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91.
The rate of reductive elimination for a family of zirconocene isobutyl hydride complexes, Cp(CpR(n)())Zr(CH(2)CHMe(2))H (Cp = eta(5)-C(5)Me(5), CpR(n)() = substituted cyclopentadienyl), has been measured as a function of cyclopentadienyl substituent. In general, the rate of reductive elimination increases modestly with the incorporation of sterically demanding substituents such as [CMe(3)] or [SiMe(3)]. A series of isotopic labeling experiments was used to elucidate the mechanism and rate-determining step for the reductive elimination process. From these studies, a new zirconocene isobutyl hydride complex, Cp' '(2)Zr(CH(2)CHMe(2))(H) (Cp' ' = eta(5)-C(5)H(3)-1,3-(SiMe(3))(2)), was designed and synthesized such that facile reductive elimination of isobutane and activation of dinitrogen was observed. The resulting dinitrogen complex, [Cp' '(2)Zr](2)(mu(2), eta(2),eta(2)-N(2)), has been characterized by X-ray diffraction and displays a bond length of 1.47 A for the N(2) ligand, the longest observed in any metallocene dinitrogen complex. Solution magnetic susceptibility demonstrates that [Cp' '(2)Zr](2)(mu(2), eta(2), eta(2)-N(2)) is a ground-state triplet, consistent with two Zr(III), d(1) centers. Mechanistic studies reveal that the dinitrogen complex is derived from the reaction of N(2) with the resulting cyclometalated zirconocene hydride rather than directly from reductive elimination of alkane. 相似文献
92.
J. J. Keller 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》1977,28(2):237-263
Summary The problem of a gas-filled tube excited by sinusoidal piston motion at one end and open at the other end is reinvestigated.It is shown that the key idea for the solution of the problem is a suitable combination of the usual amplitude nonlinearity and distortion effects. The main consequence of this is that the solution cannot be expressed in terms of a hierarchy associated with an expansion in the Mach number. Nevertheless an equation can be constructed which describes the behaviour of the flow in the limit of small Mach numbers. At the open end shock waves appear in the solution within a well-defined frequency band at each resonant frequency. Two different models which have been proposed by Wijngaarden and Jimenez respectively are used to define the boundary condition. It is seen that some basic properties of the resonant oscillations are independent of the boundary condition. Wijngaarden's model leads to very good agreement with results from several different experimenters. In this case, the width of the frequency interval where shocks occur is of the orderO(M); the width of the resonance band is of the orderO(M
1/2), just as for the closed end tube.
Zusammenfassung Betrachtet wird ein mit Gas gefülltes Rohr, welches an einem Ende offen ist und am andern Ende von einem harmonisch schwingenden Kolben angetrieben wird. Der Schlüssel zur Lösung dieses Problems ist eine geeignete Kombination der üblichen Amplitudennichtlinearität mit den Dispersionseffekten. Dies führt auf die grundlegende Konsequenz, dass es nicht möglich ist, die Lösung im Rahmen einer Hierarchie auszudrücken, welche aus einer Entwicklung in der Machzahl hervorgeht. Es ist gleichwohl möglich, eine Gleichung zu konstruieren, welche die Gasschwingungen für kleine Machzahlen beschreibt. Am offenen Ende treten innerhalb eines wohldefinierten Frequenzbandes (bei jeder Resonanzfrequenz) Stosswellen auf. Zur Definition der Randbedingung am offenen Ende werden zwei Modelle benützt, die (beziehungsweise) von Wijngaarden und Jimenez vorgeschlagen wurden. Einige der grundlegenden Eigenschaften der Lösungen sind unabhängig von der Randbedingung. Wijngaardens Modell führt auf sehr gute Übereinstimmung mit typischen Experimenten. In diesem Fall ist die Breite des Intervalls, in welchen Stösse auftreten, von der Ordnung O(M); die Breite des Resonanzbandes ist (in Übereinstimmung mit den Ergebnissen vom geschlossenen Rohr) von der OrdnungO(M 1/2).相似文献
93.
Jakob J. Keller 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》1977,28(1):107-122
Summary Second-order resonance effects in closed tubes with varying cross-sectional area are investigated. It is seen that for tubes with cross-sectional areasA(x)x
–2 solutions for the pressure disturbances can be found, as was done by W. Chester in case of tubes with constant cross-sectional area.
Zusammenfassung Es werden Resonanzeffekte zweiter Ordnung in Rohren mit veränderlicher Querschnittsfläche betrachtet. Ist die QuerschnittsflächeA(x)x –2, so können die Druckstörungen in Analogie zu Chesters Theorie analytisch berechnet werden.相似文献
94.
This paper reports the results of an investigation on the role of the supporting electrolyte in separations using electrochemically modulated liquid chromatography (EMLC) with a porous graphitic carbon stationary phase. With respect to the identity of the supporting electrolyte, the elution strength of the electrolyte anion increased as F- < OH- < BF4- < ClO4- < PF6- for injections of negatively charged aromatic molecules, whereas a 10-fold increase in electrolyte concentration induced a 60% change in retention for the same solutes. Furthermore, both the concentration and composition of the supporting electrolyte affected retention in a manner that varied with the charge of the analyte and applied potential. This behavior is explained using Gouy-Chapman diffuse double layer theory, coupled with comparisons of this theory with closely related models for ion-pair chromatography. Insights into the retention mechanism reveal that an ion-exchange mechanism controls the retention of negatively charged solutes at applied potentials removed from the potential of zero charge (PZC). At potentials close to the PZC, the electrostatic model is less effective with the predominant retention mechanism likely involving hydrophobic interactions with the carbonaceous stationary phase. The combined effects of these findings are demonstrated by using a temporal gradient in supporting electrolyte concentration to optimize an EMLC separation. 相似文献
95.
[reaction: see text] A new Prins-type cyclization between homopropargylic alcohol and aldehydes in the presence of FeX(3) to obtain 2-alkyl-4-halo-5,6-dihydro-2H-pyrans in good yield is described. Osmium-catalyzed cis dihydroxylation provided direct access to trans-2-alkyl-3-hydroxy-tetrahydro-pyran-4-ones. Anhydrous ferric halides are also shown to be excellent catalysts for the standard Prins cyclization using homoallylic alcohol. Isolation of an intermediate acetal provides substantiation of a proposed mechanism. 相似文献
96.
L. Forte K. Andrieux G. Keller C. Grabielle-Madelmont S. Lesieur M. Paternostre M. Ollivon C. Bourgaux P. Lesieur 《Journal of Thermal Analysis and Calorimetry》1998,51(3):773-782
The thermotropic transitions of 1,2-dipalmitoylphosphatidylcholine (DPPC) and the structural changes of its lamellar phases have been studied between 0 and 50°C by both DSC and synchrotron small angle X-ray diffraction/scattering as a function of temperature (XRDT) and sodium taurocholate concentration [TC] in the 0–40 mM range ([DPPC]=50 mM) at pH 7.4. The existence of multiple phase transitions (up to 5 peaks within a 5°C interval) in a narrow domain of temperature between 25 and 42°C depending on the [TC]/[lipid] ratio was observed in the DSC curves. XRDT showed that at low ratios they might correspond to transitions between lamellar phases, the structural characteristics of which are given. At higher ratios a lamellar to micellar transition was observed, and the temperature at which it was observed decreased as a function of the TC content. The relationships with DPPC vesicle bilayer permeabilization and solubilization are discussed. 相似文献
97.
A classification of the shape resonances in the photoionization of diatomic molecules into two types is proposed: the well known molecular shape resonances which appear in the σ u channel for the photoionization of the σ g shells of light molecules like 3σ g in N2 or in O2, and the atomic-like shape resonances. To illustrate this last class of shape resonances, calculations in the frozen core static exchange approximation of thed inner shell photoionization cross sections, σ, and of the angular distribution parameters, β, are performed for both HBr and HI. In our model, the σ and β curves look roughly like that of the isoelectronic Kr and Xe rare gases, but in order to obtain quantitative agreement with experiment, an approach including interchannel interactions, i.e. similar to that used for the halogen atoms would be probably necessary. 相似文献
98.
Dr. A. Keller Dr. E. Pedemonte Dr. F. M. Willmouth 《Colloid and polymer science》1970,238(1-2):385-389
Summary Extruded plugs of the styrene-butadiene-styrene amorphous copolymer Kraton 102 were found to exhibit discrete X-ray reflections in the low angle region such as are characteristic of an individual single crystal. This crystal lattice is hexagonal, with a lateral lattice spacing of 300 and an infinite period along the hexagonal axis which coincides with the extrusion direction. Annealing improved the crystal perfection, in fact a large portion of the macroscopic sample could become a single crystal. The orientation of the lattice could be influenced by deformation procedures in a consistent fashion. The diffraction effects are consistent with the styrene phase being in the form of cylinders. The cylinder diameter was estimated both from the lattice spacing coupled with the known molecular composition, and from missing reflections: both methods gave a diameter of close to 150 . Some suggestions are made on the molecular origin of this remarkable ordering phenomenon, together with pointing out some of the possible further consequences of such an order.
With 5 figures in 9 details 相似文献
Zusammenfassung Extrudierte pfropfenartige Proben von einem amorphen Block-Copolymeren Styrol-butadien-styrol (Kraton 102) ergaben diskrete Röntgenreflexe im Kleinwinkelbereich, wie sie im Weitwinkelbereich für Einzelkristalle charakteristisch sind. Das Kristallgitter ist hexagonal, lateraler Gitterabstand 300 , unendliche Periode entlang der hexagonalen Achse, die mit der Extrusionsrichtung zusammenfällt. Tempern verbesserte die Güte des Kristalls, so daß tatsächlich große Teile einer makroskopischen Probe sich zum Einzelkristall formen. Die Orientierung des Gitters kann auch durch Deformationsprozesse in konsistenter Weise beeinflußt werden. Die Beugungseffekte lassen sich deuten, wenn man für die Styrolphase Anordnungen zylindrischer Form annimmt. Der Durchmesser der Zylinder wurde geschätzt aus den Gitterabständen und den bekannten Molekulargewichtszusammensetzungen, sowie aus den fehlenden Reflexionen. Beide ergeben den Wert von ungefähr 150 . Einige Vorschläge werden über den molekularen Ursprung dieses bemerkenswerten Ordnungsphänomens gebracht, zusammen mit weiteren möglichen Konsequenzen einer solchen Ordnung.
With 5 figures in 9 details 相似文献
99.
Jaime De Andres Antonio Aguilar Jorge Domenech 《Journal of polymer science. Part A, Polymer chemistry》1988,26(5):1323-1334
The kinetics of the reaction between atactic polypropylene (APP) and oxygen in bulk at temperatures ranging from 170 to 210°C and oxygen partial pressures from 160 to 760 torr have been studied by thermal differential analysis. The reaction takes place in two successive steps, both giving hydroperoxide groups as product. Partial reaction orders with respect to APP and oxygen for the first step, which corresponds to the uncatalyzed attack of a C? H tertiary bond to give a hydroperoxide, are one and two, respectively. In the second step, interpreted as another attack on a tertiary C? H by oxygen, catalyzed by a neighboring hydroperoxide group, reaction orders are one and one-half for APP and oxygen, respectively. Activation parameters have been determined and a reaction sequence is proposed. Hydroperoxidated APP subsequently decomposes via a zero-order process giving methylketone groups as its main product. An interpretation of this process is also given. 相似文献
100.
J rg Enderlein Peter M. Goodwin Alan Van Orden W. Patrick Ambrose Rainer Erdmann Richard A. Keller 《Chemical physics letters》1997,270(5-6):464-470
We have developed a maximum likelihood estimator to distinguish between similar molecules at the single molecule level based upon fluorescence decay measurements. Time resolved fluorescence measurements for single Rhodamine 6G and tetramethylrhodamine isothiocyanate molecules in fluid flow are derived from time-correlated single photon counting. A maximum likelihood estimator is developed and applied to data from a mixture of molecules. Single molecules are identified and distinguished by their fluorescence time decays. Comparison is made between identification error rates and theoretical predictions. To our knowledge, this is the first reported example of single molecule identification by fluorescence decay in a mixture. 相似文献