全文获取类型
收费全文 | 213篇 |
免费 | 5篇 |
专业分类
化学 | 164篇 |
力学 | 10篇 |
数学 | 20篇 |
物理学 | 24篇 |
出版年
2024年 | 1篇 |
2023年 | 4篇 |
2022年 | 3篇 |
2021年 | 12篇 |
2020年 | 6篇 |
2019年 | 7篇 |
2018年 | 6篇 |
2017年 | 4篇 |
2016年 | 12篇 |
2015年 | 9篇 |
2014年 | 4篇 |
2013年 | 11篇 |
2012年 | 16篇 |
2011年 | 11篇 |
2010年 | 6篇 |
2009年 | 7篇 |
2008年 | 5篇 |
2007年 | 7篇 |
2006年 | 7篇 |
2005年 | 7篇 |
2004年 | 8篇 |
2003年 | 4篇 |
2002年 | 4篇 |
2001年 | 3篇 |
2000年 | 1篇 |
1999年 | 3篇 |
1998年 | 5篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1989年 | 1篇 |
1987年 | 3篇 |
1986年 | 4篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 3篇 |
1973年 | 2篇 |
1972年 | 2篇 |
1971年 | 2篇 |
1969年 | 1篇 |
排序方式: 共有218条查询结果,搜索用时 0 毫秒
191.
The catalytic effects of the Zn(II) complexes of a series of poliaminic ligands in the hydrolysis of the activated phosphodiesters bis-p-nitrophenyl phosphate (BNP) and 2-hydroxypropyl-p-nitrophenyl phosphate (HPNP) have been investigated. The reactions show first-order rate dependency on both substrate and metal ion complex and a pH dependence which is diagnostic of the acid dissociation of the reactive species. The mechanism of the metal catalyzed transesterification of HPNP has been assessed by solvent isotopic kinetic effect studies and involves the intramolecular nucleophilic attack of the substrate alcoholic group, activated by metal ion coordination. The intrinsic reactivity of the different complexes is controlled by the nature and structure of the ligand: complexes of tridentate ligands, particularly if characterized by a facial coordination mode, are more reactive than those of tetradentate ligands which can hardly allow binding sites for the substrate. In the case of tridentate ligands that form complexes with a facial coordination mode, a linear Br?nsted correlation between the reaction rate (log k) and the pK(a) of the active nucleophile is obtained. The beta(nuc) values are 0.75 for the HPNP transesterification and 0.20 for the BNP hydrolysis. These values are indicated as the result of the combination of two opposite Lewis acid effects of the Zn(II) ion: the activation of the substrate and the efficiency of the metal coordinated nucleophile. The latter factor apparently prevails in determining the intrinsic reactivity of the Zn(II) complexes. 相似文献
192.
SCF MO LCAO calculations using two different gaussian basis sets have been performed for the species HF, F?, BF3, BF 4 ? and HBF4 with geometry optimization. Differences in electrophilicity and proton donating capability of HF due to the formation of the adduct with BF3 are evidenced and discussed. 相似文献
193.
Oscar N. Ventura Agustí Lledós Rosanna Bonaccorsi Juan Bertrán Jacopo Tomasi 《Theoretical chemistry accounts》1987,72(3):175-195
Theoretical ab initio calculations are done on different mechanisms for the conversion of vinyl alcohol to acetaldehyde, both in gas phase and in solution. Several basis sets are used in order to assess the accuracy of the results in gas phase and a continuum model of the solvent is employed to mimic reactions in water solution. The results indicate a catalytic action of water in hydrated clusters in gas phase, whereas in solution, and within the error limits of our calculations, both neutral water-chain and ionic mechanisms appear to be equally probable. Finally, the action of acids or bases is tested through the analysis of the reaction of vinyl alcohol with H3O+ and HO–. The results of the calculations are shown to be in qualitative agreement with the experimental facts when 6-31++G basis set is used but not when either STO-3G or 4-31G basis sets are employed. 相似文献
194.
195.
Giuliano Alagona Renzo Cimiraglia Eolo Scrocco Jacopo Tomasi 《Theoretical chemistry accounts》1972,25(1):103-119
The conformation energies for monohydrated associates M · H2O, where M stands for oxirane, aziridine, oxaziridine and cyclopropene, have been obtained by using an electrostatic method, tested in a preceding paper, which relies on SCF molecular potentials calculated exactly. Stable associates have been found in the heterogroup region as well as near the bent bonds (single or double).A discussion is made on the errors in calculating thermodynamic properties for such associates in gas phase by using a priori calculations. As a numerical example the free energy change in the association process is compared for two monohydrated associates of aziridine.
Zusammenfassung Die Konformationsenergien für Anlagerungsverbindung M · H2O, wobei M für Oxiran, Aziridin, Oxaziridin und Cyclopropen steht, werden mit einer elektrostatischen Methode berechnet. Dieses Verfahren wurde in einer vorhergehenden Veröffentlichung getestet und beruht auf exakt berechneten SCF-Molekülpotentialen. Stabile Anlagerungsverbindungen wurden für Konformationen gefunden, bei denen das Wassermolekül in der Nähe der Heterogruppe oder der gezogenen Einfach- oder Doppelbindung liegt. Die Fehler bei der Berechnung thermodynamischer Eigenschaften für derartige Anlagerungsverbindungen in der Gasphase werden abgeschätzt. Als ein numerisches Beispiel wird die Differenz der freien Energie bei der Anlagerung für zwei Anlagerungsverbindungen von Aziridin und Molekül Wasser verglichen.相似文献
196.
197.
This work presents an extention of the polarizable continuum model to explicitly describe the time-dependent response of the solvent to a change in the solute charge distribution. Starting from an initial situation in which solute and solvent are in equilibrium, we are interested in modeling the time-dependent evolution of the solvent response, and consequently of the solute-solvent interaction, after a perturbation in this equilibrium situation has been switched on. The model introduces an explicit time-dependent treatment of the polarization by means of the linear-response theory. Two strategies are tested to account for this time dependence: the first one employs the Debye model for the dielectric relaxation, which assumes an exponential decay of the solvent polarization; the second one is based on a fitting of the experimental data of the solvent complex dielectric permittivity. The first approach is simpler and possibly less accurate but allows one to write an analytic expression of the equations. By contrast, the second approach is closer to the experimental evidence but it is limited to the availability of experimental data. The model is applied to the ionization process of N,N-dimethyl-aniline in both acetonitrile and water. The nonequilibrium free-energy profile is studied both as a function of the solvent relaxation coordinate and as a function of time. The solvent reorganization energy is evaluated as well. 相似文献
198.
We present a quantum-mechanical theory to study excitation energy transfers between molecular systems in solution. The model is developed within the time-dependent (TD) density-functional theory and the solvent effects are introduced in terms of the polarizable continuum model (PCM). Unique characteristic of this model is that both "reaction field" and screening effects are included in a coherent and self-consistent way. This is obtained by introducing proper solvent-specific operators in the Kohn-Sham equations and in the corresponding TD scheme. The solvation model exploits the integral equation formalism (IEF) version of PCM and it defines the solvent operators on a molecular cavity modeled on the real three-dimensional (3D) structure of the solute systems. Applications to EET in dimers of ethylene and naphtalene are presented and discussed. 相似文献
199.
Stanislaw Miertus Vladimir Frecer Emo Chiellini Federica Chiellini Roberto Solaro Jacopo Tomasi 《Journal of inclusion phenomena and macrocyclic chemistry》1998,32(1):23-46
Using a simple molecular mechanics approach interaction energy profiles of simple probes (C, CH4, C6H6, H2O, NH4
+, and HCOO-) passing through the center of the -CD ring cavity along the main molecular symmetry axis were first evaluated. Molecular Electrostatic Potential (MEP) values along the same path were also evaluated. The effect of the flexibility of the host -CD molecule together with solute-solvent (H2O) interactions have been represented by averaging structures of MD calculations for -CD alone and -CD surrounded by 133 H2O molecules. The effect of various substitutions of -CD has also been evaluated. Small symmetric hydrophobic probes (such as C, CH4, C6H6) are predicted to form stable inclusion complexes with non-substituted and substituted -CDs, the probe position typically being near the cavity center. The stability of the inclusion complexes will increase with increasing size and aliphatic character of the probe. Small polar and charged probes (such as H2O, NH4
+, HCOO-) are predicted to prefer the interaction with the solvent (water) in the bulk phase rather than the formation of inclusion complexes with non-substituted and substituted -CDs. Guest–host interactions in the stable inclusion complexes with hydrophobic probes are almost entirely dominated by dispersion interactions. The MEP reaches magnitudes close to zero in the center of the non-substituted -CD ring cavity and in most of the studied substituted -CDs and shows maximum positive or negative values outside of the cavity, near the ring faces. Substitution of -CD by neutral substituents leads to enhanced binding of hydrophobic probes and significant changes in the MEP profile along the -CD symmetry axis. 相似文献
200.
Hyungdae Kim Gregory DeWittThomas McKrell Jacopo BuongiornoLin-wen Hu 《International Journal of Multiphase Flow》2009
The quenching curves (temperature vs time) for small (∼1 cm) metallic spheres exposed to pure water and water-based nanofluids with alumina, silica and diamond nanoparticles at low concentrations (?0.1 vol%) were acquired experimentally. Both saturated (ΔTsub = 0 °C) and highly subcooled (ΔTsub = 70 °C) conditions were explored. The spheres were made of stainless steel and zircaloy, and were quenched from an initial temperature of ∼1000 °C. The results show that the quenching behavior in nanofluids is nearly identical to that in pure water. However, it was found that some nanoparticles accumulate on the sphere surface, which results in destabilization of the vapor film in subsequent tests with the same sphere, thus greatly accelerating the quenching process. The entire boiling curves were obtained from the quenching curves using the inverse heat transfer method, and revealed that alumina and silica nanoparticle deposition on the surface increases the critical heat flux and minimum heat flux temperature, while diamond nanoparticle deposition has a minimal effect on the boiling curve. The possible mechanisms by which the nanoparticles affect the quenching process were analyzed. It appears that surface roughness increase and wettability enhancement due to nanoparticle deposition may be responsible for the premature disruption of film boiling and the acceleration of quenching. The basic results were also confirmed by quench tests with rodlets. 相似文献