variance controller for nonlinear structures, inverse of the system is modeled; then, the controller parameters are tuned by a recursive optimization algorithm. The most classical recursive algorithms are gradient-based. In this paper, a relationship between gradient of the controller with that of the system model is derived by inverse lemma. Therefore, the recursive algorithm is free of any need for the gradient of the system model. Finally, an experimental test on four-tank benchmark processes is used to clarify the effectiveness of the proposed control scheme.     

Composition and in vitro antibacterial activity of essential oils from four Satureja species growing in Iran

The composition and in?vitro antibacterial activity of essential oils from four Satureja species (S. bachtiarica, S. khuzistanica, S. mutica and S. rechingeri) growing in Iran were determined. According to the results of GC-FID and GC-MS analysis, all oil samples were principally composed of phenolic constituents (carvacrol and/or thymol) with the percentages ranging from 41.2% (S. bachtiarica) to 77.7% (S. rechingeri). Determining antibacterial activities by the disc diffusion method against two Gram-positive and two Gram-negative bacteria revealed the maximum activity against Bacillus cereus with a range of minimum inhibitory concentration values from 0.25 to 1?mg?mL(-1) and minimum bactericidal concentration values from 0.5 to 1?mg?mL(-1). The oils of S. khuzistanica and S. rechingeri appeared to be more active in general than those of other species. In conclusion, the essential oils of studied Satureja species have the potential to be considered as alternatives for synthetic food preservatives.     

Pd-poly(N-vinyl-2-pyrrolidone)/KIT-6 nanocomposite: Preparation,structural study,and catalytic activity

The Pd-poly(N-vinyl-2-pyrrolidone)/KIT-6 nanocomposite was prepared by an in situ polymerization method and used as an efficient heterogeneous catalyst for C–C bond formation through the Heck coupling reaction of aryl iodides, bromides and chlorides with styrene. The physical and chemical properties of the catalyst were characterized by XRD, BET, FT-IR, TGA, UV-Vis and TEM techniques. The reactions were performed in methanol-water as solvent and the products were obtained in high yield and purity after a simple work-up. The stability of the nanocomposite catalyst was excellent and could be reused 8 times without much loss of activity in the Heck coupling reaction.     

Zinc oxide nanoparticles:A highly efficient and readily recyclable catalyst for the synthesis of xanthenes

A novel and efficient route for the synthesis of 1,8-dioxooctahydroxanthenes and 14-aryl-14H-dibenzo[a,j]xanthenes is described through one-pot multi-component reaction of dimedone and 2-naphthol with various aryl aldehydes using ZnO nanoparticles under solvent-free conditions.This method provides a novel and improved pathway for the synthesis of xanthenes in the terms of excellent yields,short reaction times,reusability and low catalyst loading.     

Synthesis,Characterization and Solvatochromism Investigation of Mixed Ligand Chelate Copper(II) Complexes with Acetyleacetonate and Three Diamine Ligands

The syntheses of three mixed ligand chelate copper(II) complexes of the type [Cu(L)(acac)(H₂O)]BPh₄ where acac=acetyleacetonate; L=N,N‐dimethyl,N′‐benzylethane‐1,2‐diamine ( L¹ ), N,N‐dimethyl, N′‐2‐methylbenzylethane‐1,2‐diamine ( L² ) or N,N‐dimethyl,N′‐2‐chlorobenzylethane‐1,2‐diamine ( L³ ) are reported and characterized by elemental analyses, spectroscopic and molar conductance measurements. The X‐ray structure of complex 1 shows that the central copper atom is placed in a distorted square pyramidal geometry made by acac and diamine chelate in the base and a H₂O molecule on the apex. The prepared complexes are fairly soluble in a large number of organic solvents and show positive solvatochromism. Calculations of SMLR (stepwise multiple linear regression) method was utilized to find the best model explaining the observed solvatochromic behavior and showed that among different solvent parameters, donor number (DN) is a dominant factor responsible for the shift in the d‐d absorption band of the complexes to the lower wavenumber with increasing its values. The importance of substituent effect in diamine ligand on the spectral and SMLR measurements is also discussed.     

Ferrite-based magnetic nanofluids used in hyperthermia applications

Magnetic ferrofluids (magnetic nanofluids) have received special attention due to their various biomedical applications such as drug delivery and hyperthermia treatment for cancer. The biological applications impose some special requirements. For example, the well-known iron oxide ferrofluids become undesirable because their iron atoms are poorly distinguishable from those of hemoglobin. A conceivable solution is to use mixed-ferrites (MFe₂O₄ where M=Co, Mn, Ni, Zn) to have a range of magnetic properties. These ferrites have attracted special attention because they save time, and because of their low inherent toxicity, ease of synthesis, physical and chemical stabilities and suitable magnetic properties. Based on the importance of ferrite particles in ferrofluids for hyperthermia treatment, this paper gives a summary on the physical concepts of ferrofluids, hyperthermia principal, magnetic properties and synthesis methods of nanosized ferrites.