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981.
We report the results of a study of white light generation in a 7.5 cm long crystal of a high band-gap material, barium fluoride, using ultrashort (<42 fs) laser pulses over a range of values of incident laser power that extend up to more than three orders of magnitude larger than the critical power for self-focusing (Pcr). We explore white light generation and the intensity and spectral distributions within filaments that are formed as a result of the interplay of self-focusing and plasma-induced defocusing. The onset of plasma effects occurs at power levels in excess of 7 GW for ultrashort pulses in BaF2. For incident power levels that are three orders of magnitude larger than the critical power, blue-shifting of the incident laser wavelength is observed in addition to asymmetric continuum generation. The blue shift enables us to estimate the temporal variation of the electron density in the plasma that is generated within the BaF2 crystal. PACS 52.38.Hb; 42.65.Jx; 42.65.Tg; 33.80.Wz; 52.35.Mw 相似文献
982.
Two tests for multivariate conditional heteroscedastic models are proposed. One is based on the cross-correlations of standardized squared residuals and the other is a score (Lagrange multiplier) test. The cross-correlations test can be used to detect the presence of multivariate conditional heteroscedasticity whereas the other test can be used for diagnostic checking. Simulation studies on the size and power of the test statistics are reported. The application of the tests is illustrated by an example using the S & P 500 and Sydney All Ordinary Indexes. 相似文献
983.
We apply a Bayesian approach to the problem of prediction in an unbalanced growth curve model using noninformative priors. Due to the complexity of the model, no analytic forms of the predictive densities are available. We propose both approximations and a prediction-oriented Metropolis-Hastings sampling algorithm for two types of prediction, namely the prediction of future observations for a new subject and the prediction of future values for a partially observed subject. They are illustrated and compared through real data and simulation studies. Two of the approximations compare favorably with the approximation in Fearn (1975, Biometrika, 62, 89–100) and are very comparable to the more accurate Rao-Blackwellization from Metropolis-Hastings sampling algorithm. 相似文献
984.
J.T. Devaraju B.H. Sharmila S. Asokan K.V. Acharya 《Applied Physics A: Materials Science & Processing》2002,75(4):515-518
The electrical switching behaviour of As45Te55-xInx (5≤x≤15) and As50Te50-xInx (2.5≤x≤11.5) has been studied over a wide range of compositions. These glasses are found to exhibit threshold switching.
The composition dependence of switching voltage (Vt) has been found to exhibit a change in slope and a local minimum at compositions x=10 and 12.5 for As45Te55-xInx and x=7.5 and 10.8 for As50Te50-xInx, respectively. The slope change in Vt verses x and the local minimum have been identified using two network topological effects, namely the rigidity percolation
threshold and the chemical threshold.
Received: 23 August 2001 / Accepted: 27 August 2001 / Published online: 11 February 2002 相似文献
985.
Laser driven shocks can lead to a dynamic failure, called film spallation. Here, we use a modified laser spallation set-up
to measure the dynamic adhesion of thin films and we propose a novel diagnostic technology. Based on correlation theory, new
spallation criteria for characterizing the progressive damage at the interface between the film and the substrate are established,
such as interface delamination, film spallation and film expulsion. With the help of the theory, the degree of damage and
the dimension of damage (i.e. fracture), such as the minimum width of delamination radius, the thickness of the film etc.,
are estimated. Experiments are carried out on epoxy/stainless steel and epoxy/Al, and the experimental results show that their
dynamic bonding strengths are about 25 MPa and 20 MPa, respectively. The detailed results, analyses and discussions are presented
in this paper.
Received: 6 February 2001 / Accepted: 3 December 2001 / Published online: 11 February 2002 相似文献
986.
The diffusion of carbon atoms between the volume and the surface of (100) molybdenum is directly studied at temperatures between 1400 and 2000 K (i.e., at process temperatures) for the first time. The balance of carbon atoms in the system is determined. The difference in the activation energies of carbon dissolution and precipitation, ΔE=E s 1-E1s, is found for the case when the diffusion fluxes of dissolved and precipitated carbon atoms are in equilibrium. This difference defines the enrichment of the surface by carbon relative to the bulk. The experimentally found activation energy of carbon dissolution is Es1=3.9 eV. The activation energy of carbon precipitation is estimated at E 1 s=1.9 eV. The latter value is close to the energy of bulk diffusion of carbon in molybdenum. 相似文献
987.
A classification has been obtained for spaces which admit complete sets of motion integrals of the (3.1)-type and are spatially homogeneous. The metrics and Killing vectors have been found in explicit form for all types of these spaces. A classification by Bianchi is given for the spaces obtained. 相似文献
988.
M. Gutowski I. Dabkowska J. Rak S. Xu J.M. Nilles D. Radisic K.H. Bowen Jr 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,20(3):431-439
The photoelectron spectra (PES) of anions of uracil-glycine and uracil-phenylalanine complexes reveal broad features with
maxima at 1.8 and 2.0 eV. The results of ab initio density functional B3LYP and second order M?ller-Plesset theory calculations indicate that the excess electron occupies a
π* orbital localized on uracil. The excess electron attachment to the complex can induce a barrier-free proton transfer (BFPT)
from the carboxylic group of glycine to the O8 atom of uracil. As a result, the four most stable structures of the anion of
uracil-glycine complex can be characterized as the neutral radical of hydrogenated uracil solvated by the anion of deprotonated
glycine. The similarity between the PES spectra for the uracil complexes with glycine and phenylalanine suggests that the
BFPT is also operative in the case of the latter anionic species. The BFPT to the O8 atom of uracil may be related to the
damage of nucleic acid bases by low energy electrons because the O8 atom is involved in a hydrogen bond with adenine in the
standard Watson-Crick pairing scheme.
Received 6 April 2002 Published online 13 September 2002 相似文献
989.
990.
N.-K. Lee T.A. Vilgis 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,28(4):451-465
We study the elastic properties of single A/B random copolymer chains, with a specific sequence and use them as theoretical
model for so called HP proteins. HP proteins carry hydrophilic (P) and hydrophobic (H) monomers. We predict a rich structure
in the force-extension relations which can be attributed to the information in the sequence. The variational method is used
to probe local minima on the path of stretching and releasing for the chain molecules. At a given force, we find multiple
configurations which are separated by energy barriers. A collapsed globular configuration consists of several domains which
unravel cooperatively. Upon stretching, the unfolding path shows a stepwise pattern corresponding to the unfolding of each
domain. While releasing, several cores can be created simultaneously in the middle of the chain, resulting in a different
path of collapse. The long-range interactions and stiffness of the chain simplify the potential landscape given by the disorder
in sequence.
Received 5 March 2002 / Received in final form 16 May 2002 Published online 13 August 2002 相似文献