首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   142168篇
  免费   2724篇
  国内免费   220篇
化学   79795篇
晶体学   1707篇
力学   4488篇
综合类   6篇
数学   20867篇
物理学   38249篇
  2022年   1103篇
  2021年   1626篇
  2020年   1910篇
  2019年   2060篇
  2018年   2870篇
  2017年   2874篇
  2016年   4439篇
  2015年   2928篇
  2014年   3657篇
  2013年   7479篇
  2012年   6661篇
  2011年   7030篇
  2010年   5098篇
  2009年   4786篇
  2008年   6159篇
  2007年   5860篇
  2006年   5279篇
  2005年   4982篇
  2004年   4449篇
  2003年   3952篇
  2002年   3827篇
  2001年   3446篇
  2000年   2844篇
  1999年   2119篇
  1998年   1854篇
  1997年   1698篇
  1996年   1695篇
  1995年   1442篇
  1994年   1484篇
  1993年   1467篇
  1992年   1535篇
  1991年   1495篇
  1990年   1486篇
  1989年   1425篇
  1988年   1321篇
  1987年   1246篇
  1986年   1217篇
  1985年   1516篇
  1984年   1598篇
  1983年   1327篇
  1982年   1355篇
  1981年   1244篇
  1980年   1144篇
  1979年   1215篇
  1978年   1330篇
  1977年   1313篇
  1976年   1240篇
  1975年   1175篇
  1974年   1194篇
  1973年   1150篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
61.
62.
The density functional theory calculation of 1H and 13C NMR chemical shifts in a series of ten 10 classically known Strychnos alkaloids with a strychnine skeleton was performed at the PBE0/pcSseg-2//pcseg-2 level. It was found that calculated 1H and 13C NMR chemical shifts provided a markedly good correlation with experiment characterized by a mean absolute error of 0.08 ppm in the range of 7 ppm for protons and 1.67 ppm in the range of 150 ppm for carbons, so that a mean absolute percentage error was as small as ~1% in both cases.  相似文献   
63.
Metabolomics is a potential tool for the discovery of new biomarkers in the early diagnosis of diseases. An ultra-fast gas chromatography system equipped to an electronic nose detector (FGC eNose) was used to identify the metabolomic profile of Volatile Organic Compounds (VOCs) in type 2 diabetes (T2D) urine from Mexican population. A cross-sectional, comparative, and clinical study with translational approach was performed. We recruited twenty T2D patients and twenty-one healthy subjects. Urine samples were taken and analyzed by FGC eNose. Eighty-eight compounds were identified through Kovats's indexes. A natural variation of 30% between the metabolites, expressed by study groups, was observed in Principal Component 1 and 2 with a significant difference (p < 0.001). The model, performed through a Canonical Analysis of Principal coordinated (CAP), allowed a correct classification of 84.6% between healthy and T2D patients, with a 15.4% error. The metabolites 2-propenal, 2-propanol, butane- 2,3-dione and 2-methylpropanal, were increased in patients with T2D, and they were strongly correlated with discrimination between clinically healthy people and T2D patients. This study identified metabolites in urine through FGC eNose that can be used as biomarkers in the identification of T2D patients. However, more studies are needed for its implementation in clinical practice.  相似文献   
64.
Sukhorukova  O. S.  Tarasenko  A. S.  Tarasenko  S. V.  Shavrov  V. G. 《JETP Letters》2020,112(7):420-427
JETP Letters - At the resonant passage of a plane elastic shear wave through an acoustically continuous heterostructure consisting of magnetic and nonmagnetic layers in a symmetric nonmagnetic...  相似文献   
65.
The accumulated knowledge regarding molecular architectures is based on established, reliable, and accessible analytical tools that provide robust structural and functional information on assemblies. However, both the dynamicity and low population of noncovalently interacting moieties within studied molecular systems limit the efficiency and accuracy of traditional methods. Herein, the use of a saturation transfer-based NMR approach to study the dynamic binding characteristics of an anion to a series of synthetic receptors derived from bambusuril macrocycles is demonstrated. The exchange rates of BF4 are mediated by the side chains on the receptor (100 s−1<kex<5000 s−1), which play a critical role in receptor-anion binding dynamics. The signal amplification obtained with this approach allows for the identification of different types of intermolecular interactions between the receptor and the anion, something that could not have been detected by techniques hitherto used to study molecular assemblies. These findings, which are supported by a computational molecular dynamic study, demonstrate the uniqueness and added value of this NMR method.  相似文献   
66.
This article describes the investigation of the importance of various reaction conditions on microsyneretic pore formation during polymerization of divinylbenzene (DVB) under so‐called “solvothermal” conditions. To induce microsyneretic pore formation, the most important parameter is an unusually high dilution of monomers with a “good” porogen solvating the polymer chains. High dilution and solvation of the growing poly(DVB) chains promote the prolongation of the polymer chains rather than their interconnection by crosslinking. Consequently, when the polymer gel density reaches the point where syneresis starts, the polymer network is geometrically too extensive to be broken up into precipitating entities and, instead, porogen droplets are formed within the continuous polymer gel. The pore geometry created by microsyneresis offers high surface area in wide mesopores and hence, high capacity for supporting functional groups or reactions with much better accessibility than narrow pores between polymer microspheres produced by macrosyneresis in conventional styrenic polymer supports. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 774–781  相似文献   
67.
The structure and properties of 12Cr1MoV steel irradiated with a zirconium ion beam were studied by optical microscopy, scanning electron microscopy, and micro- and nanoindentation. It is shown that the modification covers the entire cross-section of the irradiated specimens to a depth of 1 mm. The data on irradiation-induced structural changes are used to interpret the changes in mechanical properties of the irradiated specimens under static and cyclic loading. Particular attention is given to analysis of strain estimation by the digital image correlation method.  相似文献   
68.
Russian Chemical Bulletin - Terminal disaccharide fragment of phenolic glycolipid from Mycobacterium leprae (PGL-I) was synthesized as a glycoside with 4-(2-aminoethoxy)phenyl aglycon. The obtained...  相似文献   
69.
70.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号