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101.
102.
Summary The extraction of iron(III) from aqueous HCl, H2SO4, HClO4, HNO3 solutions by 2-carbethoxy-5-hydroxy-1-(4-tolyl)-4-pyridone (HA) dissolved in CHCl3 has been studied. Quantitative extraction of iron(III) is achieved if the concentration of the acids does not exceed 1N. The composition of the iron (III)—HA complex formed in the organic phase was investigated spectrophotometrically, radiometrically and by analysis of the isolated species. In the aqueous phase iron (III) and HA form three different complexes, depending on the initial iron: HA concentration ratio and the pH of the solution. They are the violet FeA2+, the orange-red FeA2
+ and the orange-yellow FeA3. The latter is identical with the complex found in the organic phase, which was isolated as a solid crystalline material and characterized by elemental analysis and infrared spectroscopy. A spectrophotometric method for the determination of iron(III) in the aqueous phase and in the chloroform solution, by extraction with HA, is described.
Zusammenfassung Die Extraktion von Fe(III) aus wäßrigen Lösungen von HCl, H2SO4, HClO4 oder HNO3 mit 2-Carbäthoxy-5-hydroxy-1-(4-tolyl)-4-pyridon (HA) in chloroformischer Lösung wurde untersucht. Sie verläuft quantitativ, wenn die Konzentration der Säure nicht größer ist als 1-n. Die Zusammensetzung des Fe(III)-HA-Komplexes in der organischen Phase wurde spektrophotometrisch, radiometrisch und durch Analyse der isolierten Substanz untersucht. In wäßrigem Milieu bilden Eisen(III) und HA drei verschiedene Komplexe je nach dem anfänglichen Konzentrationsverhältnis Fe(III): HA und je nach dem pH der Lösung. FeA2+ ist violett, FeA2 + ist orange-rot und FeA3 orangegelb. Diese Verbindung ist mit dem in der organischen Phase gefundenen Komplex identisch, der in kristallisierter Form isoliert und durch Elementaranalyse und IR-Spektrometrie charakterisiert wurde. Eine spektrophotometrische Methode zur Eisen(III)-Bestimmung in wäßriger Phase und in chloroformischer Lösung durch Extraktion mit HA wurde beschrieben.相似文献
103.
Summary Extraction of zirconium, niobium and tantalum from oxalic and hydrofluoric acid solutions, by 2-carbethoxy-5-hydroxy-1-(4-tolyl)-4-pyridone (HA) dissolved in chloroform was studied. Extraction mechanism for the extraction of zirconium from oxalate solutions and of niobium from fluoride solutions is proposed. Separation of zirconium and niobium from oxalate solution as well as from fluoride solution and tantalum and niobium from fluoride solution is described. Back-extraction of these metals is possible by hydrofluoric and oxalic acid. Results obtained show that the efficiency of extraction by HA decreases in the sequence tantalum > niobium > zirconium.
Zusammenfassung Die Extraktion von Zirkonium, Niob und Tantal aus oxalsauren und fluorwasserstoffsauren Lösungen mit Hilfe einer chloroformischen Lösung von 2-Carbäthoxy-5-hydroxy-(4-tolyl)-4-pyridon wurde untersucht. Ein Extraktionsmechanismus für Zirkonium aus Oxalatlösungen und für Niob aus Fluoridlösungen wurde vorgeschlagen. Die Trennung von Zirkonium und Niob aus einer Oxalatlösung oder aus einer Fluoridlösung sowie von Tantal und Niob aus einer Fluoridlösung wurde beschrieben. Die Rückextraktion dieser Metalle mit Flußsäure und Oxalsäure ist möglich. Die Ergebnisse zeigen, daß die Effizienz der Extraktion in der Reihenfolge Tantal > Niob > Zirkonium abfällt.相似文献
104.
Maja Milivojevic Fir Andrej Smidovnik Luka Milivojevic Janko Zmitek Mirko Prosek 《Journal of inclusion phenomena and macrocyclic chemistry》2009,64(3-4):225-232
The complexes of coenzyme Q10 with β- and γ-cyclodextrin in aqueous solutions were prepared in order to improve the water solubility, thermo- and photo-stability of coenzyme Q10. Complex formation resulted in an increase in water solubility at room temperature and pH 6.5 by a factor at least 102. The solubility of coenzyme Q10 in the presence of cyclodextrins linearly increases with temperature and pH. The UV light (λ = 254) and temperature together have a great effect on coenzyme Q10 stability. After 120 min of exposure at 80 °C and UV light about 72.3% of pure coenzyme Q10 was degraded. Thermo- and photo-stability was strongly improved by complex formation; more than 64% of coenzyme Q10 remained unchanged. The formation of complexes was evaluated using IR spectrometry, X-ray diffractometry and TGA/DSC analysis. 相似文献
105.
Janko Latschev 《Mathematische Annalen》2000,318(4):731-759
106.
We classify here nonmetacyclic finite 2-groups all of whose nonmetacyclic subgroups are generated by involutions (Theorem
1.1). This solves problem Nr. 710 for p = 2 stated by Y. Berkovich in [1]. For p > 2 the corresponding problem is open.
Received: 14 March 2007 Revised: 15 April 2007 相似文献
107.
Abstact: A symmetric 2‐(100, 45, 20) design is constructed that admits a tactical decomposition into 10 point and block classes of size 10 such that every point is in either 0 or 5 blocks from a given block class, and every block contains either 0 or 5 points from a given point class. This design yields a Bush‐type Hadamard matrix of order 100 that leads to two new infinite classes of symmetric designs with parameters and where m is an arbitrary positive integer. Similarly, a Bush‐type Hadamard matrix of order 36 is constructed and used for the construction of an infinite family of designs with parameters and a second infinite family of designs with parameters where m is any positive integer. © 2000 John Wiley & Sons, Inc. J Combin Designs 9: 72–78, 2001 相似文献
108.
Zvonimir Janko Hadi Kharaghani Vladimir D. Tonchev 《Designs, Codes and Cryptography》2001,24(2):225-232
A symmetric 2-(324, 153, 72) design is constructed that admits a tactical decomposition into 18 point and block classes of size 18 such that every point is in either 0 or 9 blocks from a given block class, and every block contains either 0 or 9 points from a given point class. This design is self-dual and yields a symmetric Hadamard matrix of order 324 of Bush type, being the first known example of a symmetric Bush-type Hadamard matrix of order 4n
2 for n > 1 odd. Equivalently, the design yields a strongly regular graph with parameters v=324, k=153, ==72 that admits a spread of cocliques of size 18. The Bush-type Hadamard matrix of order 324 leads to two new infinite classes of symmetric designs with parameters
and
where m is an arbitrary positive integer. 相似文献
109.
Janko Latschev 《Topology》2006,45(4):707-723
Let a smooth vector field V on a smooth closed manifold M be given and let Z⊂M be an isolated invariant set for the flow of V. In this situation, we give a necessary and sufficient condition for the existence of a Lyapunov 1-form for (V,Z) in terms of the relative asymptotic cycles associated with certain invariant measures of the flow. 相似文献
110.
Gregorovič A Apih T Kvasić I Lužnik J Pirnat J Trontelj Z Strle D Muševič I 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2011,209(1):79-82
We demonstrate excitation and detection of nuclear magnetization in a nuclear quadrupole resonance (NQR) experiment with a parallel plate capacitor, where the sample is located between the two capacitor plates and not in a coil as usually. While the sensitivity of this capacitor-based detection is found lower compared to an optimal coil-based detection of the same amount of sample, it becomes comparable in the case of very thin samples and even advantageous in the proximity of conducting bodies. This capacitor-based setup may find its application in acquisition of NQR signals from the surface layers on conducting bodies or in a portable tightly integrated nuclear magnetic resonance sensor. 相似文献