Mild Oxidation of Oxime Derivatives with KMnO4 in Ionic Liquid Media

In this research, potassium permanganate in the presence of a catalytic amount of [bmim]Br under solvent free conditions is used as an efficient and chemoselective method for oxidative cleavage of some oximes to corresponding carbonyl compounds. This experiment was carried out in mild conditions without any further oxidation of aldehydes to corresponding acids.     

Synthesis of multi-wall carbon nanotubes by copper vapor laser

Synthesis of multi-wall carbon nanotubes in a 1473 K furnace using a copper vapor laser (CVL) is reported. The operating parameters of this laser, i.e. a high fluence at the focal point and an extremely high frequency of 10 kHz, distinguished it from common laser sources in the synthesis of CNTs. Therefore, the unexpected experimental findings, the formation of MWNTs instead of the generally reported SWNTs, would be verified by these two notable parameters. Electron microscopy beside Raman spectroscopy illustrates the presence of multi-wall carbon nanotubes in the resulting product.     

1- and 2-D NMR Studies on [Rh6C(CO)14(PPh3)]2−

A complete NMR study involving both 1D and 2D ¹³C-{¹⁰³Rh} and ³¹P-{¹⁰³Rh} HMQC measurements, on [Rh₆C(CO)₁₄(PPh₃)]^2- are reported and discussed, together with the multiple Rh quantum effects found for resonances associated with edge- and face-bridging CO's. As found in [Rh₆C(CO)₁₅]^2-, the carbonyl ligands in [Rh₆C(CO)₁₄(PPh₃)]^2- undergo CO-intermolecular exchange with ¹³CO at different rates; for the edge-bridging CO's, the lower the value of ¹J(Rh–CO), the faster the rate of intermolecular exchange with ¹³CO.     

A three‐component process for the synthesis of 2,3‐dihydroquinazolin‐4(1H)‐one derivatives using nanosized nickel aluminate spinel crystals as highly efficient catalysts

NiAl₂O₄ spinel nanocrystals were synthesized as mesoporous catalysts and were fully characterized using Fourier‐transform infrared spectroscopy (FT‐IR), X‐ray diffraction patterns (XRD), scanning electron microscopy (SEM), and Energy‐dispersive X‐ray spectroscopy (EDS). These nanocrystals catalyzed the synthesis of 2,3‐dihydroquinazolin‐4(1H)‐one derivatives via a one‐pot, three‐component condensation reaction of aromatic aldehydes, isatoic anhydride, and ammonium acetate or primary aromatic amine under microwave irradiation. By far, the most obvious advantages of the offered process are efficiency and recyclability of the catalyst as well as a significantly shorter reaction time.     

Evacuating liquid coatings from a diffusive oblique fin in micro-/mini-channels

The present work emphasis on to estimate the theoretical findings of energy and exergy analysis of biodiesel fueled with diesel on variable compression ratio engine at various combinations of fuel blend at different compression ratios. This study aims to identify the optimum engine settings based on compression ratio and biodiesel blends. The engine is operated with methyl esters of rubber seed oil and its 20, 40, 60 and 80% blends with diesel on volume basis. The compression ratio is varied from 18:1 to 22:1 at five compression ratios at 80% load in 3.5 kW, 1500 rpm, single cylinder water-cooled direct injection engine. The variables analyzed are energy and exergy potential of fuel input, shaft work, cooling water, maximum pressure, heat release rate, exergy destruction, brake-specific energy consumption, brake thermal efficiency, second law efficiency, entropy generation, exhaust gas temperature and various emissions. It is observed that the combination of CR 20, B20 and B40 at 80% load gives a better performance in thermodynamic analysis of methyl esters of rubber seed oil blended with diesel in VCR engine.

     

Inverse dynamics analysis of a general spherical star-triangle parallel manipulator using principle of virtual work

Inverse dynamics of a general model of a spherical star-triangle (SST) parallel manipulator (Enferadi and Akbarzadeh Tootoonchi, Robotica 27:663–676, 2009) is the subject of this paper. This manipulator is of type 3-RRP, has good accuracy and relatively a large workspace which is free of singularities (Enferadi and Akbarzadeh Tootoonchi, Robotica, Revised paper, 2009). First, inverse kinematics utilizing the angle axis representation is solved. Next, velocity and acceleration analysis as well as link Jacobian matrices are obtained in invariant form. Finally, a systematic approach based on the principle of virtual work and the concept of link Jacobian matrices is presented. This method allows elimination of constraint forces and moments at the passive joints from motion equations. It is shown that the dynamics of the manipulator can be reduced to solving a system of three linear equations with three unknowns. Moreover, a computational algorithm for solving the inverse dynamics is developed. Two examples with different trajectories for the moving spherical platform are presented and motor torques are obtained. Results are verified using a commercial dynamics modeling package.     

A novel one‐pot procedure for preparation of some new condensed pyrido[2,3‐d]pyrimidine(1H,3H)‐2,4‐diones

A novel one‐pot procedure for preparation of some new condensed pyrido[2,3‐d]pyrimidine(1H,3H)‐2,4‐diones based on condensation of ninhydrin, alkyl cyanoacetate, and 6‐aminouracil derivatives has been reported. The reactions were carried out in refluxed ethanol and were completed in less than 2 h. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:16–18, 2007; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20242     

A stereoselective three-component reaction: KAl(SO4)2.12H2O, an efficient and reusable catalyst for the one-pot synthesis of cis-isoquinolonic acids

KAl(SO(4))(2).12H(2)O is found to catalyze efficiently the stereoselective one-pot three-component cyclocondensation of homophthalic anhydride, aldehydes, and amines under mild conditions to afford the corresponding cis-isoquinolonic acids in good yields.     

Integrated production scheduling in large-scale flexible electronic parts manufacturing

This study reports the development of a production scheduling system for the integrated management of production in large-scale, high-volume electronic assembly lines. The development of the system incorporates control and planning considerations by addressing the interaction of various subsystems. Stochastic and deterministic aspects of the problem environment are appropriately handled via relevant simulation and analytic models. By effecting a hierarchical breakdown of the problem environment, the system produces information used in practical decision making for production planning and scheduling. Procedures used encompass and address considerations for management of work-in-process, optimization of the various subsystems' performance, minimization of setup time effect, and inventory carrying costs.