In-cylinder engine flow measurement using stereoscopic molecular tagging velocimetry (SMTV)

The stereoscopic molecular tagging velocimetry (SMTV) technique is used to obtain the multiple point measurement of an instantaneous three-component velocity field inside the cylinder of an internal combustion (IC) engine assembly. A novel image processing technique is implemented to obtain the velocity data. The technique has the advantage that it eliminates the geometric details required to obtain the three components of the velocity field. The procedure involves two major steps: (i) calibration process and (ii) data acquisition and reduction. Cycle-to-cycle variations of the three-component velocity field and out-of-plane vorticity are presented inside an engine cylinder. Preliminary results show that cycle-to-cycle variations are more prominent in the velocity component perpendicular to the tumble plane, as opposed to the in-plane components. Such new insights will help better understand the details of these flows and further improve CFD models for IC engines.     

Inverse dynamics analysis of a general spherical star-triangle parallel manipulator using principle of virtual work

Inverse dynamics of a general model of a spherical star-triangle (SST) parallel manipulator (Enferadi and Akbarzadeh Tootoonchi, Robotica 27:663–676, 2009) is the subject of this paper. This manipulator is of type 3-RRP, has good accuracy and relatively a large workspace which is free of singularities (Enferadi and Akbarzadeh Tootoonchi, Robotica, Revised paper, 2009). First, inverse kinematics utilizing the angle axis representation is solved. Next, velocity and acceleration analysis as well as link Jacobian matrices are obtained in invariant form. Finally, a systematic approach based on the principle of virtual work and the concept of link Jacobian matrices is presented. This method allows elimination of constraint forces and moments at the passive joints from motion equations. It is shown that the dynamics of the manipulator can be reduced to solving a system of three linear equations with three unknowns. Moreover, a computational algorithm for solving the inverse dynamics is developed. Two examples with different trajectories for the moving spherical platform are presented and motor torques are obtained. Results are verified using a commercial dynamics modeling package.     

A novel one‐pot procedure for preparation of some new condensed pyrido[2,3‐d]pyrimidine(1H,3H)‐2,4‐diones

A novel one‐pot procedure for preparation of some new condensed pyrido[2,3‐d]pyrimidine(1H,3H)‐2,4‐diones based on condensation of ninhydrin, alkyl cyanoacetate, and 6‐aminouracil derivatives has been reported. The reactions were carried out in refluxed ethanol and were completed in less than 2 h. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:16–18, 2007; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20242     

A stereoselective three-component reaction: KAl(SO4)2.12H2O, an efficient and reusable catalyst for the one-pot synthesis of cis-isoquinolonic acids

KAl(SO(4))(2).12H(2)O is found to catalyze efficiently the stereoselective one-pot three-component cyclocondensation of homophthalic anhydride, aldehydes, and amines under mild conditions to afford the corresponding cis-isoquinolonic acids in good yields.     

Integrated production scheduling in large-scale flexible electronic parts manufacturing

This study reports the development of a production scheduling system for the integrated management of production in large-scale, high-volume electronic assembly lines. The development of the system incorporates control and planning considerations by addressing the interaction of various subsystems. Stochastic and deterministic aspects of the problem environment are appropriately handled via relevant simulation and analytic models. By effecting a hierarchical breakdown of the problem environment, the system produces information used in practical decision making for production planning and scheduling. Procedures used encompass and address considerations for management of work-in-process, optimization of the various subsystems' performance, minimization of setup time effect, and inventory carrying costs.     

An analysis of setup cost reduction in a two stage system with power investment function

Recently, a framework for analyzing investment decisions as they relate to setup cost reduction in two stage production processes has appeared in the literature. Closed form results were developed for the case of logarithmic investment function. This paper extends the results to the case of power investment function. We present an algorithm for calculating the optimal values of the decision variables. A numerical example is utilized to reveal some interesting aspects of this system.     

Activated persulfate by chelating agent Fe·/complex for in situ degradation of phenol: intermediate identification and optimization study

Research on Chemical Intermediates - Due to its high toxicity, phenol is classified as a priority. In this paper, the removal of phenol from aqueous solutions was investigated using EDTA and...     

Imprinted polymer particles for selenium uptake: synthesis, characterization and analytical applications

This work reports the preparation of molecularly imprinted polymer (MIP) particles for selective extraction and determination of selenium ions from aqueous media. Polymerization was achieved in a glass tube containing SeO₂, o-phenylenediamine, 2-vinylpyridine (VP), ethyleneglycoldimethacrylate (EDMA), 2,2′-azobisisobutyronitrile (AIBN). The polymer block obtained was ground and sieved (55-75 μm) and the Se-o-phenylenediamine complex was removed from polymer particles by leaching with 2 M of HCl, which leaves a cavity in the polymer particles. The polymer particles both prior to and after leaching have been characterized by IR and thermogravimetric (TG) studies. The effect of different parameters, such as pH, extraction time, type and least amount of eluent for elution of complex from polymer were evaluated. Extraction efficiencies >99% were obtained by elution of the polymers with 15 mL of methanol-acetonitrile mixture (1:2, v/v). The limit of detection of the proposed method followed by hydride generation atomic absorption spectroscopy (HG-AAS) was found to be 3.3 μg L⁻¹ and a dynamic linear range (DLR) of 10-200 μg L⁻¹ was obtained. The relative standard deviations (R.S.D.s) at 30.0 μg L⁻¹ of Se were below than 8.1%. The influence of various cationic interferences on percent recovery of complex was studied. The method was applied to the recovery and determination of selenium in different real samples.     

Synthesis and characterization of new nitrate-bridged polymeric complexes of mercury(II) with phosphorus ylides

Reaction of phosphorus ylides of the type X-C₆H₄-COCHPAr₃ (X = Cl and NO₂; Ar = phenyl and p-tolyl) with Hg(NO₃)₂ · H₂O in equimolar ratios using methanol as solvent are reported. X-ray crystal structure analysis of [Hg(ClC₆H₄C(O)CHPPh₃)(NO₃)(μ-NO₃)]_n · (DMSO)_n shows that the 1:1 complex adopts the noncentrosymmetric polymeric structure in the solid state with NO^-₃ anion bridges. Variation of temperature or concentration in a ³¹P NMR study indicates that the disappearance of satellites, due to coupling to ¹⁹⁹Hg, occurs at increasing temperature or decreasing concentration.