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131.
A theory has been given for the scattering of neutrons by anharmonic crystals, for which terms of the typeV
(3) (k
1j1; —k
1j1;o
j) which contribute to the sublattice displacements are not neglected. Using the standard perturbation theory in the interaction
picture or Green’s function method, an expression has been derived for the differential scattering cross-section which brings
in the shift and the width of the phonons in one-phonon energy exchange processes. It is shown that the sublattice displacements
will modify the phase factor arising from the scattering by any atom in the unit cell, and the Debye-Waller factor also gets
altered both by the sublattice displacements as well as by higher order terms arising from anharmonicity. It is shown that
the differential scattering cross-section contains a term linearly depending on the third order anharmonicity coefficientV
(3) (k
1j1;k
2j2;k
3j3) and neutron scattering by crystals should provide a useful method for evaluating the third order anharmonicity coefficients. 相似文献
132.
Jacob Philip 《Journal of Physics and Chemistry of Solids》1980,41(5):461-463
The Grüneisen parameter and lattice thermal expansion of the A-15 compounds V3Si and V3Ge at room temperature are evaluated on the basis of the method due to Brugger and Fritz [1] from the third order elastic constants reported earlier [2]. The calculated values are compared with available experimental values and are found to fit satisfactorily. 相似文献
133.
Abstract— As previously demonstrated, there is a considerable increase in the photodynamic activity of anthraquinone-sulphonic acid on the addition of ethylene glycol, glycerol and sugars in concentrations of the order of 0.4 M . This system exhibits cytostatic activity. With H2 O2 at higher concentrations there is also formation of aldehydes in approximately equivalent yields as follows:
R.CH2 OH+Q → QH2 +R.CHO
QH2 +O2 → Q+H2 O2
In accordance with the recent results of Warburg this accounts for the fundamental importance of glyceraldehyde in cancer research.
Our results on the irradiation of Proteus vulgaris SG2 in buffered medium with the addition of glycerin to anthraquinone-sulphonic acid show the existence of a similar cytostatic effect. One hour's irradiation with visible light reduces the cell count by about 50 per cent. 相似文献
R.CH
QH
In accordance with the recent results of Warburg this accounts for the fundamental importance of glyceraldehyde in cancer research.
Our results on the irradiation of Proteus vulgaris SG2 in buffered medium with the addition of glycerin to anthraquinone-sulphonic acid show the existence of a similar cytostatic effect. One hour's irradiation with visible light reduces the cell count by about 50 per cent. 相似文献
134.
The new method of azulene synthesis, described in the preceding communication, has been extended to the synthesis of guaiazulene and Se-guaiazulene. 相似文献
135.
Jacob Sagiv 《Tetrahedron》1977,33(17):2303-2313
The influence of substitution on the benzenoid 1Lb, 1La and 1B transitions is studied by the technique of linear dichroism in stretched polyethylene films.The total intensity of the 1Lb system is resolved into induced and vibrational components and the influence of various substitution patterns on the magnitude and polarization of both components is analyzed quantitatively. As expected from theoretical considerations, the vibrational components like the induced intensity are found to be strongly affected by the substituent strength and the symmetry of substitution pattern. The previously accepted assumption, according to which the vibrational intensity is regarded as a constant, appears to be completely unrealistic when dealing with cases of strong substituents. A satisfactory quantitative treatment of both weak and strong substituents using the same simple theoretical approach seems possible only if the systematic variations observed in the vibrational intensity are not neglected.A qualitative analysis is given for the 1La, and 1B systems. The results are compared with available theoretical predictions and previous experimental data.Practical implications of the present new experimental information to the study of aromatic optical activity are discussed. 相似文献
136.
G. Grimmer J. Jacob K. W. Naujack G. Dettbarn 《Fresenius' Journal of Analytical Chemistry》1981,309(1):13-19
Summary Polycyclic aromatic hydrocarbons (= PAH), sulphur- and oxygen-containing polycyclic aromatic compounds (= S- resp. O-PAC) which occur in concentrations higher than 1.5 mg/kg in a used motor oil sample originating from a gasoline powered engine were identified by comparison with reference substances (41) or, if reference compounds were lacking, characterized by mass spectrometry (about 110 compounds). Glass-capillary gas-chromatography combined with mass spectrometry was used for this inventory.To obtain a survey of the range of PAC- concentrations in different used oils from gasoline and Diesel fuel powered engines, 50 samples have been examined for a selected number of PAC.Inventory and Biological Impact of Polycyclic Carcinogens in the Environment, Part 13 相似文献
137.
The experimental charge density distribution of dimethyl-trans-2-oxohexahydro-pyrimidine-4,6-dicarboxylate 1 has been determined using single-crystal X-ray diffraction data measured at 100 K, in terms of the rigid-pseudoatom formalism. Multipole refinement converged at R(F) = 0.034 for 7283 reflections with I > 3 sigma (I) and sin theta/lambda < or = 1.13 A(-1). Covalent and hydrogen bonding interactions are analyzed using a topological analysis of the Laplacian of the charge density. The experimentally derived electrostatic potential mapped onto the reactive surface of the molecule reveals the potential binding sites of 1. 相似文献
138.
Albone DP Challenger S Derrick AM Fillery SM Irwin JL Parsons CM Takada H Taylor PC Wilson DJ 《Organic & biomolecular chemistry》2005,3(1):107-111
Amination of C-H bonds activated by ether oxygen atoms is facile with chloramine-T as nitrene source and copper(I) chloride in acetonitrile as catalyst. For cyclic ethers the hemiaminal products are generally stable and can be isolated pure. For acyclic ethers, the hemiaminal products, as expected, fragment with elimination of alcohol to yield imines. When activation of benzylic positions is remote through a conjugated system, stable benzylamine derivatives are isolated. Mechanistic studies are consistent with concerted insertion of an electrophilic nitrenoid into the C-H bond in the rate-determining step, though in an asynchronous manner with a more activated substrate. 相似文献
139.
According to the universal entropy bound, the entropy (and hence information capacity) of a complete weakly self-gravitating
physical system can be bounded exclusively in terms of its circumscribing radius and total gravitating energy. The bound’s
correctness is supported by explicit statistical calculations of entropy, gedanken experiments involving the generalized second
law, and Bousso’s covariant holographic bound. On the other hand, it is not always obvious in a particular example how the
system avoids having too many states for given energy, and hence violating the bound. We analyze in detail several purported
counterexamples of this type, and exhibit in each case the mechanism behind the bound’s efficacy.
In memoriam Asher Peres. 相似文献
140.
We use Monte Carlo simulations to identify the mechanism that allows for phase transitions in dipolar spin ice to occur and survive for an applied magnetic field H much larger in strength than that of the spin-spin interactions. In the most generic and highest symmetry case, the spins on one out of four sublattices of the pyrochlore decouple from the total local exchange+dipolar+applied field. In the special case where H is aligned perfectly along the [110] crystallographic direction, spin chains perpendicular to H show a transition to q=X long-range order, which proceeds via a one- to three-dimensional crossover. We propose that these transitions are relevant to the origin of specific heat features observed in powder samples of the Dy2Ti2O7 spin ice material for H above 1 Tesla. 相似文献