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101.
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103.
Zhdankin VV Kuehl CJ Krasutsky AP Bolz JT Simonsen AJ 《The Journal of organic chemistry》1996,61(19):6547-6551
Organosulfonyloxy derivatives of 1,2-benziodoxol-3(1H)-one (3a-c) and 3,3-bis(trifluoromethyl)-3(1H)-1,2-benziodoxole (5a-c) can be prepared in high yield by the reaction of 1-hydroxybenziodoxoles 1 or 4 and the corresponding sulfonic acids or Me(3)SiOTf in the form of stable, but moderately hygroscopic, microcrystalline solids. Reaction of the triflate derivatives 3a and 5a with alkynyltrimethylsilanes affords either alkynyliodonium triflates 6, or (E)-beta-(trifluoromethanesulfonyloxy)alkenyliodonium triflates 7, while the same reaction in the presence of pyridine selectively gives the respective 1-alkynylbenziodoxoles 8 and 9 in 82-90% yield. 相似文献
104.
Birck C Cha JY Cross J Schulze-Briese C Meroueh SO Schlegel HB Mobashery S Samama JP 《Journal of the American Chemical Society》2004,126(43):13945-13947
105.
Jakub Kołacz Henry G. Gotjen Robel Y. Bekele Jason D. Myers Jesse A. Frantz Michael Ziemkiewicz 《Liquid crystals》2020,47(4):531-539
ABSTRACTIn a planar dielectric waveguide, weak confinement of a propagating mode in a high index core leads to a measurable evanescent interaction with the cladding. In this work, we study the effect of a reorientable anisotropic cladding on the behaviour of Transverse Electric (TE) and Transverse Magnetic (TM) mode polarisations using a liquid crystal (LC)-clad waveguide architecture. The polarised evanescent field of a guided mode interacts with a voltage-tunable birefringent LC cladding to deflect an out-coupled beam. Experimental measurements are coupled with a theoretical framework and show good consistency with simulation results. We isolate the effect of mode confinement by changing the thickness of the high index core. Interactions between the LC index ellipsoid and the mode polarisation are probed by changing the initial alignment of the LC. Finally, we examine the difference in deflection between TE and TM modes, which incorporates both a change in mode confinement and a difference in LC index components. 相似文献
106.
Following a comprehensive look at the arene hydrogenation literature by soluble nanocluster catalysts, six key, unfulfilled goals in nanocluster arene hydrogenation catalysis are identified. To begin to address those six goals, well-characterized polyoxoanion- and tetrabutylammonium-stabilized Rh(0) nanoclusters have been synthesized by the reduction of the precisely defined precatalyst [Bu(4)N](5)Na(3)[(1,5-COD)Rh small middle dotP(2)W(15)Nb(3)O(62)] with H(2) in propylene carbonate solvent. These Rh(0) nanoclusters are characterized by their stoichiometry of formation, transmission electron microscopy, and the two rate constants which characterize their mechanism of formation; previous studies in our laboratories have provided additional characterization of polyoxoanion-stabilized Rh(0) nanoclusters. Propylene carbonate solutions of the Rh(0) nanoclusters catalyze the hydrogenation of anisole (methoxybenzene) under mild conditions (22-78 degrees C, 30-40 psig H(2)). Proton donors such as water or HBF(4) small middle dotEt(2)O are discovered to affect both nanocluster formation and nanocluster arene hydrogenation catalysis. Under identical conditions, the Rh(0) nanoclusters are 10-fold more active than a commercially available, oxide-supported 5% Rh/Al(2)O(3) catalyst of the same average metal-particle size. A series of lifetime experiments shows that the Rh(0) nanoclusters are capable of at least 2600 total turnovers (TTO), a lifetime significantly longer than the approximately 100 TTO often seen for nanocluster arene hydrogenation catalysts, and a lifetime slightly better than the prior record of 2000 TTO for a literature nanocluster system. The present polyoxoanion-stabilized Rh(0) nanoclusters also display a record, albeit modest, 30% selectivity for the partial hydrogenation of anisole to 1-methoxycyclohexene with an overall yield of up to 8% at higher temperatures. In comparison to the 5% Rh/Al(2)O(3) catalyst, the polyoxoanion-stabilized nanoclusters yield a 4.7-fold higher maximum yield of 1-methoxycyclohexene. Finally, the seven main findings of the present work are summarized, including how they address five of the aforementioned six main goals in nanocluster arene hydrogenation. 相似文献
107.
Holzmueller J Genson KL Park Y Yoo YS Park MH Lee M Tsukruk V 《Langmuir : the ACS journal of surfaces and colloids》2005,21(14):6392-6398
Amphiphilic dendron-rod molecules with three hydrophilic poly(ethylene oxide) (PEO) branches attached to a hydrophobic octa-p-phenylene rod stem were investigated for their ability to form two-dimensional micellar structures on a solid surface. A treelike shape of the molecules was reported to be a major factor in the formation of nonplanar micellar structures in solution and in the bulk state (cylindrical and spherical). We observed that in these treelike amphiphilic molecules the hydrophilic terminated dendron branches assemble themselves in surface monolayers with the formation of two-dimensional layered or circular micellar structures. We suggested the formation of the planar ribbon-like structures with interdigitated layering within the loosely packed monolayers and circular, ringlike structures (2D circular aggregates) in the precollapsed state. 相似文献
108.
Powell SA Tenenbaum JM Woerpel KA 《Journal of the American Chemical Society》2002,124(43):12648-12649
We have developed a route for the stereoselective synthesis of 1-oxa-2,2-(dimesityl)silacyclopentane acetals, intermediates in the synthesis of highly functionalized 1,3-diols. This route involves a diastereoselective conjugate addition reaction of a hydrosilyl anion, a subsequent diastereoselective enolate alkylation, and a fluoride-catalyzed intramolecular hydrosilylation reaction to afford the oxasilacyclopentane acetal. A highly selective nucleophilic substitution reaction, followed by oxidation of the C-Si bond, leads to the desired polyol. 相似文献
109.
Frederick MO Mulder JA Tracey MR Hsung RP Huang J Kurtz KC Shen L Douglas CJ 《Journal of the American Chemical Society》2003,125(9):2368-2369
A copper-catalyzed new C-N bond formation involving a sp-hybridized carbon is described here leading to a facile entry for syntheses of chiral ynamides. This direct N-alkynylation of amides should have a significant impact on the future development of synthetic methodologies employing ynamides. 相似文献
110.
Furuta P Brooks J Thompson ME Fréchet JM 《Journal of the American Chemical Society》2003,125(43):13165-13172
The site isolation of two dyes capable of electronic interaction via Forster energy transfer has been studied with the two dyes coumarin 343 and pentathiophene encapsulated by dendrons containing both solubilizing and electroactive moieties. Photoluminescence studies of mixtures of the dendritic dyes show that at high dendron generation, significant site isolation is achieved with relative emission characteristics influenced by both the degree of site isolation and the emission quantum yield of the dyes. Electroluminescence studies carried out in organic light emitting diode devices confirm that color tuning may be achieved by mixing the two encapsulated dyes in a single layer. However, selective carrier trapping by one of the core component dyes can dramatically influence the effectiveness of other components in the device. 相似文献