Self-diffusion of V-48 in the FeV σ-phase and in an Fe-47 wt.% V solid solution

Self-diffusion coefficients of vanadium in the FeV -phase and in the corresponding -solid solution (Fe-47 wt.% V) measured in the temperature ranges 1002–1115 °C (-phase) and 1230–1320 °C are reported. The found results differ fundamentally and significantly from the relations in ordered and disordered solid solutions [9]. The diffusivity in -phase at the transition temperature (T _/=1200 °C) is cca 14 times lower than the diffusivity in the b.c.c. solid solution, the chemical composition of which is the same. The lowering is caused by the different values of frequency factors,D _O=0.11 cm²/s andD _O=45 cm²/s. The effect of the corresponding activation enthalpiesH =252 kJ/mole andH =293 kJ/mole is small and quite opposite. The occurence of higher activation enthalpyH in the -solid solution at temperaturesT>T _/ may be attributed to a certain amount of the f.c.c. phase coexisting in the b.c.c. matrix at concentrationsc _v>27 wt.% at sufficiently high temperatures [7]. A comparison of vanadium self-diffusion characteristics measured in the -phase to the extrapolated values obtained on the basis of the previous measurements [1] in the Fe-V primary solid solutions ₁ shows that the diffusivity ratioD ₁/D (1473 K)=33 and that the activation enthalpyH is by about 3% higher than the valuesH ₁ (eq. (5)) measured in the uniphase b.c.c. solid solutions.     

Mechanism and nanosize products of the sol-gel reaction using diphenylsilanediol and 3-methacryloxypropyltrimethoxysilane as precursors

We use a first-principles calculation and small-angle neutron scattering (SANS) to investigate the mechanism and the nanosize products of the sol-gel reaction with diphenylsilanediol (DPD) and 3-methacryloxypropyltrimethoxysilane (MEMO) precursors in synthesizing a hybrid waveguide material. It is predicted that switching between a DPD hydroxyl and a MEMO methoxy with a reaction rate of 6.8 x 10(-6) s(-1) at 300 K is the fastest process for the first reaction step, thus generating diphenylmethoxysilanol (DPM) and 3-methacryloxypropyldimethoxysilanol (MEDO) as products. However, we determine that this reaction pathway could be modified by the presence of the H2O released from a catalyst such as Ba(OH)2.H2O. Next, switching between the DPM hydroxyl and the MEDO methoxy is followed to generate diphenyldimethoxysilane (DPDM) and 3-methacryloxypropylmethoxysilanediol (MEMDO). However, condensation between a MEMDO hydroxyl and a DPDM methoxy is found to be most favorable for the third reaction step, which generates the DPDM-MEMDO dimer and CH3OH molecule as products. In a similar fashion, a DPDM methoxy of the DPDM-MEMDO dimer can condense with a MEMDO hydroxyl of the second DPDM-MEMDO dimer to increase the chain, but its reaction rate of 2.8 x 10(-11) s(-1) is predicted to be about 5 times smaller than that between a DPDM methoxy and a MEMDO hydroxyl. This implies that the reaction rate for the larger nanostructures becomes smaller. Additionally, our SANS measurements determine that the final products from our sol-gel reaction are on the nanometer scale, at sizes from 1.76 to 2.36 nm.     

A novel agarofuran sesquiterpene, celahin D from Celastrus hindsii Benth

A novel agarofuran sesquiterpene polyol ester, 1beta,2beta,6alpha,15beta-tetracetoxy-8 beta,9alpha-dibenzoyloxy-beta- dihydroagarofuran (celahin D) (1), two known analogues of 1,1beta-acetoxy-8beta,9alpha-dibenzoyloxy-4al pha6alpha-dihydroxy-2beta(alphamethylbutanoyloxy)-beta-++ +dihydroagarofuran (2) and beta-acetoxy-8beta,9alpha-dibenzoyloxy-6alpha-hy droxy-2beta(alpha -methylbutanoyloxy)-beta-dihydroagarofuran (3), and a known cytotoxic sesquiterpene pyridine alkaloid, emarginatine E (4) were isolated from the stems of Celastrus hindsii Benth. Three known triterpenes, loranthol (5), lupenone (6) and friedelinol (7) were also obtained from the titled plant. Structural elucidation of compound 1 was established by 2D NMR spectra.     

Anhydrous Deprotection of Dimethyl Acetals with Acetyl Chloride/ZnCl2

Dimethyl acetals are converted to the corresponding aldehyde in THF with acetyl chloride/zinc chloride in the presence of dimethyl sulfide     

Tetrachlorosilane Catalyzed Dithioacetalization

Tetrachlorosilane was found to be a mild as well as selective catalyst for dithioacetalization of the carbonyl compounds.     

On 2-factor hamiltonian regular bipartite graphs

A k-regular bipartite graph is said to be 2-factor hamiltonian if each of its 2-factor is hamiltonian. It is well known that if a k-regular bipartite graph is 2-factor hamiltonian, then k?Q3. In this paper, we give a new proof of this fact.     

Thermal transformation of polyacrylonitrile deposited on SBA-15 type silica

Thermogravimetry, diffuse reflectance infrared Fourier transform spectroscopy, and X-ray photoelectron spectroscopy (XPS) were used for the studying of thermally induced structural changes of polyacrylonitrile (PAN) deposited on the surface of SBA-15 type mesoporous silica. Polymer was introduced onto the support by the precipitation polymerization of acrylonitrile in aqueous suspension of SBA-15. Low temperature transformation (to 723?K) of the deposited PAN was analyzed. It was found that at about 523?K, exothermic cyclization of polymer chains to the so-called ladder form of PAN occurred. However, the total cyclization of PAN required higher carbonization temperatures, at which gradual dehydrogenation followed by graphitization was initiated. XPS revealed that the cyclic form of PAN and a relatively large amount of carbonyl species, formed during the carbonization of the PAN/SBA-15 composite at 623?K, were responsible for the high sorption capacity in the methyl?Cethyl ketone (MEK) vapor elimination. The efficiency in the MEK adsorption was also influenced by the content of PAN-derived carbon deposited on the SBA-15 surface.     

Switchable wavelength generation by injection-locked fiber laser based on GS-RSOAs

This paper proposes a switchable wavelength fiber laser (SWFL) based on an arrayed waveguide grating (AWG) and a gain-saturated reflective semiconductor optical amplifier (RSOA). The SWFL was experimentally implemented in the C- and L-bands. In order to achieve narrow-linewidth oscillation, the SWFL was driven by bidirectional injection-locked RSOAs. The RSOA was operated in the gain-saturated region, using gain compression properties to obtain uniform power over a wide bandwidth. Based on this configuration, we obtained 40 C-band international telecommunication unit (ITU) wavelengths with 100-GHz channel spacing. The SWFL displayed a narrow 3-dB bandwidth (<0.06 nm), a high and uniform peak power (P _max > 0.22 dB, ΔP _max < 0.26 dB), and a high and uniform side mode suppression ratio (SMSR > 66 dB, ΔSMSR < 1 dB). The peak-power and wavelength stabilities were ±0.24 dB and ±0.01 nm, respectively, at room temperature over a 1 h period.